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Lithium metal batteries are seen as a critical piece towards electrifying aviation. During charging, plating of lithium metal, a critical failure mechanism, has been studied and mitigation strategies have been proposed. For electric…

Chemical Physics · Physics 2021-03-09 Victor Venturi , Venkatasubramanian Viswanathan

Metal components are extensively used as current collectors, anodes, and interlayers in lithium-ion batteries. Integrating these functions into one component enhances the cell energy density and simplifies its design. However, this…

In this article, a pioneering study is presented where the intermittent current interruption method is used to characterize the aging behavior of commercial lithium ion batteries. With a very resource-efficient implementation, this method…

Chemical Physics · Physics 2021-11-09 Zeyang Geng , Torbjörn Thiringer , Matthew J. Lacey

Innovative new materials are consistently emerging as electrode candidates from lithium-ion battery research, promising high energy densities and high-rate capabilities. Understanding potential structural changes, morphology evolution,…

Applied Physics · Physics 2023-06-30 Alex Lonergan , Umair Gulzar , Yan Zhang , Colm O'Dwyer

Two-dimensional (2D) materials have received considerable attention as possible electrodes in Li-ion batteries (LIBs), although a deeper understanding of the Li adsorption behavior as well as broad screening of the materials space is still…

Materials Science · Physics 2022-03-22 Sheng Gong , Shuo Wang , Taishan Zhu , Xi Chen , Jeffrey C. Grossman

Understanding solid liquid interfaces at high spatial and chemical resolution is crucial for advancing electrochemical energy storage technologies, yet this remains a persistent challenge due to the lack of characterisation techniques that…

We demonstrate that photoacoustic microscopy (PAM) can be a potential novel imaging tool to investigate the Li metal dendrite growth, a critical issue leading to short circuit and even explosion of Li metal batteries. Our results suggest…

Applied Physics · Physics 2019-10-02 Huihui Liu , Yibo Zhao , Jiasheng Zhou , Ping Li , Shou-Hang Bo , Sung-Liang Chen

The kinetic performance of graphite particles is difficult to deconvolute from half-cell experiments, where the influences of the working electrode porosity and the counter electrode contribute nonlinearly to the electrochemical re-sponse.…

Materials Science · Physics 2015-03-13 Michael Heß , Petr Novák

In this study we construct a data-driven model describing Lithium plating in a battery cell, which is a key process contributing to degradation of such cells. Starting from the fundamental Doyle-Fuller-Newman (DFN) model, we use asymptotic…

Chemical Physics · Physics 2024-08-28 Avesta Ahmadi , Kevin J. Sanders , Gillian R. Goward , Bartosz Protas

Lithium-ion batteries (LIBs) of high energy density and light-weight design, have found wide applications in electronic devices and systems. Degradation mechanisms that caused by lithiation is a main challenging problem for LIBs with high…

Computational Engineering, Finance, and Science · Computer Science 2020-06-26 Masoud Ahmadi

Alkali metal ion batteries, and in particular Li-ion batteries, have become a key technology for current and future energy storage, already nowadays powering many devices of our daily lives. Due to the inherent complexity of batteries and…

Materials Science · Physics 2021-12-14 Holger Euchner , Axel Groß

Untangling the relationship between reactions, mass transfer, and temperature within lithium-ion batteries enables control approaches that mitigate thermal hot spots and slow degradation. Here, we develop an efficient physics-based…

Chemical Physics · Physics 2022-07-07 Jie Lin , Howie N. Chu , David A. Howey , Charles W. Monroe

Accurate tracking of the internal electrochemical states of lithium-ion battery during cycling enables advanced battery management systems to operate the battery safely and maintain high performance while minimizing battery degradation. To…

Systems and Control · Electrical Eng. & Systems 2020-10-01 Sravan Pannala , Puneet Valecha , Peyman Mohtat , Jason B. Siegel , Anna G. Stefanopoulou

We present a simulation workflow for efficient investigations of the interplay between 3D lithium-ion electrode microstructures and electrochemical performance, with emphasis on lithium plating. Our approach addresses several challenges.…

Distributions of potential and lithium content inside lithium ion batteries highly affects their performance and durability. An increased heterogeneity of the lithium distribution is expected in thick electrodes with high energy densities…

In the quest for better energy storage solutions, the role of designing effective electrodes is crucial. Previous research has shown that using materials like single-side fluorinated graphene can improve the stability of ion insertion in…

Materials Science · Physics 2024-08-28 Yu-Hsiu Lin , Jose L. Mendoza-Cortes

Inactive lithium (Li) formation is the immediate cause of capacity loss and catastrophic failure of Li metal batteries. However, the chemical component and the atomic level structure of inactive Li have rarely been studied due to the lack…

Electrolyte filling is a time-critical step during battery manufacturing that also affects the battery performance. The underlying physical phenomena during filling mainly occur on the pore scale and are hard to study experimentally. In…

Due to its exceptional lithium storage capacity silicon is considered as a promising candidate for anode material in lithium-ion batteries (LIBs). In the present work we demonstrate that methods of the soft X-ray emission spectroscopy…

In this article, we derive and discuss a physics-based model for impedance spectroscopy of lithium batteries. Our model for electrochemical cells with planar electrodes takes into account the solid-electrolyte interphase (SEI) as porous…

Chemical Physics · Physics 2020-04-03 Fabian Single , Birger Horstmann , Arnulf Latz