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We develop a method using a coarse graining of the energy fluctuations of an equilibrium quantum system which produces simple parameterizations for the behaviour of the system. As an application, we use these methods to gain more…

Statistical Mechanics · Physics 2007-05-23 Jani Lukkarinen

We show that there exists a natural way to define a condition of generalized thermal equilibrium between systems governed by Tsallis thermostatistics, under the hypotheses that i) the coupling between the systems is weak, ii) the structure…

Statistical Mechanics · Physics 2007-09-17 Massimo Marino

The maximum entropy technique (MENT) is used to determine the distribution functions of physical values. MENT naturally combines required maximum entropy, the properties of a system and connection conditions in the form of restrictions…

High Energy Physics - Experiment · Physics 2007-05-23 B. Z. Belashev , M. K. Suleymanov

Thermodynamics is commonly presented as a theory of macroscopic systems in stable equilibrium, built upon assumptions of extensivity and scaling with system size. In this paper, we present a universal formulation of the elementary…

Quantum Physics · Physics 2026-03-26 Gian Paolo Beretta

A thermodynamic system of non-interacting quantum particles changes its statistical distribution formulas if there is a universal limitation for the size of energetic quantum leaps (magnitude of quantum leaps smaller than Planck energy). By…

General Relativity and Quantum Cosmology · Physics 2015-03-17 Rainer Collier

Introduced by Boltzmann under the name "monode," the microcanonical ensemble serves as the fundamental representation of equilibrium thermodynamics in statistical mechanics by counting all possible realizations of a system's states.…

Statistical Mechanics · Physics 2026-01-27 Roman Belousov , Jenna Elliott , Florian Berger , Lamberto Rondoni , Anna Erzberger

The random matrix ensembles (RME) of quantum statistical Hamiltonian operators, e.g. Gaussian random matrix ensembles (GRME) and Ginibre random matrix ensembles (Ginibre RME), are applied to following quantum statistical systems: nuclear…

Statistical Mechanics · Physics 2007-05-23 Maciej M. Duras

The physical impossibility of heat transfer under isothermal conditions implies that the classical expression for the entropy of the ideal gas may not be compatible with the internal energy of the gas itself. A corrected expression of the…

Statistical Mechanics · Physics 2023-09-01 A. Paglietti

We investigate the overdamped stochastic dynamics of a particle in an asymptotically flat external potential field, in contact with a thermal bath. For an infinite system size, the particles may escape the force field and diffuse freely at…

Statistical Mechanics · Physics 2020-06-24 Erez Aghion , David A. Kessler , Eli Barkai

A principle of maximum entropy is proposed in the context of viscous incompressible flow in Eulerian coordinates. The relative entropy functional, defined over the space of $L^2$ divergence-free velocity fields, is maximized relative to…

Fluid Dynamics · Physics 2024-02-23 Gui-Qiang G. Chen , James Glimm , Hamid Said

We develop the argument that the Gibbs-von Neumann entropy is the appropriate statistical mechanical generalisation of the thermodynamic entropy, for macroscopic and microscopic systems, whether in thermal equilibrium or not, as a…

Quantum Physics · Physics 2008-01-23 O. J. E. Maroney

Ensemble inequivalence, i.e. the possibility of observing different thermodynamic properties depending on the statistical ensemble which describes the system, is one of the hallmarks of long-range physics, which has been demonstrated in…

Statistical Mechanics · Physics 2024-08-15 Nicolò Defenu , David Mukamel , Stefano Ruffo

Before the thermodynamic limit, macroscopic averages need not commute for a quantum system. As a consequence, aspects of macroscopic fluctuations or of constrained equilibrium require a careful analysis, when dealing with several…

Mathematical Physics · Physics 2007-05-23 W. De Roeck , C. Maes , K. Netocny

We introduce a constructive framework for assigning thermodynamic structure to an arbitrary data system from its measured microstates. Starting from an empirical distribution over configurations, we first infer a data-driven energy function…

Statistical Mechanics · Physics 2026-04-29 George-Rafael Domenikos , Lock Yue Chew , Victoria Leong

A few decades after Hill's work on nano-thermodynamics, the development of a thermodynamic framework, to account consistently for the fluctuations of small systems due to their interactions with the surrounding environment, is still…

Statistical Mechanics · Physics 2019-09-23 Salvatore Calabrese , Lamberto Rondoni , Amilcare Porporato

A way to construct Boltzmann entropy, i.e., the entropy as a function of a microscopic pure state, for quantum field systems is proposed. Operators that shift the field in wavevector space are used in the construction. By employing an…

Statistical Mechanics · Physics 2020-03-25 Kyo Yoshida

In the real world, one almost never knows the parameters of a thermodynamic process to infinite precision. Reflecting this, here we investigate how to extend stochastic thermodynamics to systems with uncertain parameters, including…

Statistical Mechanics · Physics 2021-03-17 Jan Korbel , David H. Wolpert

Consider a quantum system $S$ weakly interacting with a very large but finite system $B$ called the heat bath, and suppose that the composite $S\cup B$ is in a pure state $\Psi$ with participating energies between $E$ and $E+\delta$ with…

Quantum Physics · Physics 2014-02-25 Viraj Pandya , Roderich Tumulka

From a new rigorous formulation of the general axiomatic foundations of thermodynamics we derive an operational definition of entropy that responds to the emergent need in many technological frameworks to understand and deploy thermodynamic…

Quantum Physics · Physics 2019-11-21 Gian Paolo Beretta , Enzo Zanchini

We argue that a very large class of quantum pure states of isolated macroscopic bodies have sharply peaked energy distributions, with their width relative to the average scaling between $\sim N^{-1}$ and $\sim N^{-1/2}$, with $N \gg 1$, the…

Quantum Physics · Physics 2021-07-15 Víctor Romero-Rochín