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All-perovskite tandem solar cells with narrow and wide bandgap perovskite absorbers are promising candidates for low-cost and high efficiency photovoltaic applications. However, the open circuit voltage of typical tandem structures is…

The optoelectronic properties of macromolecular semiconductors depend fundamentally on their solid-state microstructure. For example, the molecular-weight distribution influences polymeric- semiconductor properties via diverse…

Materials Science · Physics 2023-07-03 Francis Paquin , Jonathan Rivnay , Alberto Salleo , Natalie Stingelin , Carlos Silva

In developing photovoltaic devices with high efficiencies, quantitative determination of the carrier loss is crucial. In conventional solar-cell characterization techniques, however, photocurrent reduction originating from parasitic light…

Perovskite solar cells (PSCs) represent a breakthrough in photovoltaic technology, combining high power conversion efficiencies (PCEs), ease of fabrication, and tunable optoelectronic properties. However, their commercial viability is…

Materials Science · Physics 2025-06-30 Dilshod Nematov

Earlier reports demonstrated that ternary organic solar cells (OSC) made of donor polymers (D) blended with different mixtures of fullerene acceptors (A:A) performed very similarly. This finding is surprising, as the corresponding fullerene…

Applied Physics · Physics 2021-10-25 Andreas Sperlich , Michael Auth , Vladimir Dyakonov

The great progress in organic photovoltaics (OPV) over the past few years has been largely achieved by the development of non-fullerene acceptors (NFAs), with power conversion efficiencies now approaching 20%. To further improve device…

Nanowires have unique optical properties [1-4] and are considered as important building blocks for energy harvesting applications such as solar cells. [2, 5-8] However, due to their large surface-to-volume ratios, the recombination of…

Mesoscale and Nanoscale Physics · Physics 2011-05-26 Yaping Dan , Kwanyong Seo , Kuniharu Takei , Jhim H. Meza , Ali Javey , Kenneth B. Crozier

We used broadband local dielectric spectroscopy (BLDS), an electric force microscopy technique, to make non-contact measurements of conductivity in the dark and under illumination of PM6:Y6 and Y6 prepared on ITO and PEDOT:PSS/ITO. Over a…

Materials Science · Physics 2024-02-26 Rachael L. Cohn , Christopher A. Petroff , Virginia E. McGhee , John A. Marohn

A model is derived for the frequency- and time-domain opto-electronic response of perovskite solar cells (PSCs) that emphasizes the role of charge carrier exchange, .i.e. extraction and injection, from (to) the perovskite through the…

Materials Science · Physics 2023-11-10 Sandheep Ravishankar , Zhifa Liu , Yueming Wang , Thomas Kirchartz , Uwe Rau

Interplays between charge and electric field, which play a critical role in determining the charge transport, recombination, storage and hysteresis in the perovskite solar cell, have been systematically investigated by both electrical…

Materials Science · Physics 2017-10-31 Jiangjian Shi , Huiyin Zhang , Xin Xu , Dongmei Li , Yanhong Luo , Qingbo Meng

The separation of photogenerated polaron pairs in organic bulk heterojunction solar cells is the intermediate but crucial step between exciton dissociation and charge transport to the electrodes. In state-of-the-art devices, above 80% of…

Materials Science · Physics 2009-07-16 C. Deibel , T. Strobel , V. Dyakonov

We have developed and applied a mobility edge model that takes into account drift and diffusion currents to characterize the space charge limited current in organic semiconductors. The numerical solution of the drift-diffusion equation…

Materials Science · Physics 2015-05-30 Javier Dacuña , Alberto Salleo

Perovskite solar cells have shown remarkable efficiencies beyond 22%, through organic and inorganic cation alloying. However, the role of alkali-metal cations is not well-understood. By using synchrotron-based nano-X-ray fluorescence and…

The enhancement of the fill factor in the current generation of perovskite solar cells is the key for further efficiency improvement. Thus, methods to quantify the fill factor losses are urgently needed. A classical method to quantify Ohmic…

Applied Physics · Physics 2022-07-07 David Grabowski , Zhifa Liu , Gunnar Schöpe , Uwe Rau , Thomas Kirchartz

Metastable defects can decisively influence the diode factor and thus the efficiency of a solar cell. The diode factor is also influenced by the doping level and the recombination mechanisms in the solar cell. Here we quantify how the…

Applied Physics · Physics 2025-12-01 T. Wang , F. Ehre , T. P. Weiss , B. Veith-Wolf , V. Titova , N. Valle , M. Melchiorre , J. Schmidt , S. Siebentritt

Nanoscale investigations by scanning probe microscopy have provided major contributions to the rapid development of organic-inorganic halide perovskites (OIHP) as optoelectronic devices. Further improvement of device level properties…

We use a set of cosmological simulations combined with radiative transfer calculations to investigate the distribution of neutral hydrogen in the post-reionization Universe. We assess the contributions from the metagalactic ionizing…

Cosmology and Nongalactic Astrophysics · Physics 2013-08-27 Alireza Rahmati , Andreas H. Pawlik , Milan Raičević , Joop Schaye

While transient photoluminescence measurements are a very popular tool to monitor the charge-carrier dynamics in the field of halide perovskite photovoltaics, interpretation of data obtained on multilayer samples is highly challenging due…

Materials Science · Physics 2021-02-18 Lisa Krückemeier , Benedikt Krogmeier , Zhifa Liu , Uwe Rau , Thomas Kirchartz

Metal halide perovskite solar cells have gained widespread attention due to their high efficiency and high defect tolerance. The absorbing perovskite layer is as a mixed electron-ion conductor that supports high rates of ion and charge…

Using a representative translational dimer model, high throughput calculations are implemented for fast screening of a total of 74 diacenaphtho-extended heterocycle (DAH) derivatives as hole transport layer (HTL) materials in perovskite…