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Vacancy-ordered double perovskites K2SnX6 (X = I, Br, Cl) attract significant research interest due to their potential application as light-absorbing materials in perovskite solar cells. However, a deep insight into their material…

Materials Science · Physics 2019-08-30 Un-Gi Jong , Chol-Jun Yu , Yun-Hyok Kye

Hybrid Lead halide perovskites, despite having unique intrinsic properties with the possibility of flexible synthesis and device fabrication, still suffer from two fundamental issues, i.e. stability in external environment and toxicity due…

Materials Science · Physics 2018-05-16 Jiban Kangsabanik , Vipinraj Sugathan , Anuradha Yadav , Aswani Yella , Aftab Alam

Vacancy ordered halide perovskites have been extensively investigated as promising lead-free alternatives to halide perovskites for various opto-electronic applications. Among these Cs$_{2}$TiBr$_{6}$ has been reported as a stable absorber…

Materials Science · Physics 2023-06-28 B. Cucco , G. Bouder , L. Pedesseau , C. Katan , J. Even , M. Kepenekian , G. Volonakis

Despite the exceeding 23\% photovoltaic efficiency achieved in organic-inorganic hybrid perovskite solar cells obtaining, the stable materials with desirable band gap are rare and are highly desired. With the aid of first-principles…

Applied Physics · Physics 2020-02-21 Qiaoqiao Li , Liujiang Zhou , Yanfeng Ge , Yulu Ren , Jiangshan Zhao , Wenhui Wan , Kaicheng Zhang , Yong Liu

Tin-based halide perovskites have emerged as promising lead-free alternatives for optoelectronic applications, yet their structural stability and phase behavior at finite temperatures remain challenging to predict. Here, we assess the…

Materials Science · Physics 2026-05-18 Thiago Puccinelli , Lucas Martin Farigliano , Gustavo Martini Dalpian

CsSnI3 is a promising eco-friendly solution for energy harvesting technologies. It exists at room temperature in either a black perovskite polymorph or a yellow 1D double-chain, which irreversibly deteriorates in the air. In this work, we…

Materials Science · Physics 2023-02-10 Lorenzo Monacelli , Nicola Marzari

The electronic structure and energetic stability of A$_2$BX$_6$ halide compounds with the cubic and tetragonal variants of the perovskite-derived K$_2$PtCl$_6$ prototype structure are investigated computationally within the frameworks of…

The halide double perovskite Cs$_2$AgBiBr$_6$ has been proposed as a potential replacement for organic halide perovskites for photovoltaic applications. Further investigation of its dielectric response, optical properties and structural…

In contrast to lead-based perovskites, double perovskites have attracted considerable interest due to their ability to modulate photovoltaic properties and high stability through elemental control. However, most double perovskites are…

Materials Science · Physics 2024-11-01 Yue Kuai , Changcheng Chen , Pengfei Lu

Hybrid peroskite solar cells are newly emergent high-performance photovoltaic devices, which suffer from disadvantages such as toxic elements, short-term stabilities, and so on. Searching for alternative perovskites with high photovoltaic…

Materials Science · Physics 2023-08-02 Linkang Zhan , Danfeng Ye , Xinjian Qiu , Yan Cen

As a possible alternative to organic-inorganic hybrid perovskite halide, inorganic Cs2SnI6 has drawn more and more research attention recently. In order to find more Cs2SnI6 derivatives as the potential solar cell absorber materials, I-…

Materials Science · Physics 2021-08-10 Wang Xuan , Tang Yehua , Nairui Xiao , Wang Ke-Fan

The lead-free double perovskite material (viz. Cs$_2$AgBiCl$_6$) has emerged as an efficient and environmentally friendly alternative to lead halide perovskites. To make Cs$_2$AgBiCl$_6$ optically active in the visible region of solar…

Materials Science · Physics 2021-06-07 Deepika Gill , Preeti Bhumla , Manish Kumar , Saswata Bhattacharya

Despite the tremendous interest in halide perovskites in solar cells, the reason that the all-inorganic perovskite CsPbI$_3$ is unstable at room temperature remains mysterious. Here single-crystal X-ray diffraction and powder pair…

Materials Science · Physics 2020-07-08 Daniel B. Straus , Shu Guo , Milinda Abeykoon , Robert J. Cava

Amongst the X(Sn,Pb)Y$_3$ perovskites currently under scrutiny for their photovoltaic applications, the cubic B-$\alpha$ phase of CsSnI$_3$ is arguably the best characterized experimentally. Yet, according to the standard harmonic theory of…

Materials Science · Physics 2015-11-25 Christopher E. Patrick , Karsten W. Jacobsen , Kristian S. Thygesen

Halide double perovskites have recently been proposed as potential environmentally friendly alternatives to organic group and lead based hybrid halide perovskites. In particular, Cs2BiAgX6 have been synthesized and found to exhibit tunable…

Applied Physics · Physics 2019-05-03 Yunting Liang

Silver-based chalcohalide anti-perovskites (CAP), Ag$_{3}$BC (B = S, Se; C = Cl, Br, I), represent an emerging family of energy materials with intriguing optoelectronic, vibrational and ionic transport properties. However, the structural…

Perovskite-inspired materials have emerged as promising candidates for both outdoor and indoor photovoltaic applications owing to their favorable optoelectronic properties and reduced toxicity. Here, we employ the experimentally realized…

Hybrid perovskite solar cells, with their power conversion efficiency (PCE) exceeding 22%, have been representing a revolutionary concept for future energy power generation. Although listed among the Top 10 Emerging Technologies of 2016,…

Lead-free double perovskites are gaining attention for photovoltaic (PV) applications due to their long carrier lifetimes, tunable bandgaps, and low toxicity. Using first-principles calculations, we studied the structural, electronic and…

Materials Science · Physics 2025-05-16 Ardimas , Edi Suprayoga

In the previous decade, there has been a significant advancement in the performance of perovskite solar cells (PSCs), characterized by a notable increase in efficiency from 3.8% to 25%. Nonetheless, PSCs face many problems when we…

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