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Nonlinear spectroscopic techniques using entangled photon pairs can provide an opportunity to exploit non-classical correlations encoded in two-photon wavefunctions to manipulate two-exciton wavefunctions. We propose an entangled photon…

Quantum Physics · Physics 2026-04-10 Arunangshu Debnath , Shaul Mukamel

Ultrafast optical spectroscopy is a powerful technique for studying the dynamic processes of molecular systems in condensed phases. However, in molecular systems containing many dye molecules, the spectra can become crowded and difficult to…

Chemical Physics · Physics 2025-02-05 Yuta Fujihashi , Akihito Ishizaki , Ryosuke Shimizu

Recent advances in techniques for generating quantum light have stimulated research on novel spectroscopic measurements using quantum entangled photons. One such spectroscopy technique utilizes non-classical correlations among entangled…

Chemical Physics · Physics 2021-07-28 Yuta Fujihashi , Akihito Ishizaki

We theoretically propose a biphoton entanglement-enhanced multidimensional spectroscopic technique as a probe for the dissipative polariton dynamics in the ultrafast regime. It is applied to the cavity-confined monomeric photosynthetic…

Quantum Physics · Physics 2022-09-07 Arunangshu Debnath , Angel Rubio

Quantum light is increasingly recognized as a promising resource for developing optical measurement techniques. Particular attention has been paid to enhancing the precision of the measurements beyond classical techniques by using…

Chemical Physics · Physics 2023-10-03 Yuta Fujihashi , Kuniyuki Miwa , Masahiro Higashi , Akihito Ishizaki

We apply our recently developed theory of frequency-filtered and time-resolved N-photon correlations to study the two-photon spectra of a variety of systems of increasing complexity: single mode emitters with two limiting statistics (one…

Quantum Physics · Physics 2014-03-06 A. Gonzalez-Tudela , F. P. Laussy , C. Tejedor , M. J. Hartmann , E. del Valle

Recent theoretical studies in quantum spectroscopy have emphasized the potential of non-classical correlations in entangled photon pairs for selectively targeting specific nonlinear optical processes in nonlinear optical responses. However,…

Chemical Physics · Physics 2026-04-21 Yuta Fujihashi , Ozora Iso , Ryosuke Shimizu , Akihito Ishizaki

We study in this paper the efficiency of different two-photon states of light to induce the simultaneous excitation of two atoms of different kinds when the sum of the energies of the two photons matches the sum of the energies of the two…

Quantum Physics · Physics 2013-03-21 Zhan Zheng , Pablo L. Saldanha , Jose R. Rios Leite , Claude Fabre

The non-classical spectral and temporal features of entangled photons offer new possibilities to investigate the interactions of excitons in photosynthetic complexes, and to target the excitation of specific states. Simulations of…

Quantum Physics · Physics 2012-11-05 Frank Schlawin , Konstantin Dorfman , Benjamin P. Fingerhut , Shaul Mukamel

High-dimensional entanglement in the form of transverse spatial correlation between a pair of photons generated via spontaneous parametric downconversion is not only a valuable resource in many academic and real-life applications but also…

Quantum Physics · Physics 2025-08-18 Rounak Chatterjee , Vikas S Bhat , Kiran Bajar , Sushil Mujumdar

Entangled photon spectroscopy is a nascent field that has important implications for measurement and imaging across chemical, biology, and materials fields. Entangled photon spectroscopy potentially offers improved spatial and…

Optics · Physics 2021-07-07 Szilard Szoke , Manni He , Bryce P. Hickam , Scott K. Cushing

We demonstrate a new class of frequency-entangled states generated via spontaneous parametric down-conversion under extended phase matching conditions. Biphoton entanglement with coincident signal and idler frequencies is observed over a…

Quantum Physics · Physics 2009-11-10 Onur Kuzucu , Marco Fiorentino , Marius A. Albota , Franco N. C. Wong , Franz X. Kaertner

Quantum light spectroscopy, providing novel molecular information non-accessible by classical light, necessitates new computational tools when applied for complex molecular systems. We introduce two computational protocols for the molecular…

Chemical Physics · Physics 2021-09-14 Bing Gu , Daniel Keefer , Shaul Mukamel

Frequency-filtered photon correlations have been proven to be extremely useful in grasping how the detection process alters photon statistics. Harnessing the spectral correlations also permits refinement of the emission and unraveling of…

Entangled photon pairs are predicted to linearize and increase the efficiency of two-photon absorption, allowing continuous wave laser diodes to drive ultrafast time-resolved spectroscopy and nonlinear processes. Despite a range of…

Quantum Physics · Physics 2022-05-31 Bryce P. Hickam , Manni He , Nathan Harper , Szilard Szoke , Scott Cushing

Classical time-resolved optical spectroscopy experiments are performed using sequences of ultrashort light pulses, with photon fluxes incident on the sample which are many orders of magnitude higher than real-world conditions corresponding…

Pairs of photons entangled in their time-frequency degree of freedom are of great interest in quantum optics research and applications, due to their relative ease of generation and their high capacity for encoding information. Here we…

Quantum Physics · Physics 2022-02-23 Sofiane Merkouche , Valérian Thiel , Brian J. Smith

While two-photon absorption (TPA) and other forms of nonlinear interactions of molecules with isolated time-frequency-entangled photon pairs (EPP) have been predicted to display a variety of fascinating effects, their potential use in…

Quantum light is a key resource for promoting quantum technology. One such class of technology aims to improve the precision of optical measurements using engineered quantum states of light. In this study, we investigate transmission…

Quantum Physics · Physics 2020-08-10 Akihito Ishizaki

In virtual-state spectroscopy, information about the energy-level structure of an arbitrary sample is retrieved by Fourier transforming sets of measured two-photon absorption probabilities of entangled photon pairs where the degree of…

Quantum Physics · Physics 2021-08-04 Lutz Mertenskötter , Kurt Busch , Roberto de J. León-Montiel
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