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Designing molecular organic semiconductors with distinct frontier orbitals is key for the development of devices with desirable properties. Generating defined organic nanostructures with atomic precision can be accomplished by on-surface…

Gallenene is a promising low-dimensional material with a structure down to the thickness of a single atom, similar to graphene. However, van der Waals stacking of two-dimensional (2D) gallenene under confinement remain poorly understood. In…

Van der Waals materials enable the construction of atomically sharp interfaces between compounds with distinct crystal and electronic properties. This is dramatically exploited in moir\'e systems, where a lattice mismatch or twist between…

We unveil that the holey graphyne (HGY), a two-dimensional carbon allotrope where benzene rings are connected by two $-$C$\equiv$C$-$ bonds fabricated recently in a bottom-up way, exhibits topological electronic states. Using…

Mesoscale and Nanoscale Physics · Physics 2024-02-21 Yong-Cheng Jiang , Toshikaze Kariyado , Xiao Hu

Tin Selenide (SnSe) is one of the best thermoelectric materials reported to date. The possibility of growing few-layer SnSe helped boost the interest in this long-known, earth abundant material. Pristine SnSe in bulk, mono- and few-layer…

Materials Science · Physics 2017-10-11 Hansika I. Sirikumara , Thushari Jayasekera

The layer stacking morphology in nanocarbons is paramount for achieving new properties and outperforming applications. Here, we demonstrate that graphene quantum dots (GQDs) retain crystallinity and a stacking structure from CVD graphene…

DFT calculations of the electronic structure of graphane and stoichiometrically halogenated graphene derivatives (fluorographene and other analogous graphene halides) show (i) localized orbital basis sets can be successfully and effectively…

Materials Science · Physics 2012-09-20 František Karlický , Radek Zbořil , Michal Otyepka

While graphene is a semi-metal, a recently synthesized hydrogenated graphene called graphane, is an insulator. We have probed the transformation of graphene upon hydrogenation to graphane within the framework of density functional theory.…

Mesoscale and Nanoscale Physics · Physics 2012-10-05 Prachi Chandrachud , Bhalchandra S Pujari , Soumyajyoti Haldar , Biplab Sanyal , D G Kanhere

The interest in two-dimensional and layered materials continues to expand, driven by the compelling properties of individual atomic layers that can be stacked and/or twisted into synthetic heterostructures. The plethora of electronic…

In two-dimensional van der Waals (vdWs) materials, the relative twist angle between adjacent layers not only controls their electronic properties, but also determines their stacking energy. This effect makes it much easier to realize…

Mesoscale and Nanoscale Physics · Physics 2021-04-06 Yi-Wen Liu , Chen-Yue Hao , Lin He

Graphdiyne is a novel two-dimensional material deriving from graphene that has been recently synthesized and featuring uniformly distributed sub-nanometer pores. We report accurate calculations showing that graphdiyne pores permit an almost…

Undoped graphene is semi-metallic and thus not suitable for many electronic and optoelectronic applications requiring gapped semiconductor materials. However, a periodic array of holes (antidot lattice) renders graphene semiconducting with…

Mesoscale and Nanoscale Physics · Physics 2008-06-24 Thomas G. Pedersen , Christian Flindt , Jesper Pedersen , Antti-Pekka Jauho , Niels Asger Mortensen , Kjeld Pedersen

Artificially constructed van der Waals heterostructures (vdWHs) provide an ideal platform for realizing emerging quantum phenomena in condensed matter physics. Two methods for building vdWHs have been developed: stacking two-dimensional…

Materials Science · Physics 2020-12-30 Wei Yao , Martin Aeschlimann , Shuyun Zhou

Graphene, as an atomic-thick ultrasoft membrane, almost has no resistance against out-of-plane deformations and, therefore, it is always wrinkled to a certain degree. Recently, corrugated structures and their effects on the electronic…

Mesoscale and Nanoscale Physics · Physics 2016-09-13 Si-Yu Li , Hua Jiang , Jiao-Jiao Zhou , Haiwen Liu , Fan Zhang , Lin He

Here, we present a mechanism for tailoring the photonic band structure of a quarter-wave stack without changing its physical periods by embedding conductive sheets. Graphene is utilized and studied as a realistic, two-dimensional conductive…

Optics · Physics 2014-07-31 Yuancheng Fan , Zeyong Wei , Hongqiang Li , Hong Chen , Costas M. Soukoulis

Recently, the in-plane thermal transport in van der Waals (vdW) materials such as graphene, hexagonal boron nitride (h-BN), and transition metal dichalcogenides (TMDs) has been widely studied. Whereas, the cross-plane one is far from…

Materials Science · Physics 2023-07-11 S. G. Wang , H. F. Feng , Zhi-Xin Guo

The combination of two-dimensional (2D) materials into heterostructures enabled the formation of atomically thin devices with designed properties. To achieve a high density, bottom-up integration, the growth of these 2D heterostructures via…

Materials Science · Physics 2021-08-04 Martin Heilmann , Victor Deinhart , Abbes Tahraoui , Katja Höflich , J. Marcelo J. Lopes

Thermal conductivity of homogeneous twisted stacks of graphite is found to strongly depend on the misfit angle. The underlying mechanism relies on the angle dependence of phonon-phonon couplings across the twisted interface. Excellent…

Mesoscale and Nanoscale Physics · Physics 2020-10-19 Wengen Ouyang , Huasong Qin , Michael Urbakh , Oded Hod

Van der Waals (vdWs) heterostructures assembled by stacking 2D crystal layers have proven to be a new material platform for high-performance optoelectronic applications such as thin film transistors, photodetectors, and emitters. Here, we…

The electronic structure of Sc1-xVxNy epitaxial films with different alloying concentrations of V are investigated with respect to effects on thermoelectric properties. Band structure calculations on Sc0.75V0.25N indicate that V 3d states…

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