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Model Hamiltonians with long-range interaction yield energies that are corrected taking into account the universal behavior of the electron-electron interaction at short range. Although the intention of the paper is to explore the…

Chemical Physics · Physics 2020-10-28 Andreas Savin

The lack of long-range electrostatics is a key limitation of modern machine learning interatomic potentials (MLIPs), hindering reliable applications to interfaces, charge-transfer reactions, polar and ionic materials, and biomolecules. In…

Computational Physics · Physics 2025-12-23 Dongjin Kim , Bingqing Cheng

We propose a Kolmogorov-Arnold Representation-based Hamiltonian Neural Network (KAR-HNN) that replaces the Multilayer Perceptrons (MLPs) with univariate transformations. While Hamiltonian Neural Networks (HNNs) ensure energy conservation by…

Machine Learning · Computer Science 2025-08-28 Zongyu Wu , Ruichen Xu , Luoyao Chen , Georgios Kementzidis , Siyao Wang , Yuefan Deng

In this work, we consider a fundamental task in quantum many-body physics - finding and learning ground states of quantum Hamiltonians and their properties. Recent works have studied the task of predicting the ground state expectation value…

Quantum Physics · Physics 2025-01-16 Štěpán Šmíd , Roberto Bondesan

In this work, we incorporate long-range electrostatic interactions in the form of the Coulomb model with fixed charges into the functional form of short-range machine-learning interatomic potentials (MLIPs), particularly in the Moment…

Chemical Physics · Physics 2025-09-22 Dmitry Korogod , Olga Chalykh , Max Hodapp , Nikita Rybin , Ivan S. Novikov , Alexander V. Shapeev

Machine-Learned Interatomic Potentials (MLIPs) require vast amounts of atomic structure data to learn forces and energies, and their performance continues to improve with training set size. Meanwhile, the even greater quantities of…

Chemical Physics · Physics 2025-12-09 Manasa Kaniselvan , Benjamin Kurt Miller , Meng Gao , Juno Nam , Daniel S. Levine

The nonrelativistic Hamiltonians of scalar, spinor and vector particles in the electromagnetic field are studied by applying the Douglas-Kroll-Hess approach. Their relativistic Hamiltonians are expanded on the potential, and the…

High Energy Physics - Phenomenology · Physics 2022-04-20 Wanping Zhou , Xuesong Mei , Haoxue Qiao

Long-range electrostatics and polarization remain central obstacles to extending machine learning interatomic potentials (MLIPs) to ionic, polar, and interfacial systems. Here, we introduce a semi-local framework for learning electrostatics…

Materials Science · Physics 2026-05-08 Dongjin Kim , Daniel S. King , Yoonjae Park , Roya Savoj , Sebastien Hamel , Xiaoyu Wang , Bingqing Cheng

Microscopically conserving reduced models of many-body systems have a long, highly successful history. Established theories of this type are the random-phase approximation for Coulomb fluids and the particle-particle ladder model for…

Strongly Correlated Electrons · Physics 2019-07-19 Frederick Green

The H\"uckel Hamiltonian is an incredibly simple tight-binding model famed for its ability to capture qualitative physics phenomena arising from electron interactions in molecules and materials. Part of its simplicity arises from using only…

An effective Hamiltonian is derived in the case of the strong Hund coupling and on-site Coulomb interaction by means of a projective perturbation approach. A physical mechanism for charge ordering in half-doped manganites…

Strongly Correlated Electrons · Physics 2009-10-31 Shun-Qing Shen , Z. D. Wang

The crystal structure of the MAPbI$_3$ hybrid perovskite forms an intricate electrostatic puzzle with different ordering patterns of the MA molecules at elevated temperatures. For this perovskite three published model Hamiltonians based on…

Materials Science · Physics 2019-09-16 Jonathan Lahnsteiner , Ryosuke Jinnouchi , Menno Bokdam

A ubiquitous approach to obtain transferable machine learning-based models of potential energy surfaces for atomistic systems is to decompose the total energy into a sum of local atom-centred contributions. However, in many systems…

Computational Physics · Physics 2024-06-18 Jack Thomas , William J. Baldwin , Gábor Csányi , Christoph Ortner

We provide solid evidence for the long-standing presumption that model Hamiltonians with short-range interactions faithfully reproduce the physics of the long-range Coulomb interaction in real materials. For this aim, we address a generic…

Strongly Correlated Electrons · Physics 2025-06-09 Florian Gebhard , Kevin Bauerbach , Örs Legeza

The capabilities of image probe experiments are rapidly expanding, providing new information about quantum materials on unprecedented length and time scales. Many such materials feature inhomogeneous electronic properties with intricate…

Strongly Correlated Electrons · Physics 2023-05-12 S. Basak , M. Alzate Banguero , L. Burzawa , F. Simmons , P. Salev , L. Aigouy , M. M. Qazilbash , I. K. Schuller , D. N. Basov , A. Zimmers , E. W. Carlson

Machine Learning (ML) interatomic models and potentials have been widely employed in simulations of materials. Long-range interactions often dominate in some ionic systems whose dynamics behavior is significantly influenced. However, the…

Materials Science · Physics 2022-12-01 Hongyu Yu , Liangliang Hong , Shiyou Chen , Xingao Gong , Hongjun Xiang

This study presents a long-range descriptor for machine learning force fields (MLFFs) that maintains translational and rotational symmetry, similar to short-range descriptors while being able to incorporate long-range electrostatic…

Materials Science · Physics 2024-10-29 Carolin Faller , Merzuk Kaltak , Georg Kresse

Large scale Density Functional Theory (DFT) based electronic structure calculations are highly time consuming and scale poorly with system size. While semi-empirical approximations to DFT result in a reduction in computational time versus…

Materials Science · Physics 2016-12-21 Ganesh Hegde , R. Chris Bowen

We use density-matrix renormalization group, applied to a one-dimensional model of continuum Hamiltonians, to accurately solve chains of hydrogen atoms of various separations and numbers of atoms. We train and test a machine-learned…

Strongly Correlated Electrons · Physics 2016-12-28 Li Li , Thomas E. Baker , Steven R. White , Kieron Burke

We derive a "Wannier-Hubbard" model consisting of an array of overlapping atomic orbitals interacting via a local Coulomb interaction. Transforming to an orthogonal Wannier basis set, the resulting Hamiltonian displays long range hopping…

Strongly Correlated Electrons · Physics 2022-07-27 Samuel Milner , Phillip Weinberg , Adrian Feiguin
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