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We investigate the critical behavior of a near-critical fluid confined between two parallel plates in contact with a reservoir by calculating the order parameter profile and the Casimir amplitudes (for the force density and for the grand…

Statistical Mechanics · Physics 2012-03-16 Ryuichi Okamoto , Akira Onuki

An exact statistical mechanical derivation is given of the critical Casimir interactions between two defects in a planar lattice-gas Ising model. Each defect is a group of nearest-neighbor spins with modified coupling constants. Such a…

Statistical Mechanics · Physics 2016-11-23 Piotr Nowakowski , Anna Maciołek , Siegfried Dietrich

We show that critical Casimir effects can be accessed through direct simulation of a model binary fluid passing through the demixing transition. We work in the semi grand canonical ensemble, in slab geometry, in which the Casimir force…

Statistical Mechanics · Physics 2016-11-23 Francesco Puosi , David Lopes Cardozo , Sergio Ciliberto , Peter C. W. Holdsworth

The Casimir effect in quantum electrodynamics (QED) is perhaps the best-known example of fluctuation-induced long-ranged force acting on objects (conducting plates) immersed in a fluctuating medium (quantum electromagnetic field in vacuum).…

Statistical Mechanics · Physics 2009-07-13 Andrea Gambassi

Within mean-field theory we calculate the scaling functions associated with critical Casimir forces for a system consisting of two spherical colloids immersed in a binary liquid mixture near its consolute point and facing a planar,…

Soft Condensed Matter · Physics 2015-06-12 T. G. Mattos , L. Harnau , S. Dietrich

Critical Casimir forces emerge among particles or surfaces immersed in a near-critical fluid, with the sign of the force determined by surface properties and with its strength tunable by minute temperature changes. Here, we show how such…

Soft Condensed Matter · Physics 2024-09-16 Piotr Nowakowski , Nima Farahmand Bafi , Giovanni Volpe , Svyatoslav Kondrat , S. Dietrich

We review recent work on the phase behaviour of binary charged sphere mixtures as a function of particle concentration and composition. Both size ratios and charge ratios are varied over a wide range. By contrast to hard spheres the long…

We analyze the critical gas-liquid phase behavior of arbitrary fluid mixtures in their coexistence region. We focus on the setting relevant for polydisperse colloids, where the overall density and composition of the system are being…

Soft Condensed Matter · Physics 2019-11-22 Pablo de Castro , Peter Sollich

Recent experimental realizations of the critical Casimir effect have been implemented by monitoring colloidal particles immersed in a binary liquid mixture near demixing and exposed to a chemically structured substrate. In particular,…

Statistical Mechanics · Physics 2016-05-31 Francesco Parisen Toldin , Matthias Tröndle , S. Dietrich

A theoretical study of the structure formation observed very recently [Phys. Rev. Lett. 90, 128303 (2003)] in binary colloids is presented. In our model solely the dipole-dipole interaction of the particles is considered,…

Soft Condensed Matter · Physics 2009-11-10 Imre Varga , Ferenc Kun , Karoly F. Pal

Hierarchical self-assembly consisting of local associations of simple building-blocks for the formation of complex structures widely exists in nature, while the essential role of local assembly remains unknown. In this work, by using…

Soft Condensed Matter · Physics 2017-10-18 Qun-li Lei , Kunn Hadinoto , Ran Ni

A colloidal monolayer embedded in the bulk of a fluid experiences a "compressible", long-range hydrodynamic interaction which, far from boundaries, leads to a breakdown of Fick's law above a well defined length scale, showing up as…

Soft Condensed Matter · Physics 2026-05-12 M. Chamorro-Burgos , Alvaro Domínguez

We provide an exact mapping between the density functional of a binary mixture and that of the effective one-component fluid in the limit of infinite asymmetry. The fluid of parallel hard cubes is thus mapped onto that of parallel adhesive…

Soft Condensed Matter · Physics 2009-10-31 Yuri Martinez-Raton , Jose A. Cuesta

We develop a computational study of Casimir forces between three dimensional (3D) finite objects with an internal granular structure. The objects in the model consist of a finite arrangement of nanometer sized spherical particles having a…

Quantum Physics · Physics 2008-06-13 C E Román-Velázquez , Bo E Sernelius

Charged colloidal particles trapped at an air--water interface are well known to form an ordered crystal, stabilized by a long ranged repulsion, the details of this repulsion remain something of a mystery, but all experiments performed to…

Soft Condensed Matter · Physics 2016-12-22 Duck-Gyu Lee , Pietro Cicuta , Dominic Vella

The collective diffusion effects in system of a colloidal particles in a liquid crystal has been proposed. In this article described peculiarity of collective diffusion colloidal particles in a liquid crystal, which can be observe…

Soft Condensed Matter · Physics 2017-12-25 B. I. Lev , A. G. Zagorodny

A solid substrate, when exposed to a vapour, can interact with it in such a way that sufficiently close to liquid-vapour coexistence a macroscopically thick liquid wetting layer is formed on the substrate surface. If such a wetting…

Statistical Mechanics · Physics 2009-10-30 N. B. Wilding , M. Krech

The aggregation of binary colloids of same size and balanced charges is studied by Brownian dynamics simulations for dilute suspensions. It is shown that, under appropriate conditions, the formation of colloidal crystals is dominated by…

Soft Condensed Matter · Physics 2015-06-12 D. Bochicchio , A. Videcoq , R. Ferrando

The increase of the viscosity, which is observed in attractive colloidal systems by varying the temperature or the volume fraction, can be related to the formation of structures due to particle aggregation. In particular we have studied the…

Statistical Mechanics · Physics 2009-11-11 F. Mallamace , S. H. Chen , A. Coniglio , L. de Arcangelis , E. Del Gado , A. Fierro

We explore phase behaviour of a binary colloidal system under external spatially periodic modulation. We perform Monte Carlo simulation on a binary mixture of big and small repulsive Lennard-Jones particles with diameter ratio 1:2. We…

Soft Condensed Matter · Physics 2023-07-31 Suravi Pal , Jaydeb Chakrabarti , Srabani Chakrabarty nee Sarkar