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It is demonstrated that the time evolution of the electron-nuclear polarization transfer process during pulsed dynamic nuclear polarization (DNP) can be reversed on a microsecond timescale, leading to the observation of DNP echoes. The DNP…

Chemical Physics · Physics 2024-06-28 Nino Wili , Anders B. Nielsen , José P. Carvalho , Niels Chr. Nielsen

The past decade has demonstrated increasing interests in using optimal control based methods within coherent quantum controllable systems. The versatility of such methods has been demonstrated with particular elegance within nuclear…

Quantum Physics · Physics 2015-05-18 Ivan I. Maximov , Niels Chr. Nielsen , Julien Salomon , Gabriel Turinici

High-fidelity multi-qubit initialization is vital for quantum simulation, quantum information processing (QIP), and quantum sensing. In diamond platforms, nuclear spin registers can be initialized through polarization transfer from a nearby…

Quantum Physics · Physics 2026-03-02 Soham Pal , Oliver T. Whaites , Wolfgang Knolle , Tania S. Monteiro , Helena S. Knowles

Coupled electron-nuclear spins represent a promising quantum system, where the optically induced electron spin polarization can be dynamically transferred to nuclear spins via the hyperfine interaction. Most experiments on dynamic nuclear…

Materials Science · Physics 2026-01-13 A. N. Anisimov , A. V. Poshakinskiy , G. V. Astakhov

Taking inspiration from NMR spectroscopy, periodic irradiation schemes have recently shown remarkable performance when implemented into pulsed dynamic nuclear polarization (DNP) sequences. This has prompted considerable interest in…

The ability to initialise nuclear spins, which are typically in a mixed state even at low temperature, is a key requirement of many protocols used in quantum computing and simulations as well as in magnetic resonance spectroscopy and…

Quantum Physics · Physics 2018-10-02 J. E. Lang , J. -P. Tetienne , T. S. Monteiro

Nuclear spin hyperpolarization techniques, such as dynamic nuclear polarization (DNP) and parahydrogen-induced polarization (PHIP), have revolutionized nuclear magnetic resonance and magnetic resonance imaging. In these methods, a readily…

Dynamic nuclear polarization (DNP) enhances the intensity of NMR signals by transferring polarization from electron spins to nuclei via microwave irradiation. Pulsed DNP methods offer more control on the spin dynamics than conventional…

Chemical Physics · Physics 2026-01-07 Lorenzo Niccoli , Gian-Marco Camenisch , Matías Chávez , Matthias Ernst

Over the last two decades magic angle spinning dynamic nuclear polarization (MAS DNP) has revolutionized NMR for materials characterization, tackling its main limitation of intrinsically low sensitivity. Progress in theoretical…

Chemical Physics · Physics 2025-02-18 Daniel Jardon- Alvarez , Michal Leskes

Aimed at the simulation, design, and interpretation of advanced pulse experiments crossing the boundaries between nuclear magnetic resonance (NMR) and electron paramagnetic resonance (EPR), including the rapidly emerging, hybrid discipline…

Nuclear electric resonance (NER) is based on nuclear magnetic resonance mediated by spatial oscillations of electron spin domains excited by a radio frequency (RF) electric field, and it allows us to investigate the spatial distribution of…

Mesoscale and Nanoscale Physics · Physics 2012-10-25 S. Watanabe , G. Igarashi , N. Kumada , Y. Hirayama

The thesis is centred on the theory of experimental methods in solid-state Nuclear Magnetic Resonance (ssNMR) spectroscopy, which deals with the interaction of electromagnetic radiation with nuclei in a magnetic field and possessing a…

Quantum Physics · Physics 2017-11-21 Ravi Shankar Palani

The integration on a single chip of the sensitivity-relevant electronics of nuclear magnetic resonance (NMR) and electron spin resonance (ESR) spectrometers is a promising approach to improve the limit of detection, especially for samples…

Instrumentation and Detectors · Physics 2020-03-09 Nergiz Sahin Solmaz , Marco Grisi , Alessandro Valentino Matheoud , Gabriele Gualco , Giovanni Boero

The hyperpolarization of nuclear spins can enable powerful imaging and sensing techniques provided the hyperpolarization is sufficiently long-lived. Recent experiments on nanodiamond $^{13}$C nuclear spins demonstrate that relaxation times…

Mesoscale and Nanoscale Physics · Physics 2024-02-20 Gargee Sharma , Torsten Gaebel , Ewa Rej , David J. Reilly , Sophia E. Economou , Edwin Barnes

Spin engineering of advanced pulse sequences has had a transformative impact on the development of nuclear magnetic resonance (NMR) spectroscopy, to an extending degree also electron paramagnetic resonance (EPR), and the hybrid between the…

Chemical Physics · Physics 2025-01-31 Jose P. Carvalho , Anders Bodholt Nielsen , Eniko Baligacs , Nino Wili , Niels Chr. Nielsen

Dynamic nuclear polarization experiments use microwave irradiation to transfer the larger electron polarization to nuclear spins of interest, and thus enhance the NMR transitions above thermal equilibrium. How the polarization transfer from…

Chemical Physics · Physics 2026-01-12 Gian-Marco Camenisch , Nino Wili , Gunnar Jeschke , Matthias Ernst

Dynamic nuclear polarization is widely used to enhance the sensitivity of nuclear magnetic resonance. It is presently the method of choice for enhancing the sensitivity of high-field solid state NMR experiments performed under cryogenic…

Chemical Physics · Physics 2022-02-02 Maria Grazia Concilio , Ilya Kuprov , Lucio Frydman

We studied spatial distribution of dynamic nuclear polarization (DNP) in a Hall-bar device in a breakdown regime of the quantum Hall effect (QHE). We detected nuclear magnetic resonance (NMR) signals from the polarized nuclear spins by…

Mesoscale and Nanoscale Physics · Physics 2011-01-25 Minoru Kawamura , Kimitoshi Kono , Yoshiaki Hashimoto , Shingo Katsumoto , Tomoki Machida

Dynamic nuclear polarization (DNP) using the boron vacancy ($\mathrm{V_B^-}$) in hexagonal boron nitride (hBN) has gained increasing attention. Understanding this DNP requires systematically investigating the optically detected magnetic…

Dynamic Nuclear Polarization (DNP) is a powerful suite of techniques that deliver multifold signal enhancements in NMR and MRI. The generated athermal spin states can also be exploited for quantum sensing and as probes for many-body…