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Basis sets of atomic orbitals are very efficient for density functional calculations but lack a systematic variational convergence. We present a variational method to optimize numerical atomic orbitals using a single parameter to control…

Condensed Matter · Physics 2009-11-07 E. Anglada , J. Soler , J. Junquera , E. Artacho

The electronic structure of solids can routinely be calculated by standard methods like density functional theory. However, in complicated situations like interfaces, grain boundaries or contact geometries one needs to resort to more…

Materials Science · Physics 2025-11-18 Henrik Dick , Thomas Dahm

Construction of hybrid atomic orbitals is proposed as the approximate common eigen states of finite first moment matrices. Their hybridization and orientation can be a-priori tunned as per their anticipated neighbourhood. Their Wannier…

Materials Science · Physics 2021-09-15 Manoar Hossain , Joydev De , Joydeep Bhattacharjee

Accurate, global Potential Energy Surfaces (PES) expressed in sum-of-products (SOP) form are a prerequisite for efficient high-dimensional quantum dynamics simulations using the MCTDH method. This work introduces a methodology for…

Chemical Physics · Physics 2026-03-31 Antoine Aerts

In this paper, we describe a numerical method to solve numerically the weakly dispersive fully nonlinear Serre-Green-Naghdi (SGN) celebrated model. Namely, our scheme is based on reliable finite volume methods, proven to be very effective…

Fluid Dynamics · Physics 2020-02-20 Gayaz Khakimzyanov , Denys Dutykh , Oleg Gusev , Nina Shokina

A construction of node-less atomic orbitals and energy-dependent, node-reduced partial waves is presented, that contains the full information of the atomic eigenstates and that allows to represent the scattering properties in a transparent…

Chemical Physics · Physics 2012-10-23 Peter E. Blöchl , Clemens Först

We propose the *State Space Neural Operator* (SS-NO), a compact architecture for learning solution operators of time-dependent partial differential equations (PDEs). Our formulation extends structured state space models (SSMs) to joint…

Machine Learning · Computer Science 2026-03-09 Nodens Koren , Samuel Lanthaler

We present a set of benchmark calculations for the Kohn-Sham elastic transmission function of five representative single-molecule junctions. The transmission functions are calculated using two different density functional theory (DFT)…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 M. Strange , I. S. Kristensen , K. S. Thygesen

In order to increase the accuracy of the linearized augmented plane wave method (LAPW) we present a new approach where the plane wave basis function is augmented by two different atomic radial components constructed at two different…

Materials Science · Physics 2015-12-10 A. V. Nikolaev , D. Lamoen , B. Partoens

We show that the algorithm based on the weighted essentially nonoscillatory (WENO) scheme with anti-diffusive flux corrections can be used as a solver of the radiative transfer equations. This algorithm is highly stable and robust for…

Astrophysics · Physics 2009-11-11 Jing-Mei Qiu , Chi-Wang Shu , Long-Long Feng , Li-Zhi Fang

We investigate a classical phase-space approach of matter-wave propagation based on the Truncated Wigner Equation (TWE). We show that such description is suitable for ideal matter waves in quadratic time-dependent confinement as well as for…

Quantum Gases · Physics 2015-05-19 François Impens , David Guéry-Odelin

To obtain convergent numerical approximations without using any orthogonalization operations is of great importance in electronic structure calculations. In this paper, we propose and analyze a class of iteration schemes for the discretized…

Numerical Analysis · Mathematics 2022-09-28 Xiaoying Dai , Liwei Zhang , Aihui Zhou

We present an accurate and efficient framework for real-space Hubbard-corrected density functional theory. In particular, we obtain expressions for the energy, atomic forces, and stress tensor suitable for real-space finite-difference…

Computational Physics · Physics 2025-10-20 Sayan Bhowmik , Andrew J. Medford , Phanish Suryanarayana

The combination of density functional theory with dynamical mean-field theory (DFT+DMFT) has become a powerful first-principles approach to tackle strongly correlated materials in condensed matter physics. The wide use of this approach…

Strongly Correlated Electrons · Physics 2022-05-10 Xin Qu , Peng Xu , Rusong Li , Gang Li , Lixin He , Xinguo Ren

We demonstrate that Daubechies wavelets can be used to construct a minimal set of optimized localized contracted basis functions in which the Kohn-Sham orbitals can be represented with an arbitrarily high, controllable precision. Ground…

The installed amount of renewable energy has expanded massively in recent years. Wave energy, with its high capacity factors has great potential to complement established sources of solar and wind energy. This study explores the problem of…

Neural and Evolutionary Computing · Computer Science 2019-12-17 Mehdi Neshat , Ehsan Abbasnejad , Qinfeng Shi , Bradley Alexander , Markus Wagner

Problems related to wavelength assignment (WA) in optical communications networks involve allocating transmission wavelengths for known transmission paths between nodes that minimize a certain objective function, for example, the total…

In this paper, we propose and analyze semi-implicit numerical schemes for the stochastic wave equation (SWE) with general nonlinearity and multiplicative noise. These numerical schemes, called stochastic scalar auxiliary variable (SAV)…

Numerical Analysis · Mathematics 2022-08-30 Jianbo Cui , Jialin Hong , Liying Sun

We present an efficient classical algorithm based on the construction of a unitary quantum circuit for simulating the Isotropic Wave Equation (IWE) in one, two, or three dimensions. Using an analogy with the massless Dirac equation, second…

Quantum Physics · Physics 2025-12-04 Kevin Lively , Vittorio Pagni , Gonzalo Camacho

We review the simple linear muffin-tin orbital method in the atomic-spheres approximation and a tight-binding representation (TB-LMTO-ASA method), and show how it can be generalized to an accurate and robust Nth order muffin-tin orbital…

Condensed Matter · Physics 2009-09-25 O. K. Andersen , T. Saha-Dasgupta , R. W. Tank , C. Arcangeli , O. Jepsen , G. Krier