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Chemical bonding in molecules and solids arises from the overlap of valence electron wave functions, forming extended molecular orbitals and dispersing Bloch states, respectively. Core electrons with high binding energies, on the other…

Materials Science · Physics 2010-08-10 S. Lizzit , G. Zampieri , L. Petaccia , R. Larciprete , P. Lacovig , E. D. L. Rienks , A. Baraldi , Ph. Hofmann

We present an ab-initio density function theory to investigate the electronic and magnetic structures of the bilayer graphene with intercalated atoms C, N, and O. The intercalated atom although initially positioned at the middle site of the…

Materials Science · Physics 2010-01-07 S. J. Gong , W. Sheng , Z. Q. Yang , J. H. Chu

Graphene, a 2-dimensional monolayer form of sp2 hybridizated carbon atoms, is attracting increasing attention due to its unique and superior physicochemical properties. Covalently functionalized graphene layers, with their modifiable…

Materials Science · Physics 2014-08-11 Karolina Z. Milowska , Jacek A. Majewski

The intercalation of an oxide barrier between graphene and its metallic substrate for chem- ical vapor deposition is a contamination-free alternative to the transfer of graphene to dielectric supports, usually needed for the realization of…

Graphite is a well-studied material with known electronic and optical properties. Graphene, on the other hand, which is just one layer of carbon atoms arranged in a hexagonal lattice, has been studied theoretically for quite some time but…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 F. Molitor , D. Graf , C. Stampfer , T. Ihn , K. Ensslin

Annealing the Ru metal that typically contains residual carbon impurities offers a facile way to grow graphene on Ru(0001) at the macroscopic scale. Two superstructures of the graphene/Ru(0001) interface with periodicities of 3.0-nm and…

Materials Science · Physics 2011-11-09 De-en Jiang , Mao-Hua Du , Sheng Dai

Controlled defect creation is a prerequisite for the detailed study of disorder effects in materials. Here, we irradiate a graphene/Ir(111)-interface with low-energy Ar+ to study the induced structural changes. Combining computer…

Materials Science · Physics 2013-11-01 E. H. Åhlgren , S. K. Hämäläinen , O. Lehtinen , P. Liljeroth , J. Kotakoski

A number of interesting properties of graphene and graphite are postulated to derive from the peculiar bandstructure of graphene. This bandstructure consists of conical electron and hole pockets that meet at a single point in momentum (k)…

Strongly Correlated Electrons · Physics 2007-05-23 Aaron Bostwick , Taisuke Ohta , Thomas Seyller , K. Horn , Eli Rotenberg

Silicon represents a common intrinsic impurity in graphene, commonly bonding to either three or four carbon neighbors respectively in a single or double carbon vacancy. We investigate the effect of the latter defect (Si-C$_4$) on the…

Experimental and theoretical studies of manganese deposition on graphene/Ni(111) shows that a thin ferromagnetic Ni3Mn layer, which is protected by the graphene overlayer, is formed upon Mn intercalation. The electronic bands of graphene…

Electrons most often organize into Fermi-liquid states in which electron-electron interactions play an inessential role. A well known exception is the case of one-dimensional (1D) electron systems (1DES). In 1D the electron Fermi-surface…

Strongly Correlated Electrons · Physics 2010-01-09 Fan Zhang , Hongki Min , Marco Polini , A. H. MacDonald

We investigate the electronic band structure and transport properties of periodically alternating mono- and bi-layer graphene superlattices (MBLG SLs). In such MBLG SLs, there exists a zero-averaged wave vector (zero-$\overline{k}$) gap…

Materials Science · Physics 2015-12-22 Xiong Fan , Wenjun Huang , Tianxing Ma , Li-Gang Wang , Hai-Qing Lin

Epitaxial growth of graphene on transition metal substrates is an important route for obtaining large scale graphene. However, the interaction between graphene and the substrate often leads to multiple orientations, distorted graphene band…

The modular nature and unique electronic properties of two-dimensional (2D) covalent organic frameworks (COFs) make them an attractive option for applications in catalysis, optoelectronics, and spintronics. The fabrications of such devices…

Materials Science · Physics 2021-04-15 Joseph Frimpong , Zhen-Fei Liu

Supercapacitors store energy via the formation of an electric double layer, which generates a strong electric field at the electrode-electrolyte interface. Unlike conventional metallic electrodes, graphene-derived materials suffer from a…

Materials Science · Physics 2015-03-12 Maxwell D. Radin , Tadashi Ogitsu , Minoru Otani , Juergen Biener , Brandon C. Wood

The 1+1 layer folded graphene sheets that deviate from AB stacking are successfully fabricated and their electronic structures are investigated by Raman spectroscopy. Significant blue shift of the 2D band of folded graphene compared to that…

Materials Science · Physics 2009-11-13 Zhenhua Ni , Yingying Wang , Ting Yu , Yumeng You , Zexiang Shen

We study the electronic and transport properties of a graphene-based superlattice theoretically by using an effective Dirac equation. The superlattice consists of a periodic potential applied on a single-layer graphene deposited on a…

Mesoscale and Nanoscale Physics · Physics 2015-02-26 Jonas R. F. Lima

Graphene grown by chemical vapor deposition and supported on SiO2 and sapphire substrates was studied following controlled introduction of defects induced by 35 keV carbon ion irradiation. Changes in Raman spectra following fluences ranging…

$\alpha$-graphyne is a two-dimensional sheet of $sp$-$sp^2$ hybridized carbon atoms in a honeycomb lattice. While the geometrical structure is similar to that of graphene, the hybridized triple bonds give rise to electronic structure that…

Materials Science · Physics 2017-08-04 Hyeondeok Shin , Jeongnim Kim , Hoonkyung Lee , Olle Heinonen , Anouar Benali , Yongkyung Kwon

We present a semi-analytical model of the resonance phenomena occurring in a hybrid system made of a 1D array of periodic subwavelength slits deposited on an insulator/graphene layer. We show that the spectral response of this hybrid system…