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Density functional theory (DFT) is a widespread and effective tool in electronic structure calculations for ground-state electron systems. Its success has prompted exploration into the use of DFT for non-collective excited states. The delta…

Chemical Physics · Physics 2025-08-12 Ethan Pollack , Rohan Maniar , John P. Perdew

We present a modification of the $\Delta$SCF method of calculating energies of excited states, in order to make it applicable to resonance calculations of molecules adsorbed on metal surfaces, where the molecular orbitals are highly…

Materials Science · Physics 2009-03-06 Jeppe Gavnholt , Thomas Olsen , Mads Engelund , Jakob Schiøtz

Delta-self-consistent field theory (delta-SCF) is a conceptually simple and computationally inexpensive method for finding excited states. Using the maximum overlap method to guide optimization of the excited state, delta-SCF has been shown…

Chemical Physics · Physics 2021-04-07 Susannah Bourne Worster , Oliver Feighan , Frederick R. Manby

Vector and scalar potentials are used for convenience in solving boundary value problems involving electromagnetic (EM) fields. The potentials are made unique by choosing a non-unique gauge relationship. The most commonly used gauges are…

Classical Physics · Physics 2022-01-31 D. V. Giri , Frederick M. Tesche , Michael A. Morgan

We extend ground-state density-functional theory to excited states and provide the theoretical formulation for the widely used $\Delta SCF$ method for calculating excited-state energies and densities. As the electron density alone is…

Chemical Physics · Physics 2024-03-08 Weitao Yang , Paul W. Ayers

Using a set of oscillator strengths and excited-state dipole moments of near full configuration interaction (FCI) quality determined for small compounds, we benchmark the performances of several single-reference wave function methods (CC2,…

Chemical Physics · Physics 2021-06-14 Rudraditya Sarkar , Martial Boggio-Pasqua , Pierre-François Loos , Denis Jacquemin

The implementation of an efficient self-consistent field (SCF) method including both scalar relativistic effects and spin-orbit interaction in density functional theory (DFT) is presented. We make use of Gaussian-type orbitals (GTOs) and…

Chemical Physics · Physics 2024-05-03 Yannick J. Franzke , Werner M. Schosser , Fabian Pauly

In this article, we study the no-boundary wave function in scalar-tensor gravity with various potentials for the non-minimally coupled scalar field. Our goal is to calculate probabilities for the scalar field - and hence the effective…

General Relativity and Quantum Cosmology · Physics 2015-05-28 Dong-il Hwang , Hanno Sahlmann , Dong-han Yeom

The single stretched-wire method is commonly used to measure the magnetic field strength and magnetic axis in an accelerator magnet. The integrated voltage at the connection terminals of the wire is a measure for the flux linked with the…

Accelerator Physics · Physics 2020-06-18 Stephan Russenschuck

Near-degenerate electronic structures remain a major challenge for conventional single-reference density functional theory (DFT). To address this problem, we propose time-dependent $\Delta$SCF (TD$\Delta$SCF), a novel linear-response scheme…

Chemical Physics · Physics 2026-05-12 Shuto Shibasaki , Fumiya Mohri , Takashi Tsuchimochi

A gravity theory is developed with the metric ${\hat g}_{\mu\nu}= {g}_{\mu\nu}+B\partial_\mu\phi\partial_\nu\phi$. In the present universe the additional contribution from the scalar field in the metric ${\hat g}_{\mu\nu}$ can generate an…

General Relativity and Quantum Cosmology · Physics 2009-10-31 M. A. Clayton , J. W. Moffat

We estimate the gravitational wave spectra generated in strongly supercooled phase transitions by bubble collisions and fluid motion. We derive analytically in the thin-wall approximation the efficiency factor that determines the share of…

Cosmology and Nongalactic Astrophysics · Physics 2023-02-03 Marek Lewicki , Ville Vaskonen

The direct detection of gravitational waves (GWs) is an invaluable new tool to probe gravity and the nature of cosmic acceleration. A large class of scalar-tensor theories predict that GWs propagate with velocity different than the speed of…

General Relativity and Quantum Cosmology · Physics 2017-04-19 Dario Bettoni , Jose María Ezquiaga , Kurt Hinterbichler , Miguel Zumalacárregui

Theoretical approaches to strong field phenomena driven by plasmonic fields are based on the length gauge formulation of the laser-matter coupling. From the theoretical viewpoint it is known there exists no preferable gauge and consequently…

Atomic Physics · Physics 2015-12-30 A. Chacón , M. Lewenstein , M. F. Ciappina

Cascading gauge theories of Klebanov et.al. provide a model within a framework of gauge theory/string theory duality for a four dimensional non-conformal gauge theory with a spontaneously generated mass scale. Using the dual supergravity…

High Energy Physics - Theory · Physics 2008-11-26 Alex Buchel

We use numerical simulations to study the relation between the velocity of the Local Group and its gravitational acceleration. This relation serves as a test for the kinematic origin of the CMB dipole and as a method for estimating beta. We…

Astrophysics · Physics 2007-05-23 P. Ciecielag , M. Chodorowski , A. Kudlicki

We propose to "gauge" the group of similarity transformations that acts on a space of non-Hermitian scalar theories. We introduce the "similarity gauge field", which acts as a gauge connection on the space of non-Hermitian theories…

High Energy Physics - Theory · Physics 2022-05-03 Maxim N. Chernodub , Peter Millington

High-level vibrational calculations have been used to investigate anharmonicity in a wide variety of materials using density-functional-theory (DFT) methods. We have developed a new and efficient approach for describing strongly-anharmonic…

Materials Science · Physics 2017-06-20 Joseph C. A. Prentice , R. J. Needs

We show that the heating effect of spontaneous wave-function collapse models implies an experimentally significant increment $\Delta T$ of equilibrium temperature in a mechanical oscillator. The obtained form $\Delta T$ is linear in the…

Quantum Physics · Physics 2015-03-05 Lajos Diósi

Kohn-Sham Density Functional Theory (KS-DFT) has been traditionally solved by the Self-Consistent Field (SCF) method. Behind the SCF loop is the physics intuition of solving a system of non-interactive single-electron wave functions under…

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