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Using seven semiconductors/insulators with band gaps covering the range from 1 eV to 10 eV we systematically explore the performance of two different variants of self-consistency associated with famous Hedin's system of equations: the full…

Materials Science · Physics 2022-01-20 Andrey L. Kutepov

The detailed atomic structure of quasicrystals has been an open question for decades. Here, we present a quasilattice-conserved optimization method (quasiOPT), with particular quasiperiodic boundary conditions. As the atomic coordinates…

Materials Science · Physics 2015-06-23 Xiao-Tian Li , Xiao-Bao Yang , Yu-Jun Zhao

In this contribution we present a protocol to evaluate partial and total Auger decay rates combining the restricted active space self-consistent field electronic structure method for the bound part of the spectrum and numerically obtained…

Chemical Physics · Physics 2019-10-30 Gilbert Grell , Oliver Kühn , Sergey I. Bokarev

We present a new, all-electron implementation of the GW approximation and apply it to wurtzite ZnO. Eigenfunctions computed in the local-density approximation (LDA) by the full-potential linearized augmented-plane-wave (LAPW) or the…

Materials Science · Physics 2009-11-07 Manabu Usuda , Noriaki Hamada , Takao Kotani , Mark van Schilfgaarde

For the recent GW100 test set of molecular ionization energies, we present a comprehensive assessment of different GW methodologies: fully self-consistent GW (scGW), quasiparticle self-consistent GW (qsGW), partially self-consistent GW0…

Chemical Physics · Physics 2018-05-17 Fabio Caruso , Matthias Dauth , Michiel J. van Setten , Patrick Rinke

We present a detailed study of local and non-local correlations in the electronic structure of elemental transition metals carried out by means of the Quasiparticle Self-consistent GW (QSGW ) and Dynamical Mean Field Theory (DMFT). Recent…

Strongly Correlated Electrons · Physics 2017-02-01 L. Sponza , P. Pisanti , A. Vishina , S. Acharya , D. Pashov , J. Vidal , C. Weber , G. Kotliar , M. van Schilfgaarde

A novel approach for GW-based calculations of quasiparticle properties for finite systems is presented, in which the screened interaction is obtained directly from a linear response calculation of the density-density correlation function.…

Strongly Correlated Electrons · Physics 2015-05-13 George Pal , Yaroslav Pavlyukh , Hans Christian Schneider , Wolfgang Huebner

Physical implementation of Quantum Information Processing (QIP) by liquid-state Nuclear Magnetic Resonance (NMR), using weakly coupled spin-1/2 nuclei of a molecule, is well established. Nuclei with spin$>$1/2 oriented in liquid crystalline…

Quantum Physics · Physics 2009-11-10 Ranabir Das , Anil Kumar

Within the framework of many-body perturbation theory based on Green's functions, the $GW$ approximation has emerged as a pivotal method for computing quasiparticle energies and excitation spectra. However, its high computational cost and…

Chemical Physics · Physics 2025-12-25 Yueyang Zhang , Wei Wu , Peifeng Su

By recasting the non-linear frequency-dependent $GW$ quasiparticle equation into a linear eigenvalue problem, we explain the appearance of multiple solutions and unphysical discontinuities in various physical quantities computed within the…

Chemical Physics · Physics 2022-06-16 Enzo Monino , Pierre-François Loos

We present a Kernel Ridge Regression (KRR) based supervised learning method combined with Genetic Algorithms (GAs) for the calculation of quasiparticle energies within Many-Body Green's Functions Theory. These energies representing…

Computational Physics · Physics 2020-12-04 Gianluca Tirimbó , Onur Çaylak , Björn Baumeier

Using multiwavelets, we have obtained total energies and corresponding atomization energies for the GGA-PBE and hybrid-PBE0 density functionals for a test set of 211 molecules with an unprecedented and guaranteed $\mu$Hartree accuracy.…

We introduce an algorithm based on Generalized Dual Method (GDM) to efficiently study the dynamics of a particle in quasiperiodic environments without the need to use periodic approximations or to save the information of the vertices that…

Chaotic Dynamics · Physics 2022-04-28 Alan Rodrigo Mendoza Sosa , Atahualpa S. Kraemer

The GW self-energy method has long been recognized as the gold standard for quasiparticle (QP) calculations of solids in spite of the fact that the neglect of vertex corrections and the use of a DFT starting point lacks rigorous…

Materials Science · Physics 2017-12-06 Per S. Schmidt , Christopher E. Patrick , Kristian S. Thygesen

Determining the properties of molecules and materials is one of the premier applications of quantum computing. A major question in the field is how to use imperfect near-term quantum computers to solve problems of practical value. Inspired…

We report on the importance of GW self-energy corrections for the electronic structure of light actinides in the weak-to-intermediate coupling regime. Our study is based on calculations of the band structure and total density of states of…

Strongly Correlated Electrons · Physics 2014-05-15 Towfiq Ahmed , R. C. Albers , A. V. Balatsky , C. Friedrich , Jian-Xin Zhu

A quasi-equilibrium (QE) computational scheme was recently developed in general relativity to calculate the complete gravitational wavetrain emitted during the inspiral phase of compact binaries. The QE method exploits the fact that the the…

General Relativity and Quantum Cosmology · Physics 2009-10-31 Hwei-Jang Yo , Thomas W. Baumgarte , Stuart L. Shapiro

Nuclear quantum phenomena beyond the Born-Oppenheimer approximation are known to play an important role in a growing number of chemical and biological processes. While there exists no unique consensus on a rigorous and efficient…

The emergence of machine learning methods in quantum chemistry provides new methods to revisit an old problem: Can the predictive accuracy of electronic structure calculations be decoupled from their numerical bottlenecks? Previous attempts…

Computational Physics · Physics 2020-08-26 M. Gastegger , A. McSloy , M. Luya , K. T. Schütt , R. J. Maurer

Quasiparticle spectra of potentially half-metallic Co2MnSi and Co2FeSi Heusler compounds have been calculated within the one-shot GW approximation in an all-electron framework without adjustable parameters. For Co2FeSi the many-body…

Materials Science · Physics 2013-01-04 Markus Meinert , Christoph Friedrich , Günter Reiss , Stefan Blügel