Related papers: Synchronous Tunneling in a Multidimensional Quarti…
Coupled instantons are introduced by generalizing the double well potential to multiple mutually coupled wells. Physically this corresponds to the simultaneous tunneling of multiple degrees of freedom. A system with four equal minima is…
We consider quantum tunnelling in asymmetric double-well systems for which the local minima in the two wells have the same energy, but the frequencies differ slightly. We derive a generalization of instanton theory for these asymmetric…
We present a path - integral approach to treat a 2D model of a quantum bifurcation. The model potential has two equivalent minima separated by one or two saddle points, depending on the value of a continuous parameter. Tunneling is…
The combination of transfer learning (TL) a low level potential energy surface (PES) to a higher level of electronic structure theory together with ring-polymer instanton (RPI) theory is explored and applied to malonaldehyde. The RPI…
Instanton methods, in which imaginary-time evolution gives the tunneling rate, have been widely used for studying quantum tunneling in various contexts. Nevertheless, how accurate instanton methods are for the problems of macroscopic…
We consider the cosmological model of a self-interacting $\phi^4 - \phi^2$ quantum scalar field and extend our previous results, [3], on resonant tunneling and consequent particle production, to the case of finite temperature. Using the…
We develop a new simulation technique based on path-integral molecular dynamics for calculating ground-state tunneling splitting patterns from ratios of symmetrized partition functions. In particular, molecular systems are rigorously…
Instanton theory has arisen as a practical tool for calculating tunneling splittings in molecular systems. Unfortunately, the original formulation of instanton theory fundamentally breaks down when trying to calculate the level splitting in…
This article presents a review on the theoretical and the experimental developments on macroscopic quantum tunneling and phase transition of the escape rate in spin systems. We present the basic ideas with simplified calculations so that it…
The tunneling decay event of a metastable state in a fully connected quantum spin model can be simulated efficiently by path integral quantum Monte Carlo (QMC) [Isakov $et~al.$, Phys. Rev. Lett. ${\bf 117}$, 180402 (2016).]. This is because…
Within the framework of the instanton approach we present analytical results for the following model problems: (i) particle penetration through a parabolic potential barrier, where the instanton solution practically coincides with the exact…
We discuss quantum tunneling between classically BPS saturated solitons in two-dimensional theories with N=2 supersymmetry and a compact space dimension. Genuine BPS states form shortened multiplets of dimension two. In the models we…
The ring-polymer instanton approach is applied to compute the ground-state tunnelling splitting of four isotopomers of the formic acid dimer using the accurate PES of Qu and Bowman [Phys. Chem. Chem. Phys., 2016, 18, 24835]. As well as…
We analyze the (de)localization properties of a quasi-exactly solvable (QES) sextic potential $V_{\text{QES}}(x) = \frac{1}{2}(x^6 + 2x^4 - 2(2\lambda + 1)x^2)$ as a function of the tunable parameter $\lambda \in [-\frac{3}{4}, 6]$. For…
Spin coherent state path integrals with discontinuous semiclassical paths are investigated with special reference to a realistic model for the magnetic degrees of freedom in the Fe8 molecular solid. It is shown that such paths are essential…
We develop an instantonic calculus to derive an analytical expression for the thermally-assisted tunneling decay rate of a metastable state in a fully connected quantum spin model. The tunneling decay problem can be mapped onto the Kramers…
In part I, we presented the ring-polymer instanton with explicit friction (RPI-EF) method and showed how it can be connected to the \textit{ab initio} electronic friction formalism. This framework allows the calculation of tunneling…
We compute tunneling in a quantum field theory in 1+1 dimensions for a field potential $U(\Phi)$ of the asymmetric double well type. The system is localized initially in the ``false vacuum''. We consider the case of a {\em compact space}…
Quantum phase transitions (QPTs) in the spin-boson model with/without the rotating-wave approximation (RWA) are systematically investigated through variational calculations using a sub-Ohmic bath with high spectral density. Four cases…
We investigate a novel stochastic technique for the global optimization of complex potential energy surfaces (PES) that avoids the freezing problem of simulated annealing by allowing the dynamical process to tunnel energetically…