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We consider quantum computational models defined via a Lie-algebraic theory. In these models, specified initial states are acted on by Lie-algebraic quantum gates and the expectation values of Lie algebra elements are measured at the end.…

Quantum Physics · Physics 2009-11-13 Rolando Somma , Howard Barnum , Gerardo Ortiz , Emanuel Knill

Quantum computing is being extensively used in quantum chemistry, especially in simulating simple molecules and evaluating properties like the ground state energy, dipole moment, etc. The transformation of a molecular Hamiltonian from the…

Quantum Physics · Physics 2024-01-18 Harshdeep Singh , Sabyashachi Mishra , Sonjoy Majumder

We present a basis-set-free approach to the variational quantum eigensolver using an adaptive representation of the spatial part of molecular wavefunctions. Our approach directly determines system-specific representations of qubit…

Quantum Physics · Physics 2021-01-05 Jakob S. Kottmann , Philipp Schleich , Teresa Tamayo-Mendoza , Alán Aspuru-Guzik

To treat a problem with a Quantum Processing Unit (QPU), it must be transformed into a sequence of quantum operations, or gates: this is the quantum description of the problem. These operations are either packed into a query (i.e. quantum…

Quantum Physics · Physics 2026-03-19 Robin Ollive , Stéphane Louise

In a pre-selected Hilbert space of quantum states the unitarity of the evolution is usually guaranteed via a pre-selection of the generator (i.e., of the Hamiltonian operator) in self-adjoint form. In fact, the simultaneous use of both of…

Quantum Physics · Physics 2013-11-26 Miloslav Znojil

Quantum computing has long promised transformative advances in data analysis, yet practical quantum machine learning has remained elusive due to fundamental obstacles such as a steep quantum cost for the loading of classical data and poor…

While quantum algorithms for solving large scale systems of linear equations offer potentially exponential speedups, their application has largely been confined to sparse matrices. This work extends the scope of these algorithms to a broad…

Quantum Physics · Physics 2026-02-27 Kun Tang , Jun Lai

Quantum computers can be used to address molecular structure, materials science and condensed matter physics problems, which currently stretch the limits of existing high-performance computing resources. Finding exact numerical solutions to…

Quantum chemistry provides a target for quantum simulation of considerable scientific interest and industrial importance. The majority of algorithms to date have been based on a second-quantized representation of the electronic structure…

Quantum Physics · Physics 2013-12-17 Borzu Toloui , Peter J. Love

Quantum computation of vibrational properties of molecules is a promising platform to obtain computational advantages for computational chemistry. However, fault-tolerant quantum computations of vibrational properties remain a relatively…

We explore the utilization of higher-order discretization techniques in optimizing the gate count needed for quantum computer based solutions of partial differential equations. To accomplish this, we present an efficient approach for…

Quantum Physics · Physics 2024-12-30 Boris Arseniev , Dmitry Guskov , Richik Sengupta , Igor Zacharov

The linearity inherent in quantum mechanics limits current quantum hardware from directly solving nonlinear systems governed by nonlinear differential equations. One can opt for linearization frameworks such as Carleman linearization, which…

Quantum Physics · Physics 2026-02-10 Tayyab Ali

Quantum algorithms for diverse problems, including search and optimization problems, require the implementation of a reflection operator over a target state. Commonly, such reflections are approximately implemented using phase estimation.…

Quantum Physics · Physics 2018-03-08 Anirban Narayan Chowdhury , Yigit Subasi , Rolando D. Somma

A quantum eigensolver is designed under a multi-layer cluster mean-field (CMF) algorithm by partitioning a quantum system into spatially-separated clusters. For each cluster, a reduced Hamiltonian is obtained after a partial average over…

We generalize a recently proposed algebraic method in order to treat non-Hermitian Hamiltonians. The approach is applied to several quadratic Hamiltonians studied earlier by other authors. Instead of solving the Schr\"odinger equation we…

Quantum Physics · Physics 2020-09-04 Francisco M. Fernández

Quantum computing has been increasingly applied in nuclear physics. In this work, we combine quantum computing with the complex scaling method to address the resonance problem. Due to the non-Hermiticity introduced by complex scaling,…

Nuclear Theory · Physics 2024-09-11 Hantao Zhang , Dong Bai , Zhongzhou Ren

We present a quantum algorithm for finding the minimum of a function based on multistep quantum computation and apply it for optimization problems with continuous variables, in which the variables of the problem are discretized to form the…

Quantum Physics · Physics 2023-07-03 Hefeng Wang , Hua Xiang

Exactly-solvable Hamiltonians that can be diagonalized using relatively simple unitary transformations are of great use in quantum computing. They can be employed for decomposition of interacting Hamiltonians either in Trotter-Suzuki…

Quantum Physics · Physics 2023-09-19 Smik Patel , Tzu-Ching Yen , Artur F. Izmaylov

We study the regimes in which Hamiltonian simulation benefits from randomization. We introduce a sparse-QSVT construction based on composite stochastic decompositions, where dominant terms are treated deterministically and smaller…

Quantum Physics · Physics 2026-04-10 Francesco Paganelli , Michele Grossi , Andrea Giachero , Thomas E. O'Brien , Oriel Kiss

The development of tailored materials for specific applications is an active field of research in chemistry, material science and drug discovery. The number of possible molecules that can be obtained from a set of atomic species grow…