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As a fundamental task in computational chemistry, retrosynthesis prediction aims to identify a set of reactants to synthesize a target molecule. Existing template-free approaches only consider the graph structures of the target molecule,…

Computation and Language · Computer Science 2024-01-29 Yifeng Liu , Hanwen Xu , Tangqi Fang , Haocheng Xi , Zixuan Liu , Sheng Zhang , Hoifung Poon , Sheng Wang

The calculation of reactive properties is a challenging task in chemical reaction discovery. Machine learning (ML) methods play an important role in accelerating electronic structure predictions of activation energies and reaction…

Chemical Physics · Physics 2025-05-02 Joe Gilkes , Mark Storr , Reinhard J. Maurer , Scott Habershon

Training data attribution (TDA) methods ask which training documents are responsible for a model behavior. However, models often learn broad concepts shared across many examples. Moreover, existing TDA methods are supervised -- they require…

Artificial Intelligence · Computer Science 2026-03-18 J Rosser

Recent breakthroughs in natural language processing and computer vision, driven by efficient pre-training on large datasets, have enabled foundation models to excel on a wide range of tasks. However, this potential has not yet been fully…

Machine Learning · Computer Science 2025-02-03 Özgün Turgut , Philip Müller , Martin J. Menten , Daniel Rueckert

Recent efforts to improve the predictability of TALYS-2.0 calculated charged-particle residual product cross sections have focused on adjusting parameters related to the optical model potential and pre-equilibrium process. Although adjusted…

A continuing challenge in atomic resolution microscopy is to identify significant structural motifs and their assembly rules in synthesized materials with limited observations. Here we propose and validate a simple and effective hybrid…

Materials Science · Physics 2023-05-31 Jiadong Dan , Moaz Waqar , Ivan Erofeev , Kui Yao , John Wang , Stephen J. Pennycook , N. Duane Loh

Machine learning has emerged as a powerful tool for predicting molecular properties in chemical reaction networks with reduced computational cost. However, accurately predicting energies of transition state (TS) structures remains a…

Chemical Physics · Physics 2025-04-29 Stefan Gugler , Markus Reiher

The strategy of pre-training a large model on a diverse dataset, then fine-tuning for a particular application has yielded impressive results in computer vision, natural language processing, and robotic control. This strategy has vast…

Systems and Control · Electrical Eng. & Systems 2024-07-30 Bruce D. Lee , Anders Rantzer , Nikolai Matni

There currently exist no quantitative methods to determine the appropriate conditions for solid-state synthesis. This not only hinders the experimental realization of novel materials but also complicates the interpretation and understanding…

We train a neural network to predict chemical toxicity based on gene expression data. The input to the network is a full expression profile collected either in vitro from cultured cells or in vivo from live animals. The output is a set of…

Genomics · Quantitative Biology 2019-02-04 Peter Eastman , Vijay S. Pande

Many chemical reactions can be formulated in terms of particle diffusion in a complex energy landscape. Transition path theory (TPT) is a theoretical framework for describing the direct (reaction) pathways from reactant to product states…

Statistical Mechanics · Physics 2023-10-03 Paul C Bressloff

We consider sequential state and parameter learning in state-space models with intractable state transition and observation processes. By exploiting low-rank tensor train (TT) decompositions, we propose new sequential learning methods for…

Numerical Analysis · Mathematics 2024-07-04 Yiran Zhao , Tiangang Cui

The prediction of organic reaction outcomes is a fundamental problem in computational chemistry. Since a reaction may involve hundreds of atoms, fully exploring the space of possible transformations is intractable. The current solution…

Machine Learning · Computer Science 2018-01-01 Wengong Jin , Connor W. Coley , Regina Barzilay , Tommi Jaakkola

Rare events such as conformational changes in biomolecules, phase transitions, and chemical reactions are central to the behavior of many physical systems, yet they are extremely difficult to study computationally because unbiased…

Machine Learning · Statistics 2026-04-16 Yuanqi Du , Jiajun He , Dinghuai Zhang , Eric Vanden-Eijnden , Carles Domingo-Enrich

Finetuning pretrained models occurs in a low-dimensional subspace of the full parameter space. Prior work has focused on characterizing this optimization subspace, but largely ignored the complementary question: why do certain directions…

Machine Learning · Computer Science 2026-05-11 Junjie Yu , Yue Wang , Zihan Deng , Yan Zhu , Wenxiao Ma , Quanying Liu

In this paper, we consider the supervised pre-trained transformer for a class of sequential decision-making problems. The class of considered problems is a subset of the general formulation of reinforcement learning in that there is no…

Machine Learning · Computer Science 2024-10-03 Hanzhao Wang , Yu Pan , Fupeng Sun , Shang Liu , Kalyan Talluri , Guanting Chen , Xiaocheng Li

Deploying generative machine learning techniques to generate novel chemical structures based on molecular fingerprint representation has been well established in molecular design. Typically, sequential learning (SL) schemes such as hidden…

Biomolecules · Quantitative Biology 2022-04-07 Mohammad Sajjad Ghaemi , Karl Grantham , Isaac Tamblyn , Yifeng Li , Hsu Kiang Ooi

Large Language Models (LLMs) have the potential to accelerate small molecule drug design due to their ability to reason about information from diverse sources and formats. However, their practical utility remains unclear due to the lack of…

With the recent advances in machine learning for quantum chemistry, it is now possible to predict the chemical properties of compounds and to generate novel molecules. Existing generative models mostly use a string- or graph-based…

Biomolecules · Quantitative Biology 2020-10-14 Vitali Nesterov , Mario Wieser , Volker Roth

We present a verified computational model of the SH3 domain transition state (TS) ensemble. This model was built for three separate SH3 domains using experimental s in all-atom protein folding simulations. While averaging over all…

Biomolecules · Quantitative Biology 2007-05-23 Isaac A. Hubner , Katherine A. Edmonds , Eugene I. Shakhnovich