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We present a thermodynamic theory of the Kovacs effect based on the idea that the configurational degrees of freedom of a glass-forming material are driven out of equilibrium with the heat bath by irreversible thermal contraction and…

Materials Science · Physics 2016-12-14 Eran Bouchbinder , J. S. Langer

Quantum thermalization in contemporary quantum devices, in particular quantum computers, has recently attracted significant theoretical interest. Unusual thermalization processes, such as the Quantum Mpemba Effect (QME), have been explored…

Quantum Physics · Physics 2024-12-05 Marc Espinosa Edo , Lian-Ao Wu

We demonstrate that irreversibility arises from the principle of microscopic reversibility and the presence of memory in the time evolution of a single copy of a system driven by a protocol. We introduce microscopic reversibility by using…

Statistical Mechanics · Physics 2015-11-30 J. Ricardo Arias-Gonzalez

Practical implementations of quantum technologies require preparation of states with a high degree of purity---or, in thermodynamic terms, very low temperatures. Given finite resources, the Third Law of thermodynamics prohibits perfect…

Quantum imaginary-time evolution (QITE) is a fundamental framework for preparing ground and thermal states, yet its computational cost scales significantly with the evolution duration $\tau$. Reducing this duration is critical for practical…

Quantum Physics · Physics 2026-04-21 Yumeng Zeng , Jeongrak Son , Mile Gu , Xiao Yuan

Complex and even non-monotonic responses to external control can be found in many thermodynamic systems. In such systems, non-equilibrium shortcuts can rapidly drive the system from an initial state to a desired final state. One example is…

Statistical Mechanics · Physics 2023-04-28 Supraja S. Chittari , Zhiyue Lu

The fact that macroscopic systems approach thermal equilibrium may seem puzzling, for example, because it may seem to conflict with the time-reversibility of the microscopic dynamics. We here prove that in a macroscopic quantum system for a…

Statistical Mechanics · Physics 2015-06-18 Sheldon Goldstein , Takashi Hara , Hal Tasaki

Thermodynamics is commonly presented as a theory of macroscopic systems in stable equilibrium, built upon assumptions of extensivity and scaling with system size. In this paper, we present a universal formulation of the elementary…

Quantum Physics · Physics 2026-03-26 Gian Paolo Beretta

We frame Newton's Law of Cooling as a gradient flow within the context of information geometry. This connects it to a thermodynamic uncertainty relation and the Horse-Carrot Theorem, and reveals novel instances of asymmetric relaxations in…

Mathematical Physics · Physics 2025-02-20 Alessandro Bravetti , Miguel Ángel García Ariza , Pablo Padilla

I suggest that the origin of the Mpemba effect (the freezing of hot water before cold) is freezing-point depression by solutes, either gaseous or solid, whose solubility decreases with increasing temperature so that they are removed when…

Chemical Physics · Physics 2017-01-30 J. I. Katz

We analyze the temperature relaxation phenomena of systems in contact with a thermal reservoir that undergo a non-Markovian diffusion process. From a generalized Langevin equation, we show that the temperature is governed by a law of…

Statistical Mechanics · Physics 2015-06-23 Luciano C. Lapas , Rogelma M. S. Ferreira , Fernando A. Oliveira , J. Miguel Rubí

Understanding relaxation dynamics in open quantum systems is a central problem in nonequilibrium quantum physics. Here we investigate the quantum Mpemba effect in the spin-boson model. In the weak-coupling Markovian regime we show that the…

Quantum Physics · Physics 2026-03-19 P. Chirico , G. Di Bello , G. De Filippis , C. A. Perroni

We investigate the thermodynamic behaviour of a Bose gas interacting with repulsive forces and confined in a harmonic anisotropic trap. We develop the formalism of mean field theory for non uniform systems at finite temperature, based on…

Condensed Matter · Physics 2015-06-25 S. Giorgini , L. P. Pitaevskii , S. Stringari

The majority vote model is one of the simplest opinion systems yielding distinct phase transitions and has garnered significant interest in recent years. However, its original formulation is not, in general, thermodynamically consistent,…

Statistical Mechanics · Physics 2023-06-16 Felipe Hawthorne , Mário J. de Oliveira , Pedro E. Harunari , Carlos E. Fiore

The quantum Mpemba effect (QMPE), an intriguing anomalous relaxation phenomenon, has recently attracted significant attention. However, how various types of noise, which are ubiquitous in real systems, may affect the QMPE remains unknown.…

Quantum Physics · Physics 2025-07-17 Mingrui Zhao , Zhonghuai Hou

Inspired by responses to the work (arXiv:1310.6514), we solved the one-dimensional, nonlinear Fourier initial and boundary condition problem using the finite element method. Examination of all possible parameters reveals the following: 1.…

Chemical Physics · Physics 2015-01-16 Xi Zhang , Yongli Huang , Zengsheng Ma , Chang Q Sun

Via molecular dynamics simulations we study ICE formation in the TIP4P/Ice model that is known to describe structure and dynamics in various phases of WATER accurately. For this purpose well equilibrated configurations from different…

Statistical Mechanics · Physics 2024-07-10 Soumik Ghosh , Purnendu Pathak , Sohini Chatterjee , Subir K. Das

Master equation could be applied to model various kinds of biochemical systems. A general theory for its time-dependent nonequilibrium thermodynamics is rigorously derived. We not only introduce a concept of general internal energy, but…

Statistical Mechanics · Physics 2009-04-16 Hao Ge

The nonequilibrium thermodynamics of interacting quantum many-body systems is investigated within the framework of thermal time-dependent density functional theory using a generalized linear-response formulation for the full quantum work…

Quantum Physics · Physics 2025-12-23 Antonio Palamara , Francesco Plastina , Antonello Sindona , Irene D'Amico

It is "conventional wisdom" that the uncertainty of local temperature measurements on equilibrium systems diverges exponentially fast as their temperature $T$ drops to zero. In contrast, some exactly solvable models showcase a more benign…

Quantum Physics · Physics 2018-07-04 Karen V. Hovhannisyan , Luis A. Correa