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Precision spectroscopy of atomic hydrogen is an important way to test bound-state quantum electrodynamics (QED), one of the building blocks of the Standard Model. In its simplest form, such a test consists of the comparison of a measured…

Atomic Physics · Physics 2025-12-24 Lothar Maisenbacher

Precision spectroscopy of the hydrogen molecule is a test ground of quantum electrodynamics (QED), and may serve for determination of fundamental constants. Using a comb-locked cavity ring-down spectrometer, for the first time, we observed…

Atomic Physics · Physics 2018-04-18 L. -G. Tao , A. -W. Liu , K. Pachucki , J. Komasa , Y. R. Sun , J. Wang , S. -M. Hu

Despite quantum electrodynamics (QED) being one of the most stringently tested theories underpinning modern physics, recent precision atomic spectroscopy measurements have uncovered several small discrepancies between experiment and theory.…

Quantum electrodynamics is the first successful and still the most successful quantum field theory. Simple atoms, being essentially QED systems, allow highly accurate theoretical predictions. Because of their simple spectra, such atoms have…

High Energy Physics - Phenomenology · Physics 2011-07-19 Savely G. Karshenboim

High-precision laser spectroscopy of atomic hydrogen has led to an impressive accuracy in tests of bound-state quantum electrodynamics (QED). At the current level of accuracy many systematics have to be studied very carefully and only…

Atomic Physics · Physics 2022-09-21 J. J. Krauth , L. S. Dreissen , C. Roth , E. L. Gründeman , M. Collombon , M. Favier , K. S. E. Eikema

A recent 15 parts-per-million (ppm) experiment on muonic hydrogen found a major discrepancy with QED and independent nuclear size determinations. Here we find a significant discrepancy in a different type of exotic atom, a medium-Z nucleus…

We consider quantum electrodynamics (QED) corrections to the fine splitting $E(2P_{3/2}) - E(2P_{1/2})$ in the Li atom. We derive complete formulas for the $m\,\alpha^6$ and $m\,\alpha^7\,\ln\alpha$ contributions and calculate them…

Atomic Physics · Physics 2015-06-19 Mariusz Puchalski , Krzysztof Pachucki

The simplest molecules in nature, molecular hydrogen ions in the form of H2+ and HD+, provide an important benchmark system for tests of quantum electrodynamics in complex forms of matter. Here, we report on such a test based on a frequency…

Atomic Physics · Physics 2016-02-03 J. Biesheuvel , J. -Ph. Karr , L. Hilico , K. S. E. Eikema , W. Ubachs , J. C. J. Koelemeij

Precision physics aims to use atoms and molecules to test and develop the fundamental theory of matter, possibly beyond the Standard Model. Most of the atomic and molecular phenomena are described by the QED (quantum electrodynamics) sector…

Chemical Physics · Physics 2024-06-11 Ádám Nonn , Ádám Margócsy , Edit Mátyus

Atomic hydrogen energy levels calculated to high precision are required to assist experimental researchers working on spectroscopy in the pursuit of testing quantum electrodynamics (QED) and probing for physics beyond the Standard Model.…

Atomic Physics · Physics 2023-09-12 David M. Jacobs , Marko Horbatsch

Comparison of precision frequency measurements to quantum electrodynamics (QED) predictions for Rydberg states of hydrogen-like ions can yield information on values of fundamental constants and test theory. With the results of a calculation…

Atomic Physics · Physics 2009-02-02 U. D. Jentschura , P. J. Mohr , J. N. Tan , B. J. Wundt

We consider a one-dimensional effective quantum electrodynamics (QED) model of the relativistic hydrogen-like atom using delta-potential interactions. We discuss the general exact theory and the Hartree-Fock approximation. The present…

Mathematical Physics · Physics 2023-06-27 Timothée Audinet , Julien Toulouse

The hydrogen molecule has become a test ground for quantum electrodynamical calculations in molecules. Expanding beyond studies on stable hydrogenic species to the heavier radioactive tritium-bearing molecules, we report on a measurement of…

Chemical Physics · Physics 2018-04-25 T. Madhu Trivikram , M. Schlösser , W. Ubachs , E. J. Salumbides

In an atom, the interaction of a bound electron with the vacuum fluctuations of the electromagnetic field leads to complex shifts in the energy levels of the electron, with the real part of the shift corresponding to a shift in the energy…

Quantum Physics · Physics 2023-06-05 G. Jordan Maclay

The workhorse of atomic physics, quantum electrodynamics, is one of the best-tested theories in physics. However recent discrepancies have shed doubt on its accuracy for complex atomic systems. To facilitate the development of the theory…

Atomic Physics · Physics 2022-08-16 B. M. Henson

Quantum electrodynamical (QED) calculations of ionization energies of the $1snd\,D$ states are performed for the helium atom. We reproduce the previously known relativistic and QED effects up to order $m\alpha^5$ and extend the theory by…

Atomic Physics · Physics 2020-07-14 Vladimir A. Yerokhin , Vojtěch Patkóš , Mariusz Puchalski , Krzysztof Pachucki

Using the Dirac equation, radiative corrections and finite nuclear size and mass corrections, we calculate the $1s$-$2s$ quantum transition frequency $f_{1s,2s}$ of hydrogen and its uncertainty due to the uncertainties $\delta m_e, \delta…

Atomic Physics · Physics 2023-05-09 Igor Kuzmenko , Tetyana Kuzmenko , Y. Avishai , Y. B. Band

Absolute transition frequencies of the $2s\; ^2{\rm S}_{1/2} \rightarrow 2p\;^2\mathrm{P}_{1/2,3/2}$ transitions in Be$^+$ were measured for the isotopes $^{7,9-12}$Be. The fine structure splitting of the $2p$ state and its isotope…

Inner-shell electrons naturally sense the electric field close to the nucleus, which can reach extreme values beyond $10^{15}\,\text{V}/\text{cm}$ for the innermost electrons. Especially in few-electron highly charged ions, the interaction…

An optical measurement of the 2S hyperfine interval in atomic hydrogen using two-photon spectroscopy of the 1S-2S transition gives a value of 177 556 834.3(6.7) Hz. The uncertainty is 2.4 times smaller than achieved by our group in 2003 and…

Atomic Physics · Physics 2013-05-29 N. Kolachevsky , A. Matveev , J. Alnis , C. G. Parthey , S. G. Karshenboim , T. W. Haensch
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