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Grain boundary-based mechanisms are known to control the plastic deformation and failure of nanocrystalline metals, with manipulation of the boundary structure a promising path for tuning this response. In this study, the role of…

Materials Science · Physics 2021-05-26 Jenna L. Wardini , Charlette M. Grigorian , Timothy J. Rupert

Amorphous complexions have recently been demonstrated to simultaneously enhance the ductility and stability of certain nanocrystalline alloys. In this study, three quinary alloys (Cu-Zr-Hf-Mo-Nb, Cu-Zr-Hf-Nb-Ti, and Cu-Zr-Hf-Mo-W) are…

Materials Science · Physics 2022-02-02 Charlette M. Grigorian , Timothy J. Rupert

Amorphous complexions in nanocrystalline metals have the potential to improve mechanical properties and radiation tolerance, as well as resistance to grain growth. In this study, the stability of amorphous complexions in binary and ternary…

Materials Science · Physics 2020-12-18 Charlette M. Grigorian , Timothy J. Rupert

Grain boundary complexions have been observed to affect the mechanical behavior of nanocrystalline metals, improving both strength and ductility. While an explanation for the improved ductility exists, the observed effect on strength…

Materials Science · Physics 2018-03-28 Vladyslav Turlo , Timothy J. Rupert

Nanocrystalline metals are promising radiation tolerant materials due to their large interfacial volume fraction, but irradiation-induced grain growth can eventually degrade any improvement in radiation tolerance. Therefore, methods to…

Building on the recent discovery of tough nanocrystalline Cu-Zr alloys with amorphous intergranular films, this paper investigates ternary nanocrystalline Cu-Zr-Hf alloys with a focus on understanding how alloy composition affects the…

Materials Science · Physics 2019-08-16 Charlette M. Grigorian , Timothy J. Rupert

Nanocrystalline metal alloys show great potential as structural materials, but are often only available in small volumes such as thin films or powders. However, recent research has suggested that dopant segregation and grain boundary…

Materials Science · Physics 2019-07-01 Olivia K. Donaldson , Timothy J. Rupert

Amorphous grain boundary complexions act as toughening features within a microstructure because they can absorb dislocations more efficiently than traditional grain boundaries. This toughening effect should be a strong function of the local…

Materials Science · Physics 2023-08-09 Pulkit Garg , Timothy J. Rupert

Amorphous grain-boundary (GB) complexions in thermally stable nanocrystalline alloys are commonly assumed to be structurally homogeneous, yet their disordered nature makes them susceptible to local short-range ordering (SRO). The influence…

Materials Science · Physics 2026-05-27 Frederic Sansoz , Eve-Audrey Picard

Microcompression testing is used to probe the uniaxial stress-strain response of a nanocrystalline alloy, with an emphasis on exploring how grain size and grain boundary relaxation state impact the complete flow curve and failure behavior.…

Materials Science · Physics 2014-08-26 Amirhossein Khalajhedayati , Timothy J. Rupert

Nanocrystalline metals typically have high fatigue strengths, but low resistance to crack propagation. Amorphous intergranular films are disordered grain boundary complexions that have been shown to delay crack nucleation and slow crack…

Amorphous interfacial complexions have been shown to restrict grain growth and improve damage tolerance in nanocrystalline alloys, with increased chemical complexity stabilizing the complexions themselves. Here, we investigate local…

Materials Science · Physics 2026-03-05 Esther C. Hessong , Zhengyu Zhang , Tianjiao Lei , Mingjie Xu , Toshihiro Aoki , Timothy J. Rupert

Nanocrystalline Cu-3 at.% Zr powders with ~20 nm average grain size were created with mechanical alloying and their thermal stability was studied from 550-950 {\deg}C. Annealing drove Zr segregation to the grain boundaries, which led to the…

Materials Science · Physics 2015-08-31 Amirhossein Khalajhedayati , Timothy J. Rupert

Complexions are phase-like interfacial features that can influence a wide variety of properties, but the ability to predict which material systems can sustain these features remains limited. Amorphous complexions are of particular interest…

Materials Science · Physics 2017-08-22 Jennifer D. Schuler , Timothy J. Rupert

Stabilization of grain structure is important for nanocrystalline alloys, and grain boundary segregation is a common approach to restrict coarsening. Doping can alter grain boundary structure, with high temperature states such as amorphous…

Materials Science · Physics 2023-09-15 Tianjiao Lei , Esther C. Hessong , Daniel S. Gianola , Timothy J. Rupert

Although nanocrystalline alloys regularly exhibit high strengths, their use in structural applications often face challenges due to sample size limitations, unstable microstructures, and the limited ability to plastically deform. The…

Amorphous interfacial complexions are particularly resistant to radiation damage and have been primarily studied in alloys with good glass-forming ability, yet recent reports suggest that these features can form even in immiscible alloys…

Materials Science · Physics 2023-11-21 Doruk Aksoy , Penghui Cao , Jason R. Trelewicz , Janelle P. Wharry , Timothy J. Rupert

Amorphous grain boundary complexions lack long-range crystalline order but are not featureless, as distinct gradients in structural short-range order have been reported through their thickness. In this work, we test the hypothesis that the…

Materials Science · Physics 2023-09-19 Pulkit Garg , Timothy J. Rupert

Specimen- and grain-size effects on nanoscale plastic deformation mechanisms and mechanical properties of polycrystalline yttria-stabilized tetragonal zirconia (YSTZ) nanopillars are studied by molecular dynamics simulations. Through…

Materials Science · Physics 2019-05-02 Ning Zhang , Mohsen Asle Zaeem

Solute segregation is used to limit grain growth in nanocrystalline metals, but this stabilization often breaks down at high temperatures. Amorphous intergranular films can form in certain alloys at sufficiently high temperatures, providing…

Materials Science · Physics 2018-05-16 Jennifer D. Schuler , Olivia K. Donaldson , Timothy J. Rupert
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