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Motivated by recent experiments, we present a theoretical investigation of how the electro-osmotic flow occurring in a capillary is modified when its charged surfaces are coated by charged polymers. The theoretical treatment is based on a…

Mesoscale and Nanoscale Physics · Physics 2015-07-17 Umberto Marini Bettolo Marconi , Michele Monteferrante , Simone Melchionna

We consider the derivation and numerical solution of the flow of passive and active polar liquid crystals, whose molecular orientation is subjected to a tangential anchoring on an evolving curved surface. The underlying passive model is a…

Computational Physics · Physics 2019-01-18 Ingo Nitschke , Sebastian Reuther , Axel Voigt

Present paper reports, the structural, microstructural, electrical, dielectric properties and ion dynamics of a sodium based solid polymer electrolyte films comprising of PEO8-NaPF6+ x wt. % SN. The structural and surface morphology…

Materials Science · Physics 2018-07-12 Anil Arya , A. L. Sharma*

Salt transport in bulk electrolytes is limited by diffusion and convection, but in microstructures with charged surfaces (e.g. microfluidic devices, porous media, soils, or biological tissues) surface conduction and electro-osmotic flow…

Fluid Dynamics · Physics 2015-05-30 Ali Mani , Martin Z. Bazant

The ongoing scientific interest in the properties and structure of electric double layers (EDLs) stems from their pivotal role in (super)capacitive energy storage, energy harvesting, and water treatment technologies. Classical density…

Soft Condensed Matter · Physics 2016-04-28 Andreas Härtel , Sela Samin , Rene van Roij

In low-permeability rock, fluid and mineral transport occur in pores and fracture apertures at the scale of micrometers and below. At this scale, the presence of surface charge, and a resultant electrical double layer, may considerably…

Fluid Dynamics · Physics 2018-05-02 Asger Bolet , Gaute Linga , Joachim Mathiesen

Using molecular dynamics simulations we study the dynamics of a water-like TIP5P model of water in hydrophilic and hydrophobic confinement. We find that in case of extreme nanocofinement such that there is only one molecular layer of water…

Soft Condensed Matter · Physics 2010-05-14 Pradeep Kumar

Electrostatic interactions fundamentally govern the structure and transport of electrolytes. In concentrated electrolytes, however, electrostatic and steric correlations, together with ion-solvent coupling, give rise to complex behavior,…

Chemical Physics · Physics 2026-02-10 Daehyeok Kim , Taejin Kwon , Jeongmin Kim

Maxwell's models for viscoelastic flows are famous for their potential to unify elastic motions of solids with viscous motions of liquids in the continuum mechanics perspective. But rigorous proofs are lacking. The present note is a…

Analysis of PDEs · Mathematics 2022-12-21 Sébastien Boyaval

Electrohydrodynamics is crucial in many nanofluidic and biotechnological applications. In such small scales, the complexity due to the coupling of fluid dynamics with the dynamics of ions is increased by the relevance of thermal…

Fluid Dynamics · Physics 2022-01-19 Alberto Gubbiotti , Mauro Chinappi , Carlo Massimo Casciola

Non-equilibrium molecular dynamics (NEMD) simulations of fluid flow have highlighted the peculiarities of nanoscale flows compared to classical fluid mechanics; in particular, boundary conditions can deviate from the no-slip behavior at…

Soft Condensed Matter · Physics 2025-03-11 Giorgia Marcelli , Tecla Bottinelli Montandon , Roya Ebrahimi Viand , Felix Höfling

This work presents a theoretical and numerical study of electrokinetic flow and the zeta potential for the case of slit channels with nanoscale roughness of dimensions comparable to the Debye length, by employing molecular dynamics…

Fluid Dynamics · Physics 2020-08-03 Sijia Huang , Amir M. Rahmani , Troy Singletary , Carlos E. Colosqui

In the context of describing electrons in solids as a fluid in the hydrodynamic regime, we consider a flow of electrons in a channel of finite width, i.e.~a Poiseuille flow. The electrons are accelerated by a constant electric field. We…

Mesoscale and Nanoscale Physics · Physics 2018-12-05 Johanna Erdmenger , Ioannis Matthaiakakis , Rene Meyer , David Rodríguez Fernández

We present for the first time an experimental investigation of electrohydrodynamic (EHD) flows within a neutrally buoyant drop with initial radius of 2.25 mm. Utilizing particle image velocimetry (PIV) and high-speed shadowgraphy, we…

Fluid Dynamics · Physics 2025-02-19 Joel R. Karp , Bertrand Lecordier , Mostafa S. Shadloo

In this article we present a system of coupled non-linear PDEs modeling an anisotropic electrokinetic flow. We show the existence of suitable weak solutions in three spatial dimensions, that is weak solutions which fulfill an energy…

Analysis of PDEs · Mathematics 2024-07-30 Dietmar Hömberg , Robert Lasarzik , Luisa Plato

The surface of a polar liquid presents a special environment for the solvation and organization of charged solutes, which differ from bulk behaviors in important ways. These differences have motivated many attempts to understand…

Soft Condensed Matter · Physics 2022-06-07 Stephen J. Cox , Phillip L. Geissler

On the basis of a hydrodynamical model analogous to that in critical fluids, we investigate the influences of shear flow upon the electrostatic contribution to the viscosity of binary electrolyte solutions in the Debye-H\"{u}ckel…

Statistical Mechanics · Physics 2007-05-23 Hirofumi Wada

The rectification of electro-osmotic flows is important in micro/nano fluidics applications such as micro-pumps and energy conversion devices. Here, we propose a simple electro-osmotic diode in which colloidal particles are contained…

Mesoscale and Nanoscale Physics · Physics 2021-10-04 Shihori Koyama , Daisuke Inoue , Akihisa Okada , Hiroaki Yoshida

Molecular dynamics simulations have been performed on pure liquid water, aqueous solutions of sodium chloride, and polymer solutions exposed to a strong external electric field with the goal to gain molecular insight into the structural…

Soft Condensed Matter · Physics 2016-08-08 I. Nezbeda , J. Jirsák , F. Moučka , W. R. Smith

We present an efficient and robust numerical model for simulation of electrokinetic phenomena in porous networks over a wide range of applications including energy conversion, desalination, and lab-on-a-chip systems. Coupling between fluid…

Fluid Dynamics · Physics 2016-10-04 Shima Alizadeh , Ali Mani