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We discuss how x-ray Compton scattering spectra can be used for investigating the evolution of electronic states in cathode materials of Li batteries under the lithiation/delithiation process. In particular, our analysis of the Compton…

Lithium-ion batteries (LIBs) have become essential in modern energy storage; however, their performance is often limited by the stability and efficiency of their components, particularly the cathode and electrolyte. Transition metal layered…

Materials Science · Physics 2025-07-15 M. D. Hashan C. Peiris , Michael Woodcox , Diana Liepinya , Robert Shepard , Hao Liu , Manuel Smeu

The reliability, lower computational complexity, and ease of implementation of control observers make them one of the most promising methods for the state estimation of Li-ion batteries (LIBs) in commercial applications. To pave their way,…

Systems and Control · Electrical Eng. & Systems 2024-12-03 Muhammad Saeed , Arash Khalatbarisoltani , Zhongwei Deng , Wenxue Liu , Faisal Altaf , Shuai Lu , Xiaosong Hu

Recently, considerable efforts have been made on research and improvement for Ni-rich lithium-ion batteries to meet the demand from vehicles and grid-level large-scale energy storage. Development of next-generation high-performance…

This work presents a comparative study of optimization techniques for parameter identification in equivalent electrical models of lithium-ion batteries. The 2RC model is applied to a set of twelve batteries using four publicly available…

Optimization and Control · Mathematics 2025-12-03 Johan Sebastian Suarez Sepúlveda , Edgar Hernando Sepúlveda-Oviedo , Bruno Jammes , Corinne Alonso

We have studied the electronic structure of Li$_{1+x}$[Mn$_{0.5}$Ni$_{0.5}$]$_{1-x}$O$_2$ ($x$ = 0.00 and 0.05), one of the promising cathode materials for Li ion battery, by means of x-ray photoemission and absorption spectroscopy. The…

Strongly Correlated Electrons · Physics 2015-07-28 Y. Yokoyama , D. Ootsuki , T. Sugimoto , H. Wadati , J. Okabayashi , Xu Yang , Fei Du , Gang Chen , T. Mizokawa

Rechargeable lithium metal batteries (LMBs) with an ultrahigh theoretical energy density have attracted more and more attentions for their crucial applications of portable electronic devices, electric vehicles, and smart grids. However, the…

Materials Science · Physics 2024-10-22 Yanchen Fana , Xiang Chenb , Dominik Legut , Qianfan Zhang

Energy storage technologies that can meet the unprecedented demands of a sustainable energy system based on intermittent energy sources require new battery materials. We investigate high ionic conductors, Li$_3$ClO glasses. In the present…

Materials Science · Physics 2021-04-09 Young Won Choi , Moyses Araujo , Levente Vitos , Raquel Lizárraga

This contribution presents a diagnosis scheme for batteries to detect and isolate internal faults in the form of small parameter changes. This scheme is based on an electrochemical reduced-order model of the battery, which allows the…

Systems and Control · Electrical Eng. & Systems 2021-03-19 Luis D. Couto , Jorn M. Reniers , David A. Howey , Michel Kinnaert

Li metal has been deposited on the surface of a Ru(0001) single crystal containing patches of monolayer-thick epitaxial graphene islands. The use of low-energy electron microscopy and diffraction allowed us to {\em in situ} monitor the…

Monitoring the health of lithium-ion batteries' internal components as they age is crucial for optimizing cell design and usage control strategies. However, quantifying component-level degradation typically involves aging many cells and…

Computational Engineering, Finance, and Science · Computer Science 2024-04-09 Sina Navidi , Adam Thelen , Tingkai Li , Chao Hu

Thick Li-ion battery electrodes with high ion transport rates could enable batteries that cost less and that have higher gravimetric and volumetric energy density, because they require fewer inactive cell-components. Finding ways to…

Materials Science · Physics 2015-05-14 V. Pavan Nemani , Stephen J. Harris , Kyle C. Smith

Battery degradation is a major challenge in electric vehicles (EV) and energy storage systems (ESS). However, most degradation investigations focus mainly on estimating the state of charge (SOC), which fails to accurately interpret the…

Machine Learning · Computer Science 2025-04-22 Md Azizul Hoque , Babul Salam , Mohd Khair Hassan , Abdulkabir Aliyu , Abedalmuhdi Almomany , Muhammed Sutcu

In this article, a novel implementation of a widely used pseudo-two-dimensional (P2D) model for lithium-ion battery simulation is presented with a transmission line circuit structure. This implementation represents an interplay between…

Chemical Physics · Physics 2021-11-03 Zeyang Geng , Siyang Wang , Matthew J. Lacey , Daniel Brandell , Torbjörn Thiringer

We report on the origin of the surface structural disordering in graphite anodes induced by lithium intercalation and deintercalation processes. Average Raman spectra of graphitic anodes reveal that cycling at potentials that correspond to…

Materials Science · Physics 2011-08-04 Vijay A. Sethuraman , Laurence J. Hardwick , Venkat Srinivasan , Robert Kostecki

Solid electrolytes for solid-state Li-ion batteries are stimulating considerable interest for next-generation energy storage applications. The Li$_7$La$_3$Zr$_2$O$_{12}$ garnet-type solid electrolyte has received appreciable attention as a…

We demonstrate a physical mechanism that enhances a splitting of diatomic $\rm Li_2$ at cellulose surfaces. The origin of this splitting is a possible surface induced diatomic excited state resonance repulsion. The atomic Li is then free to…

Mesoscale and Nanoscale Physics · Physics 2014-02-10 Mathias Boström , Dan Huang , Weihong Yang , Clas Persson , Bo E. Sernelius

The potential of tetra-penta-deca-hexagonal graphene (TPDH-gr), a recently proposed 2D carbon allotrope as an anodic material in lithium ion batteries (LIB), was investigated through density functional theory (DFT) calculations. The results…

The demand for lithium ion batteries (LIBs) on the market has gradually risen, with production increasing every year. To meet industrial needs, the development of digital twins designed to optimize LIB manufacturing processes is essential.…

We review recent ab initio molecular dynamics studies of electrode/electrolyte interfaces in lithium ion batteries. Our goals are to introduce experimentalists to simulation techniques applicable to models which are arguably most faithful…

Materials Science · Physics 2013-04-23 Kevin Leung