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We present a statistical model of a dilute polymer solution in good solvent in the presence of low-molecular weight cosolvent. We investigate the conformational changes of the polymer induced by a change of the cosolvent concentration and…

Statistical Mechanics · Physics 2014-11-10 Yu. A. Budkov , A. L. Kolesnikov , N. Georgi , M. G. Kiselev

We propose and study a model for the equilibrium statistical mechanics of a pressurised semiflexible polymer ring. The Hamiltonian has a term which couples to the algebraic area of the ring and a term which accounts for bending…

Statistical Mechanics · Physics 2009-11-13 Mithun K. Mitra , Gautam I. Menon , R. Rajesh

We review some recent coarse-graining and multi-scale methods, but also put forward some new ideas for addressing such issues. We find that, if one is guided by nonequilibrium statistical mechanics and thermodynamics, it is possible to…

Soft Condensed Matter · Physics 2009-11-06 Patrick Ilg , Vlasis Mavrantzas , Hans Christian Öttinger

Experimental observations and computer simulations have recently revealed universal aspects of polymer solution behaviour that were previously unknown. This progress has been made possible due to developments in experimental methodologies…

Soft Condensed Matter · Physics 2020-07-03 J. Ravi Prakash

Chain-like macromolecules (polymers) show characteristic adsorption properties due to their flexibility and internal degrees of freedom, when attracted to surfaces and interfaces. In this review we discuss concepts and features that are…

Soft Condensed Matter · Physics 2009-11-07 Roland Netz , David Andelman

The localization kinetics of a regular block-copolymer of total length $N$ and block size $M$ at a selective liquid-liquid interface is studied in the limit of strong segregation between hydrophobic and polar segments in the chain. We…

Soft Condensed Matter · Physics 2009-11-11 A. Corsi , A. Milchev , V. G. Rostiashvili , T. A. Vilgis

Motivated by the experiments on DNA under torsion, we consider the problem of pulling a polymer out of a potential well by a force applied to one of its ends. If the force is less than a critical value, then the process is activated and has…

Soft Condensed Matter · Physics 2009-10-31 K. L. Sebastian

We study how an active bath is transduced into the internal fluctuation spectrum of a semiflexible polymer. Starting from the statistics of active forces exerted by an explicit bath of active Brownian particles, we derive an effective…

Soft Condensed Matter · Physics 2026-04-14 Love Grover , Anil Kumar Dasanna , Abhishek Chaudhuri

We use thermodynamic perturbation theory to calculate the free energies and resulting phase diagrams of binary systems of spherical colloidal particles and interacting polymer coils in good solvent within an effective one-component…

Soft Condensed Matter · Physics 2009-11-10 B. Rotenberg , J. Dzubiella , J. -P. Hansen , A. A. Louis

Monte Carlo simulations have been performed to analyze the sub-diffusion dynamics of a tagged monomer in self-avoiding polymerized membranes in the flat phase. By decomposing the mean square displacement into the out-of-plane ($\parallel$)…

Soft Condensed Matter · Physics 2015-06-22 Ken-ichi Mizuochi , Hiizu Nakanishi , Takahiro Sakaue

We study the conformations of polymer chains in a poor solvent, with and without bending rigidity, by means of a simple statistical mechanics model. This model can be exactly solved for chains of length up to N=55 using exact enumeration…

Statistical Mechanics · Physics 2007-11-26 Anthony J. Guttmann , Jesper L. Jacobsen , Iwan Jensen , Sanjay Kumar

The dynamical scaling properties of selfavoiding polymerized membranes with internal dimension D are studied using model A dynamics. It is shown that the theory is renormalizable to all orders in perturbation theory and that the dynamical…

Condensed Matter · Physics 2009-10-30 Kay Joerg Wiese

The theory of the dynamics of polymers in solution is developed coming from the hydrodynamic theory of the Brownian motion (BM) and the Rouse-Zimm (RZ) model. It is shown that the time correlation functions describing the polymer motion…

Soft Condensed Matter · Physics 2007-05-23 V. Lisy , J. Tothova , B. Brutovsky , A. V Zatovsky

We use direct numerical simulations to study homogeneous, and isotropic turbulent flows of dilute polymer solutions at high Reynolds and Deborah numbers. We find that for small wavenumbers $k$, the kinetic energy spectrum shows…

Fluid Dynamics · Physics 2023-02-14 Marco E Rosti , Prasad Perlekar , Dhrubaditya Mitra

We derive a general mean-field theory of inhomogeneous polymer dynamics; a theory whose form has been speculated and widely applied, but not heretofore derived. Our approach involves a functional integral representation of a…

Soft Condensed Matter · Physics 2015-06-18 Glenn H. Fredrickson , Henri Orland

The dynamics of ring polymer melts are studied via molecular dynamics simulations of the Kremer-Grest bead-spring model. Rouse mode analysis is performed in comparison with linear polymers by changing the chain length. Rouse-like behavior…

Soft Condensed Matter · Physics 2021-09-23 Shota Goto , Kang Kim , Nobuyuki Matubayasi

The breakage of a polymer chain of segments, coupled by anharmonic bonds with applied constant external tensile force is studied by means of Molecular Dynamics simulation. We show that the mean life time of the chain becomes progressively…

Soft Condensed Matter · Physics 2015-05-27 J. Paturej , A. Milchev , V. G. Rostiashvili , T. A. Vilgis

The structure of a polystyrene matrix filled with tightly cross-linked polystyrene nanoparticles, forming an athermal nanocomposite system, is investigated by means of a Monte Carlo sampling formalism. The polymer chains are represented as…

Soft Condensed Matter · Physics 2014-01-17 Georgios G. Vogiatzis , Evangelos Voyiatzis , Doros N. Theodorou

We show that effective interactions mediated by disorder between two directed polymers can be modelled as the crosscorrelation of noises in the Kardar-Parisi-Zhang (KPZ) equations satisfied by the respective free energies of these polymers.…

Condensed Matter · Physics 2009-10-31 Abhik Basu

This work investigates the effects of tangent polar activity on the conformational and dynamic properties of entangled polymer melts through Langevin molecular dynamics simulations. We examine systems composed of all self-propelled,…

Soft Condensed Matter · Physics 2024-11-19 Javier Oller-Iscar , Andrés R. Tejedor , Marisol Ripoll , Jorge Ramírez
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