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The addition of co-solutes to colloidal suspensions is often employed to induce tunable depletion interactions. In this work we investigate effective colloidal interactions arising from binary co-solute mixtures of hard spheres and patchy…

Soft Condensed Matter · Physics 2021-08-25 Philip H. Handle , Emanuela Zaccarelli , Nicoletta Gnan

Colloidal crystals with a diamond and pyrochlore structure display wide photonic band gaps at low refractive index contrasts. However, these low-coordinated and open structures are notoriously difficult to self-assemble from colloids…

Soft Condensed Matter · Physics 2019-06-26 Tonnishtha Dasgupta , Gabriele M. Coli , Marjolein Dijkstra

We consider a ternary mixture of hard colloidal spheres, ideal polymer spheres, and rigid vanishingly thin needles, which model stretched polymers or colloidal rods. For this model we develop a geometry-based density functional theory,…

Soft Condensed Matter · Physics 2009-11-07 Matthias Schmidt , Alan R. Denton

Brownian dynamics simulations are utilized to study segregation phenomena far from thermodynamic equilibrium. In the present study, we expand upon the analysis of binary colloid mixtures and additionally introduce a third particle species…

Soft Condensed Matter · Physics 2024-06-10 Kay Hofmann , Marc Isele , Artur Erbe , Paul Leiderer , Peter Nielaba

Colloidal model systems allow studying crystallization kinetics under fairly ideal conditions with rather well characterized pair interactions and minimized external influences. In complementary approaches therefore experiment, analytic…

Soft Condensed Matter · Physics 2015-06-19 Thomas Palberg

Catalytically active colloids maintain non-equilibrium conditions in which they produce and deplete chemicals and hence effectively act as sources and sinks of molecules. While individual colloids that are symmetrically coated do not…

Soft Condensed Matter · Physics 2015-06-11 Rodrigo Soto , Ramin Golestanian

We review recent experimental, numerical, and analytical results on active suspensions of self-propelled colloidal beads moving in (quasi) two dimensions. Active colloids form part of the larger theme of active matter, which is noted for…

Soft Condensed Matter · Physics 2014-09-03 Julian Bialké , Thomas Speck , Hartmut Löwen

Point polarizable molecules at fixed spatial positions have solvable electrostatic properties in classical approximation, the most familiar being the Clausius-Mossotti (CM) formula. This paper generalizes the model and imagines various…

Materials Science · Physics 2009-11-10 Philip B. Allen

The liquid-liquid phase separation of a binary solvent can be arrested by colloidal particles trapped at the interface [K. Stratford et al., Science 309, 5744 (2005)]. We show experimentally that the colloidal network so formed can remain…

Soft Condensed Matter · Physics 2015-05-14 Eduardo Sanz , Kathryn A. White , Paul S. Clegg , Michael E. Cates

The surface phase behavior of binary mixtures of colloidal hard rods in contact with a solid substrate (hard wall) is studied, with special emphasis on the region of the phase diagram that includes the smectic A phase. The colloidal rods…

Soft Condensed Matter · Physics 2010-12-17 Daniel de las Heras , Yuri Martínez-Ratón , Enrique Velasco

Over the past decade, a combination of crystal structure prediction techniques and experimental synthetic work has thoroughly explored the phase diagrams of binary hydrides under pressure. The fruitfulness of this dual approach is…

Superconductivity · Physics 2022-02-21 Katerina P. Hilleke , Eva Zurek

We use time-resolved mechanical spectroscopy to offer a detailed picture of the gelation dynamics of cellulose nanocrystal (CNC) suspensions following shear cessation in the presence of salt. CNCs are charged, rodlike colloids that…

Soft Condensed Matter · Physics 2024-02-20 Lise Morlet-Decarnin , Thibaut Divoux , Sebastien Manneville

We examine the fluid phase behaviour of the binary mixture of hard superellipses using the scaled particle theory The superellipse is a general two dimensional convex object which can be tuned between circular and rectangular shapes…

Soft Condensed Matter · Physics 2020-09-02 Sakine Mizani , Peter Gurin , Roohollah Aliabadi , Hamdollah Salehi , Szabolcs Varga

We present a scaled particle density functional study of two-dimensional binary mixtures of hard convex particles with one or both species being ellipses. In particular, we divide our study into two parts. The first part is devoted to the…

Soft Condensed Matter · Physics 2022-06-07 Yuri Martinez-Raton

We investigate the slow dynamics of a colloidal model with two repulsive length scales, whose interaction potential is the sum of a hard-core and a square shoulder. Despite the simplicity of the interactions, Mode-Coupling theory predicts a…

Soft Condensed Matter · Physics 2014-07-16 Nicoletta Gnan , Gayatri Das , Matthias Sperl , Francesco Sciortino , Emanuela Zaccarelli

Demixing of binary liquids is a ubiquitous transition, which is explained using a well-established thermodynamic formalism that requires equality of intensive thermodynamics parameters across the phase boundaries. Demixing transitions also…

A simple three-dimensional model of a fluid whose constituent particles interact via a short range attractive and long range repulsive potential is used to model the aggregation into large spherical-like clusters made up of hundreds of…

Soft Condensed Matter · Physics 2025-02-11 Antonio Díaz-Pozuelo , Diego González-Salgado , Enrique Lomba

We present results of Monte-Carlo simulations for finite 2D single and bilayer systems. Strong Coulomb correlations lead to arrangement of particles in configurations resembling a crystal lattice. For binary layers, there exists a…

Mesoscale and Nanoscale Physics · Physics 2015-06-24 A. V. Filinov , M. Bonitz , Yu. E. Lozovik

Understanding the condensed-phase behavior of chiral molecules is important in biology, as well as in a range of technological applications, such as the manufacture of pharmaceuticals. Here, we use molecular dynamics simulations to study a…

Statistical Mechanics · Physics 2023-12-27 Pablo M. Piaggi , Roberto Car , Frank H. Stillinger , Pablo G. Debenedetti

The phase diagram of a simple model with two patches of type A and ten patches of type B (2A10B) on the face centred cubic lattice has been calculated by simulations and theory. Assuming that there is no interaction between the B patches…

Soft Condensed Matter · Physics 2015-06-12 N. G. Almarza , J. M. Tavares , E. G. Noya , M. M. Telo da Gama