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The kinetic theory for a fluid of hard spheres which undergo endothermic and/or exothermic reactions with mass transfer is developed. The exact balance equations for concentration, density, velocity and temperature are derived. The Enskog…

Statistical Mechanics · Physics 2007-05-23 James F. Lutsko

The aim of this work is to analyze the entropy, entropy flux and entropy supply rate of granular fluids within the frameworks of the Boltzmann equation and continuum thermodynamics. It is shown that the entropy inequality for a granular gas…

Statistical Mechanics · Physics 2010-11-17 Gilberto M. Kremer

The general Ericksen-Leslie system for the flow of nematic liquid crystals is reconsidered in the non-isothermal case aiming for thermodynamically consistent models. The non-isothermal model is then investigated analytically. A fairly…

Analysis of PDEs · Mathematics 2015-04-07 Matthias Hieber , Jan Pruess

We propose a model describing Seebeck effect on a weak link between two quantum systems with fine-tunable ground states of Fermi and Non-Fermi liquid origin. The experimental realization of the model can be achieved by utilizing the quantum…

Mesoscale and Nanoscale Physics · Physics 2018-02-06 T. K. T. Nguyen , M. N. Kiselev

Water-in-Salt-Electrolytes (WiSEs) are a promising class of next-generation electrolytes. Unlike classical dilute electrolytes or more conventional battery electrolytes, WiSEs are characterised by their super-concentrated salt concentration…

How magnetism affects the Seebeck effect is an important issue widely concerned in the thermoelectric community yet remaining elusive. Based on a thermodynamic analysis of spin degrees of freedom on varied $d$-electron based ferro- and…

Materials Science · Physics 2021-06-15 Peijie Sun , K. Ramesh Kumar , Meng Lyu , Zhen Wang , Junsen Xiang , Wenqing Zhang

A generally relativistic theory of thermodynamics is developed, based on four main physical principles: heat is a local form of energy, therefore described by a thermal energy tensor; conservation of mass, equivalent to conservation of…

General Relativity and Quantum Cosmology · Physics 2007-05-23 Sean A. Hayward

The static dielectric constant of liquid water is computed using classical force field based molecular dynamics simulation at fixed electric displacement D. The method to constrain the electric displacement is the finite temperature…

Chemical Physics · Physics 2016-04-07 Chao Zhang , Michiel Sprik

The Stokes-Einstein relation (SER) is one of the most robust and widely employed results from the theory of liquids. Yet sizable deviations can be observed for self-solvation, which cannot be explained by the standard hydrodynamic…

Statistical Mechanics · Physics 2018-06-15 Benoit Charbonneau , Patrick Charbonneau , Grzegorz Szamel

An inhomogeneous electric field is used to study the deflection of a supersonic beam of water molecules. The deflection profiles show strong broadening accompanied by a small net displacement towards higher electric fields. The profiles are…

Chemical Physics · Physics 2009-11-13 Ramiro Moro , Jaap Bulthuis , Jonathon Heinrich , Vitaly V. Kresin

Poisson-Boltzmann (PB) theory is the classic approach to soft matter electrostatics which has been applied to numerous problems of physical chemistry and biophysics. Its essential limitations are the neglect of correlation effects and of…

Soft Condensed Matter · Physics 2016-08-03 Sahin Buyukdagli , Ralf Blossey

The Seebeck coefficient, which is proportional to a ratio of the thermoelectric conductivity to electrical conductivity has been examined for Dirac electrons in the organic conductor $\alpha$-(BEDT-TTF)$_2$I$_3$ [BEDT-TTF denotes a molecule…

Materials Science · Physics 2023-05-11 Yoshikazu Suzumura , Masao Ogata

Topological Insulators are the best thermoelectric materials involving a sophisticated physics beyond their solid state and electronic structure. We show that exists a topological contribution to the thermoelectric effect that arise between…

Mesoscale and Nanoscale Physics · Physics 2019-04-24 Daniel Baldomir , Daniel Faílde

We study diffusive mixing in the presence of thermal fluctuations under the assumption of large Schmidt number. In this regime we obtain a limiting equation that contains a diffusive thermal drift term with diffusion coefficient obeying a…

Statistical Mechanics · Physics 2015-06-18 A. Donev , T. G. Fai , E. Vanden-Eijnden

A generalization of the Gibbs entropy postulate is proposed based on the BBGKY hierarchy as the nonequilibrium entropy for a system of N interacting particles. This entropy satisfies the basic principles of thermodynamics in the sense that…

Statistical Mechanics · Physics 2007-05-23 A. Perez-Madrid

We present the perturbative solution of the multicomponent Boltzmann kinetic equation based on the set of observables including the hydrodynamic velocity and temperature for each component. The solution is obtained by modifying the formal…

Statistical Mechanics · Physics 2008-01-23 S. V. Savenko , E. A. J. F. Peters , P. J. A. M. Kerkhof

Using recently developed consistent and robust first order relativistic hydrodynamics of a dissipative fluid we propose a generalization but weak version of Tolman-Ehrenfest relation and Klein's law on a general background spacetime. These…

General Relativity and Quantum Cosmology · Physics 2024-12-02 Bhera Ram , Bibhas Ranjan Majhi

A comprehensive, semi-quantitative model for the thermodynamics of hydrophobic solvation is presented. The model is based on a very simple premise suggested by the scaled particle theory and treats both solute and solvent molecules as hard…

Biological Physics · Physics 2007-05-23 Hong Qian

Fluid dynamics accompanies with the entropy production thus increases the local temperature, which plays an important role in charged systems such as the ion channel in biological environment and electrodiffusion in capacitors/batteries. In…

Fluid Dynamics · Physics 2017-11-09 Pei Liu , Simo Wu , Chun Liu

We present the first thermoelectric measurements on pentacene field effect transistors. We report high values of the Seebeck coefficient at room temperature between 240 and 500 micro V/K depending on the dielectric surface treatment. These…

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