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Classical algorithms for predicting the equilibrium geometry of strongly correlated molecules require expensive wave function methods that become impractical already for few-atom systems. In this work, we introduce a variational quantum…

In quantum control theory, a question of fundamental and practical interest is how an arbitrary unitary transformation can be decomposed into minimum number of elementary rotations for implementation, subject to various physical…

Mesoscale and Nanoscale Physics · Physics 2019-05-29 Xiao-Ming Zhang , Jianan Li , Xin Wang , Man-Hong Yung

Classical simulation of quantum systems plays an important role in the study of many-body phenomena and in the benchmarking and verification of quantum technologies. Exact simulation is often limited to small systems because the dimension…

Quantum Physics · Physics 2024-06-04 Dominik S. Wild , Sabina Drăgoi , Corbin McElhanney , Jonathan Wurtz , Sheng-Tao Wang

We present a quantum algorithm for simulating rovibrational Hamiltonians on fault-tolerant quantum computers. The method integrates exact curvilinear kinetic energy operators and general-form potential energy surfaces expressed in a hybrid…

Quantum Physics · Physics 2026-04-07 Michał Szczepanik , Ákos Nagy , Emil Żak

Quantum simulation of the electronic structure problem is one of the most researched applications of quantum computing. The majority of quantum algorithms for this problem encode the wavefunction using $N$ Gaussian orbitals, leading to…

Continuous unitary transformations are a powerful tool to extract valuable information out of quantum many-body Hamiltonians, in which the so-called flow equation transforms the Hamiltonian to a diagonal or block-diagonal form in second…

Strongly Correlated Electrons · Physics 2017-03-23 S. Sahin , K. P. Schmidt , R. Orus

We provide an explicit recursive divide and conquer approach for simulating quantum dynamics and derive a discrete first quantized non-relativistic QED Hamiltonian based on the many-particle Pauli Fierz Hamiltonian. We apply this recursive…

Quantum Physics · Physics 2024-03-19 Priyanka Mukhopadhyay , Torin F. Stetina , Nathan Wiebe

We present a new approach to simulating Hamiltonian dynamics based on implementing linear combinations of unitary operations rather than products of unitary operations. The resulting algorithm has superior performance to existing simulation…

Quantum Physics · Physics 2018-08-02 Andrew M. Childs , Nathan Wiebe

While quantum simulators promise to explore quantum many-body physics beyond classical computation, their capabilities are limited by the available native interactions in the hardware. On many platforms, accessible Hamiltonians are largely…

Quantum Physics · Physics 2025-12-29 Or Katz , Alexander Schuckert , Tianyi Wang , Eleanor Crane , Alexey V. Gorshkov , Marko Cetina

The randomized linear combination of unitaries (LCU) method with many applications to early fault-tolerant quantum computing algorithms has been proposed. This quantum algorithm computes the same expectation values as the original, fully…

Quantum Physics · Physics 2026-02-16 Kaito Wada , Hiroyuki Harada , Yasunari Suzuki , Yuuki Tokunaga , Naoki Yamamoto , Suguru Endo

The physics of a quantum system with many degrees of freedom is often approximated by downfolding: most of the degrees of freedom are "folded into" a much smaller number of degrees of freedom, resulting in an effective Hamiltonian that…

Quantum Physics · Physics 2025-06-23 Troy Van Voorhis

Quantum simulation is a foundational application for quantum computers, projected to offer insights into complex quantum systems beyond the reach of classical computation. However, with the exception of Trotter-based methods, which suffer…

Quantum Physics · Physics 2026-02-10 Amir Kalev , Itay Hen

Combinatorial problems are formulated to find optimal designs within a fixed set of constraints. They are commonly found across diverse engineering and scientific domains. Understanding how to best use quantum computers for combinatorial…

The simulation of chemistry is among the most promising applications of quantum computing. However, most prior work exploring algorithms for block-encoding, time-evolving, and sampling in the eigenbasis of electronic structure Hamiltonians…

Starting from a general $N$-band Hamiltonian with weak spatial and temporal variations, we derive a low energy effective theory for transport within one or several overlapping bands. To this end, we use the Wigner representation that allows…

Mesoscale and Nanoscale Physics · Physics 2013-08-09 Christian Wickles , Wolfgang Belzig

Model-based quantum optimal control promises to solve a wide range of critical quantum technology problems within a single, flexible framework. The catch is that highly-accurate models are needed if the optimized controls are to meet the…

Quantum Physics · Physics 2023-04-25 Andy J. Goldschmidt , Frederic T. Chong

Developing Hamiltonian models for quantum processors with many qubits on the same chip is crucial for advancing quantum computing technologies. Stray couplings between qubits lead to errors in gate operations. This study underscores the…

Quantum Physics · Physics 2024-12-12 Xuexin Xu , Manabputra , Chloé Vignes , Mohammad H. Ansari , John Martinis

Hamiltonian simulation is a promising application for quantum computers to achieve a quantum advantage. We present classical algorithms based on tensor network methods to optimize quantum circuits for this task. We show that, compared to…

Quantum Physics · Physics 2023-06-05 Conor Mc Keever , Michael Lubasch

Quantum computing holds promise for outperforming classical computing in specialized applications such as optimization. With current Noisy Intermediate Scale Quantum (NISQ) devices, only variational quantum algorithms like the Quantum…

Quantum Physics · Physics 2024-07-08 Daniel Müssig , Markus Wappler , Steve Lenk , Jörg Lässig

Variational quantum algorithms dominate contemporary gate-based quantum enhanced optimisation, eigenvalue estimation and machine learning. Here we establish the quantum computational universality of variational quantum computation by…

Quantum Physics · Physics 2021-05-25 Jacob Biamonte