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In spin crossover materials, an abrupt phase transition between a low spin state and a high spin state can be driven by temperature, pressure or by light irradiation. Of a special relevance are Fe(II) based coordination polymers where, in…

Despite a clear demonstration of bistability in spin-crossover (SCO) materials, the absence of long-range magnetic order and poor electrical conductivity limit their prospect in spintronic and nanoelectronic applications. Intending to…

X-ray magnetic circular dichroism at the Er M4,5 edge is used to study the switching behavior of the hard ErFe2 layers in an epitaxial [ErFe2(70{\AA})/YFe2 (150{\AA})]{\times}25 exchange-spring superlattice. Magnetic hysteresis loops for…

Using soft x-ray absorption spectroscopy and magnetic circular dichroism at the Co-$L_{2,3}$ edge we reveal that the spin state transition in LaCoO$_{3}$ can be well described by a low-spin ground state and a triply-degenerate high-spin…

Materials with spin-crossover (SCO) properties hold great potentials in information storage and therefore have received a lot of concerns in the recent decades. The hysteresis phenomena accompanying SCO is attributed to the intermolecular…

Chemical Physics · Physics 2022-10-11 Hong-zhou Ye , Chong Sun , Hong Jiang

Spin chirality provides a powerful route to control magnetic and topological phases in materials, enabling next-generation spintronic and quantum technologies. Coplanar noncollinear antiferromagnets with Kagome lattice spin geometries host…

A collective excitation of the spin structure in a magnetic insulator can transmit spin-angular momentum with negligible dissipation. This quantum of a spin wave, introduced more than nine decades ago, has always been manipulated through…

Rapidly developing science and technology demand new materials with versatile and promising properties for practical applications. In this context, pseudo-octahedral iron(II) spin crossover (SCO) complexes are particularly appealing - not…

We study a spin system with two- and four-spin exchange interactions on the triangular lattice, which is a possible model for the nuclear magnetism of solid $^3$He layers. It is found that a novel spin structure with scalar chiral order…

Condensed Matter · Physics 2009-10-30 Tsutomu Momoi , Kenn Kubo , Koji Niki

The interplay between chirality and magnetism has been a source of fascination among scientists for over a century. In recent years, chirality-induced spin selectivity (CISS) has attracted renewed interest. It has been observed that…

Mesoscale and Nanoscale Physics · Physics 2024-08-07 Mohammad Reza Safari , Frank Matthes , Claus M. Schneider , Karl-Heinz Ernst , Daniel E. Bürgler

We report high temperature synchrotron X-ray diffraction (SXRD), dc magnetization and current-voltage (I-V) characteristics for the samples of Co$_{2.75}$Fe$_{0.25}$O$_4$ ferrite. The material was prepared by chemical reaction of the Fe and…

Materials Science · Physics 2020-04-16 R. N. Bhowmik , P. D. Babu , A. K. Sinhac , Abhay Bhisikar

We present the first systematic observation of scaling of thermal hysteresis with the temperature scanning rate around an abrupt thermodynamic transition in correlated electron systems. We show that the depth of supercooling and…

Information can be stored in magnetic materials by encoding with the direction of the magnetic moment of elements. A figure of merit for these systems is the energy needed to change the information rewrite the storage by changing the…

Spin crossover (SCO) complexes are highly promising candidates for a myriad of potential applications in room-temperature electronics; however, as it stands, establishing a clear connection between their spin-state switching and transport…

Materials Science · Physics 2025-07-18 Archit Dhingra , M. Zaid Zaz

A microscopic model for the room-temperature multiferroic BiFeO$_3$ that includes two Dzyaloshinskii-Moriya interactions and single-ion anisotropy along the ferroelectric polarization predicts both the zero-field spectroscopic modes as well…

Strongly Correlated Electrons · Physics 2015-10-28 Randy S. Fishman , Jun Hee Lee , Sándor Bordács , István Kézsmárki , Urmas Nagel , Toomas Rõõm

This article describes a mean-field theoretical model for Spin-Crossover (SCO) materials and explores its implications. It is based on a simple Hamiltonian that yields the high spin molar fraction as a function of temperature and pressure,…

Materials Science · Physics 2023-04-12 Mario Reis , Yongqiang Cheng , Antonio M. dos Santos

In this letter, we report the structural, electronic and ferroelectric properties of the layered mixed-valent transition-metal compound, Sr$_{4}$Fe$_{6}$O$_{12}$ (SFO). We demonstrate how SFO undergoes a phase transition from a…

Strongly Correlated Electrons · Physics 2025-02-05 Arindam Sarkar , Hena Das , Prashant Singh , Aftab Alam

The antiferromagnetism in transition metal compounds is mostly mediated by the bridging anions through a so-called superexchange mechanism. However, in materials like normal spinels $AB_2X_4$ with local moments only at the $A$ site, such an…

Materials Science · Physics 2024-10-22 Liang-Wen Ji , Si-Qi Wu , Bai-Zhuo Li , Wu-Zhang Yang , Shi-Jie Song , Yi Liu , Jing Li , Zhi Ren , Guang-Han Cao

The crossover from localized- to itinerant-electron behavior is associated with many intriguing phenomena in condensed-matter physics. In this paper, we investigate the crossover from localized to itinerant regimes in the spinel system…

Strongly Correlated Electrons · Physics 2015-07-20 J. Ma , J. H. Lee , S. E. Hahn , Tao Hong , H. B. Cao , A. A. Aczel , Z. L. Dun , M. B. Stone , W. Tian , Y. Qiu , J. R. D. Copley , H. D. Zhou , R. S. Fishman , M. Matsuda

Here we propose a mechanism by which spin polarization can be generated dynamically in chiral molecular systems undergoing photo-induced electron transfer. The proposed mechanism explains how spin polarization emerges in systems where…

Mesoscale and Nanoscale Physics · Physics 2021-08-19 Thomas P. Fay , David T. Limmer
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