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Many theoretical expressions of dissipation along non-equilibrium processes have been proposed. However, they have not been fully verified by experiments. Especially for systems strongly interacting with environments the connection between…

Statistical Mechanics · Physics 2019-12-03 Ketan Goyal , Xian He , Ryoichi Kawai

We consider a quantum linear oscillator coupled at an arbitrary strength to a bath at an arbitrary temperature. We find an exact closed expression for the oscillator density operator. This state is non-canonical but can be shown to be…

Quantum Physics · Physics 2013-05-29 ILki Kim , Guenter Mahler

The validity of the Second Law of thermodynamics, indisputable in the macroscopic world, is challenged at the mesoscopic level: a mesoscopic isolated system, possessing spatial dimensions of the order of a few microns, is capable, as shown…

Classical Physics · Physics 2007-05-23 B. Crosignani , P. Di Porto , C. Conti

We provide a stochastic mathematical representation for Clausius' and Kelvin-Planck's statements of the Second Law of Thermodynamics in terms of the entropy productions of a finite, compact driven Markov system and its lift. A surjective…

Probability · Mathematics 2022-11-09 Yue Wang , Hong Qian

We generalize the Clausius (in)equality to overdamped mesoscopic and macroscopic diffusions in the presence of nonconservative forces. In contrast to previous frameworks, we use a decomposition scheme for heat which is based on an exact…

Statistical Mechanics · Physics 2015-05-07 Christian Maes , Karel Netocny

For a small driven system coupled strongly to a heat bath, internal energy and exchanged heat are identified such that they obey the usual additive form of the first law. By identifying this exchanged heat with the entropy change of the…

Statistical Mechanics · Physics 2016-02-03 Udo Seifert

The Markovian evolution of an open quantum system is characterized by a positive entropy production, while the global entropy gets redistributed between the system and the environment degrees of freedom. Starting from these premises, we…

We use rigorous nonequilibrium thermodynamic arguments to establish that (i) the nonequilibrium entropy S(T_{0}) of any system is bounded below by the experimentally (calorimetrically) determined entropy S_{expt}(T_{0}), (ii)…

Chemical Physics · Physics 2013-04-23 P. D. Gujrati

Dissipative quantum systems are frequently described within the framework of the so-called "system-plus-reservoir" approach. In this work we assign their description to the Maximum Entropy Formalism and compare the resulting thermodynamic…

Statistical Mechanics · Physics 2017-01-04 Lisan M. M. Durão , Amir O. Caldeira

Atmospheric systems incorporating thermal dynamics must be stable with respect to both energy and entropy. While energy conservation can be enforced via the preservation of the skew-symmetric structure of the Hamiltonian form of the…

Numerical Analysis · Mathematics 2023-10-31 Kieran Ricardo , David Lee , Kenneth Duru

Heat is a physical manifestation of entropy, where the removal of entropy from a thermal energy reservoir permits the conversion of heat into work. This entropy transfer is facilitated by the cold thermal energy reservoir in typical heat…

Quantum Physics · Physics 2025-11-12 Liam Judd McClelland

Thermodynamics is commonly presented as a theory of macroscopic systems in stable equilibrium, built upon assumptions of extensivity and scaling with system size. In this paper, we present a universal formulation of the elementary…

Quantum Physics · Physics 2026-03-26 Gian Paolo Beretta

Accurate characterization of entropy plays a pivotal role in capturing reversible and irreversible heating in supercapacitors during charging/discharging cycles. However, numerical methods that can faithfully capture entropy variation in…

Numerical Analysis · Mathematics 2024-09-17 Jie Ding , Xiang Ji , Shenggao Zhou

This study proposes a novel spatial discretization procedure for the compressible Euler equations which guarantees entropy conservation at a discrete level when an arbitrary equation of state is assumed. The proposed method, based on a…

Fluid Dynamics · Physics 2025-09-24 Alessandro Aiello , Carlo De Michele , Gennaro Coppola

We consider a situation where an $N$-level system (NLS) is coupled to a heat bath without being necessarily thermalized. For this situation we derive general Jarzinski-type equations and conclude that heat and entropy is flowing from the…

Quantum Physics · Physics 2021-08-25 Heinz-Jürgen Schmidt , Jürgen Schnack , Jochen Gemmer

We analyze the entropy production and the maximal extractable work from a squeezed thermal reservoir. The nonequilibrium quantum nature of the reservoir induces an entropy transfer with a coherent contribution while modifying its thermal…

Quantum Physics · Physics 2016-05-18 Gonzalo Manzano , Fernando Galve , Roberta Zambrini , Juan M. R. Parrondo

Thermodynamic entropy, as defined by Clausius, characterizes macroscopic observations of a system based on phenomenological quantities such as temperature and heat. In contrast, information-theoretic entropy, introduced by Shannon, is a…

Quantum Physics · Physics 2017-01-04 Mirjam Weilenmann , Lea Krämer , Philippe Faist , Renato Renner

We extend certain basic and general concepts of thermodynamics to discrete Markov systems exchanging work and heat with reservoirs. In this framework we show that the celebrated Clausius inequality can be generalized and becomes an…

Statistical Mechanics · Physics 2011-12-07 B. Gaveau , M. Moreau , L. S. Schulman

Since reversible computing requires preservation of all information throughout the entire computational process, this implies that all errors that appear as a result of the interaction of the information-carrying system with uncontrolled…

Quantum Physics · Physics 2009-11-13 Lev B. Levitin , Tommaso Toffoli

Active biological systems reside far from equilibrium, dissipating heat even in their steady state, thus requiring an extension of conventional equilibrium thermodynamics and statistical mechanics. In this Letter, we have extended the…

Soft Condensed Matter · Physics 2017-12-22 Dibyendu Mandal , Katherine Klymko , Michael R. DeWeese