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We use microwaves to engineer repulsive long-range interactions between ultracold polar molecules. The resulting shielding suppresses various loss mechanisms and provides large elastic cross sections. Hyperfine interactions limit the…

Atomic Physics · Physics 2018-10-24 Tijs Karman , Jeremy M. Hutson

Quantum gases of ultracold polar molecules have novel properties because of the strong dipolar forces between molecules. Current experiments shield the molecules from destructive collisions by engineering long-range repulsive interactions…

Quantum Gases · Physics 2025-09-26 Bijit Mukherjee , Luis Santos , Jeremy M. Hutson

Scattering resonances are an essential tool for controlling interactions of ultracold atoms and molecules. However, conventional Feshbach scattering resonances, which have been extensively studied in various platforms, are not expected to…

We develop double microwave shielding, which has recently enabled evaporative cooling to the first Bose-Einstein condensate of polar molecules [Bigagli et al., Nature 631, 289 (2024)]. Two microwave fields of different frequency and…

Quantum Gases · Physics 2026-03-13 Tijs Karman , Niccolò Bigagli , Weijun Yuan , Siwei Zhang , Ian Stevenson , Sebastian Will

Harnessing the potential wide-ranging quantum science applications of molecules will require control of their interactions. Here, we use microwave radiation to directly engineer and tune the interaction potentials between ultracold calcium…

By applying a circularly polarized and slightly blue-detuned microwave field with respect to the first excited rotational state of a dipolar molecule, one can engineer a long-range, shallow potential well in the entrance channel of the two…

Quantum Gases · Physics 2018-10-24 Lucas Lassablière , Goulven Quéméner

Ultracold polar molecules can be shielded from fast collisional losses using microwaves, but achieving the required polarization purity is technically challenging. Here, we propose a scheme for shielding using microwaves with polarization…

Quantum Physics · Physics 2020-04-15 Tijs Karman

Trapped samples of ultracold molecules are often short-lived, because close collisions between them result in trap loss. We investigate the use of shielding with static electric fields to create repulsive barriers between polar molecules to…

Quantum Gases · Physics 2024-02-20 Bijit Mukherjee , Jeremy M. Hutson

We investigate the use of microwave radiation to produce a repulsive shield between pairs of ultracold polar molecules and prevent collisional losses that occur when molecular pairs reach short range. We carry out coupled-channels…

Atomic Physics · Physics 2019-12-03 Tijs Karman , Jeremy M. Hutson

We discuss techniques to engineer effective long-range interactions between polar molecules using external static electric and microwave fields. We consider a setup where molecules are trapped in a two-dimensional pancake geometry by a…

Quantum Physics · Physics 2009-11-13 A. Micheli , G. Pupillo , H. P. Büchler , P. Zoller

Spin mixtures of degenerate fermions are a cornerstone of quantum many-body physics, enabling superfluidity, polarons, and rich spin dynamics through $s$-wave scattering resonances. Combining them with strong, long-range dipolar…

We show that the electric dipole-dipole interaction between a pair of polar molecules undergoes an all-out transformation when superimposed by a far-off resonant optical field. The combined interaction potential becomes tunable by variation…

Atomic Physics · Physics 2015-05-30 Mikhail Lemeshko , Bretislav Friedrich

We theoretically study collisions between ultracold polar molecules that are polarized by microwave or static electric fields. We systematically study the dependence on field strength, microwave polarization, and detuning from rotational…

Atomic Physics · Physics 2022-02-09 Tijs Karman , Zoe Z. Yan , Martin Zwierlein

Ultracold dipolar molecules hold great promise for the creation of novel quantum states of matter, but the realization of long-lived molecular bulk samples with strong dipole-dipole interactions has remained elusive. Here, we realize a…

We discuss techniques to tune and shape the long-range part of the interaction potentials in quantum gases of polar molecules by dressing rotational excitations with static and microwave fields. This provides a novel tool towards…

Statistical Mechanics · Physics 2009-11-11 H. P. Büchler , E. Demler , M. Lukin , A. Micheli , N. Prokof'ev , G. Pupillo , P. Zoller

We calculate the microwave spectra of ultracold KRb alkali metal dimers, including hyperfine interactions and in the presence of electric and magnetic fields. We show that microwave transitions may be used to transfer molecules between…

Chemical Physics · Physics 2015-05-13 J. Aldegunde , Hong Ran , Jeremy M. Hutson

Microwave(MW) fields with strong field strength, ultralow phase-noise and tunable polarization are crucial for stabilizing and manipulating ultracold polar molecules, which have emerged as a promising platform for quantum sciences. In this…

We propose a method to engineer repulsive long-range interactions between ultracold ground-state molecules using optical fields, thus preventing short-range collisional losses. It maps the microwave coupling recently used for collisional…

A coherent electromagnetic field can be described by its amplitude, frequency, and phase. All these properties can influence the interaction between the field and an atom. Here we demonstrate the phase shaping of microwaves that are…

We study collisions of ultracold CaF molecules in strong static electric fields. These fields allow the creation of long-range barriers in the interaction potential, effectively preventing the molecules from reaching the short-range region…

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