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The performance of quantum algorithms for ground-state energy estimation is directly impacted by the quality of the initial state, where quality is traditionally defined in terms of the overlap of the input state with the target state. An…

A well-known cluster expansion, which leads to virial expansion for the free energy of low density systems, is modified in such a way that it becomes applicable to the description of condensed state of matter. To this end, the averaging of…

Statistical Mechanics · Physics 2018-12-21 G. S. Bokun , M. F. Holovko

Methods which aim at universal applicability must be able to describe both weak and strong electronic correlation with equal facility. Such methods are in short supply. The combination of symmetry projection for strong correlation and…

Chemical Physics · Physics 2020-05-14 Yiheng Qiu , Thomas M. Henderson , Jinmo Zhao , Gustavo E. Scuseria

We recently proposed a novel approach to converging electronic energies equivalent to high-level coupled-cluster (CC) computations by combining the deterministic CC($P$;$Q$) formalism with the stochastic configuration interaction (CI) and…

Chemical Physics · Physics 2021-03-23 J. Emiliano Deustua , Jun Shen , Piotr Piecuch

Multi-task clustering (MTC) has attracted a lot of research attentions in machine learning due to its ability in utilizing the relationship among different tasks. Despite the success of traditional MTC models, they are either easy to stuck…

Machine Learning · Computer Science 2018-08-27 Yazhou Ren , Xiaofan Que , Dezhong Yao , Zenglin Xu

We generalize the coupled-cluster (CC) approach with singles, doubles, and the non-iterative treatment of triples termed $\Lambda$CCSD(T) to Hamiltonians containing three-body interactions. The resulting method and the underlying CC…

Nuclear Theory · Physics 2013-11-22 Sven Binder , Piotr Piecuch , Angelo Calci , Joachim Langhammer , Petr Navrátil , Robert Roth

It has been over ten years since Kane's influential proposal for a silicon-based nuclear spin quantum computer using phosphorous donors. Since then, silicon-based architectures have been refined as the experimental challenges associated…

Quantum Physics · Physics 2009-05-26 John J. L. Morton

We present an innovative cluster-based method employing linear combinations of diverse cluster mean-field (cMF) states, and apply it to describe the ground state of strongly-correlated spin systems. In cluster mean-field theory, the ground…

Strongly Correlated Electrons · Physics 2024-05-03 Athanasios Papastathopoulos-Katsaros , Thomas M. Henderson , Gustavo E. Scuseria

The coherent potential approximation, CPA, is a useful tool to treat systems with disorder. Cluster theories have been proposed to go beyond the translation invariant single-site CPA approximation and include some short range correlations.…

Condensed Matter · Physics 2009-10-31 C. I. Ventura , R. A. Barrio , .

In this paper we utilize superoperator formalism to explore the entanglement evolution of four-qubit cluster states in a number of decohering environments. A four-qubit cluster state is a resource for the performance of an arbitrary single…

Quantum Physics · Physics 2015-05-20 Yaakov S. Weinstein , Jay Feldman , Jacob Robins , Jason Zukus , Gerald Gilbert

We introduce a simple definition of the weight of any given Slater determinant in the coupled-cluster state, namely as the expectation value of the projection operator onto that determinant. The definition can be applied to any…

Chemical Physics · Physics 2025-03-05 Håkon Emil Kristiansen , Håkon Kvernmoen , Simen Kvaal , Thomas Bondo Pedersen

We present the implementation of relativistic coupled cluster quadratic response theory (QR-CC), following our development of relativistic equation of motion coupled cluster quadratic response theory (QR-EOMCC) [X. Yuan et al., J. Chem.…

Chemical Physics · Physics 2025-11-17 Xiang Yuan , Loïc Halbert , Lucas Visscher , André Severo Pereira Gomes

We present a similarity transformation theory based on a polynomial form of a particle-hole pair excitation operator. In the weakly correlated limit, this polynomial becomes an exponential, leading to coupled cluster doubles. In the…

Strongly Correlated Electrons · Physics 2016-11-23 Matthias Degroote , Thomas M. Henderson , Jinmo Zhao , Jorge Dukelsky , Gustavo E. Scuseria

We introduce a unitary coupled-cluster (UCC) ansatz termed $k$-UpCCGSD that is based on a family of sparse generalized doubles (D) operators which provides an affordable and systematically improvable unitary coupled-cluster wavefunction…

Quantum Physics · Physics 2019-01-07 Joonho Lee , William J. Huggins , Martin Head-Gordon , K. Birgitta Whaley

In a series of two articles, we propose a comprehensive mathematical framework for Coupled-Cluster-type methods. In this second part, we analyze the nonlinear equations of the single-reference Coupled-Cluster method using topological degree…

Numerical Analysis · Mathematics 2023-03-28 Mihály A. Csirik , Andre Laestadius

We apply the coupled cluster method (CCM) to the Hamiltonian version of the latticised O(4) non-linear sigma model. The method, which was initially developed for the accurate description of quantum many-body systems, gives rise to two…

High Energy Physics - Lattice · Physics 2009-10-30 N. E. Ligterink , N. R. Walet , R. F. Bishop

We implement the Multi-Reference Unitary Coupled Cluster Singles and Doubles (MR-UCCSD) model with a quantum circuit that conserves the particle number to study the ground state energies of LiH, BeH$_2$, and H$_6$. This approach simplifies…

Quantum Physics · Physics 2025-04-15 Di Wu , C. L. Bai , H. Sagawa , H. Q. Zhang

It has recently been established that cluster-like states -- states that are in the same symmetry-protected topological phase as the cluster state -- provide a family of resource states that can be utilized for Measurement-Based Quantum…

Quantum Physics · Physics 2022-08-24 Nathanan Tantivasadakarn , Ashvin Vishwanath

A new state specific correlation correction to configuration interaction singles (CIS) excitation energies is preseted using coupled cluster perturbation theory (CCPT). General expressions for CIS-CCPT are derived and expanded explicitly to…

Chemical Physics · Physics 2015-06-19 Jason N. Byrd , Victor F. Lotrich , Rodney J. Bartlett

Properly spin-adapted coupled-cluster theory for general open-shell configurations remains an active area of research in electronic structure theory. In this contribution we examine Lindgren's normal-ordered exponential ansatz to correlate…

Chemical Physics · Physics 2024-10-02 Alexander Gunasekera , Nicholas Lee , David P. Tew
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