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The present manuscript revisits one of the earliest approaches to treating molecular systems within the Schr\"odinger formalism of quantum mechanics: the Heitler-London (HL) model. Originally proposed in 1927 and based on a linear…

Chemical Physics · Physics 2025-11-12 Washington P. da Silva , Daniel Vieira , Jonas Maziero , Edgard P. M. Amorim

The calculation of thermodynamic properties of biochemical systems typically requires the use of resource-intensive molecular simulation methods. One example thereof is the thermodynamic profiling of hydration sites, i.e. high-probability…

Biomolecules · Quantitative Biology 2020-01-08 Ahmadreza Ghanbarpour , Amr H. Mahmoud , Markus A. Lill

The interface between hemoglobin (Hb) and its environment, in particular water, is of great physiological relevance. Here, results from {\it in vitro}, {\it in vivo}, and computational experiments (molecular dynamics simulations) are…

Chemical Physics · Physics 2021-10-08 Markus Meuwly , Martin Karplus

Artificial hydrocarbon networks (AHN) is a novel supervised learning method inspired on the structure and the inner chemical mechanisms of organic compounds. As any other cutting-edge algorithm, there are two challenges to be faced:…

Machine Learning · Computer Science 2020-05-22 Jose Roberto Ayala-Solares , Hiram Ponce

Polymers contain functional groups that participate in hydrogen bond (H-bond) with water molecules, establishing a robust H-bond network that influences bulk properties. This study utilized molecular dynamics (MD) simulations to examine the…

Soft Condensed Matter · Physics 2023-05-02 Kokoro Shikata , Takuma Kikutsuji , Nobuhiro Yasoshima , Kang Kim , Nobuyuki Matubayasi

The recombination of hydrogen in the interstellar medium, taking place on surfaces of microscopic dust grains, is an essential process in the evolution of chemical complexity in interstellar clouds. The H_2 formation process has been…

Condensed Matter · Physics 2009-11-07 Ofer Biham , Azi Lipshtat

Predicting which proteins interact together from amino-acid sequences is an important task. We develop a method to pair interacting protein sequences which leverages the power of protein language models trained on multiple sequence…

Biomolecules · Quantitative Biology 2024-12-30 Umberto Lupo , Damiano Sgarbossa , Anne-Florence Bitbol

RNA 3D architectures are stabilized by sophisticated networks of (non-canonical) base pair interactions, which can be conveniently encoded as multi-relational graphs and efficiently exploited by graph theoretical approaches and recent…

Quantitative Methods · Quantitative Biology 2022-06-03 Vincent Mallet , Carlos Oliver , Jonathan Broadbent , William L. Hamilton , Jérôme Waldispühl

Background: It is necessary and essential to discovery protein function from the novel primary sequences. Wet lab experimental procedures are not only time-consuming, but also costly, so predicting protein structure and function reliably…

Quantitative Methods · Quantitative Biology 2017-03-09 Quan Zou , Shixiang Wan , Ying Ju , Jijun Tang , Xiangxiang Zeng

Persistent homology theory is a relatively new but powerful method in data analysis. Using simplicial complexes, classical persistent homology is able to reveal high dimensional geometric structures of datasets, and represent them as…

Algebraic Topology · Mathematics 2023-12-05 Yaru Gao , Yan Xu , Fengchun Lei

We explore the consequences of very high dimensionality in the dynamical landscape of protein folding. Consideration of both typical range of stabilising interactions, and folding rates themselves, leads to a model of the energy…

Biological Physics · Physics 2007-05-23 T. C. B. McLeish

The prototypical Hydrogen bond in water dimer and Hydrogen bonds in the protonated water dimer, in other small molecules, in water cyclic clusters, and in ice, covering a wide range of bond strengths, are theoretically investigated by…

Chemical Physics · Physics 2017-08-02 Pier Luigi Silvestrelli

Grate and co-workers at Pacific Northwest National Laboratory recently developed high information content triazine-based sequence-defined polymers that are robust by not having hydrolyzable bonds and can encode structure and functionality…

Chemical Physics · Physics 2019-07-31 Surl-Hee Ahn , Jay W. Grate , Eric F. Darve

We introduce NetworKit, an open-source software package for analyzing the structure of large complex networks. Appropriate algorithmic solutions are required to handle increasingly common large graph data sets containing up to billions of…

Social and Information Networks · Computer Science 2015-11-16 Christian L. Staudt , Aleksejs Sazonovs , Henning Meyerhenke

Bodge is a free and open-source Python package for constructing large-scale real-space tight-binding models for calculations in condensed matter physics. "Large-scale" means that it should remain performant even for lattices with millions…

Superconductivity · Physics 2024-10-14 Jabir Ali Ouassou

Hyaluronan, a sugar polymer found outside the plasma membrane, is a critical component of the extracellular matrix (ECM) scaffold. Hyaluronan's length and moderate negative charge aid in ECM entanglement and solubility. This allows it to…

Chemical Physics · Physics 2023-04-04 Miguel Riopedre , Denys Biriukov , Martin Dračínský , Hector Martinez-Seara

Functional protein-protein interactions are crucial in most cellular processes. They enable multi-protein complexes to assemble and to remain stable, and they allow signal transduction in various pathways. Functional interactions between…

Biomolecules · Quantitative Biology 2018-11-14 Anne-Florence Bitbol

We present an extension of the Poisson-Boltzmann model in which the solute of interest is immersed in an assembly of self-orienting Langevin water dipoles, anions, cations, and hydrophobic molecules, all of variable densities. Interactions…

Biological Physics · Physics 2021-04-08 Patrice Koehl , Marc Delarue , Henri Orland

Interactive molecular graphics applications facilitate analysis of three dimensional protein structures. Naturally, non-interactive 2-D snapshots of the protein structures do not convey the same level of geometric detail. Several 2-D…

Quantitative Methods · Quantitative Biology 2014-02-24 Francis Bell , Chunyu Zhao , Ahmet Sacan

Protein phosphorylation involves the reversible modification of a protein (substrate) residue by another protein (kinase). Liquid chromatography-mass spectrometry studies are rapidly generating massive protein phosphorylation datasets…

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