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Atomic carbon ([CI]) is a key species in the carbon chemistry of the interstellar medium (ISM). Using the Submillimeter Wave Astronomy Satellite (SWAS), we conducted a [CI]($^3$P$_1$--$^3$P$_0$) 492 GHz survey covering approximately 4…

Aims. We study the effect of large scale dynamics on the molecular composition of the dense interstellar medium during the transition between diffuse to dense clouds. Methods. We followed the formation of dense clouds (on sub-parsec scales)…

Astrophysics of Galaxies · Physics 2018-04-11 M. Ruaud , V. Wakelam , P. Gratier , I. A. Bonnell

The distribution of molecules between the gas and solid phase during star and planet formation, determines the trajectory of gas and grain surface chemistry, as well as the delivery of elements to nascent planets. This distribution is…

Solar and Stellar Astrophysics · Physics 2022-11-16 Elettra L. Piacentino , Karin I. Öberg

To explain grain growth and destruction in warm media, ice mantle formation and sublimation in cold media, and gas line emission spectroscopy, astrochemical models must mimic the gas--solid abundance ratio. Ice-sublimation mechanisms…

Astrophysics of Galaxies · Physics 2024-04-04 F. Kruczkiewicz , F. Dulieu , A. V. Ivlev , P. Caselli , B. M. Giuliano , C. Ceccarelli , P. Theulé

A new, more comprehensive model of gas-grain chemistry in hot molecular cores is presented, in which nondiffusive reaction processes on dust-grain surfaces and in ice mantles are implemented alongside traditional diffusive surface/bulk-ice…

Astrophysics of Galaxies · Physics 2022-02-23 Robin T. Garrod , Mihwa Jin , Kayla A. Matis , Dylan Jones , Eric R. Willis , Eric Herbst

In spite of accounting for only a small fraction of the mass of the Interstellar Medium (ISM), dust plays a primary role in many physical and chemical processes in the Universe. It is the main driver of extinction of radiation in the…

Astrophysics of Galaxies · Physics 2026-02-12 G. La Mura , G. Mulas , M. A. Iatì , C. Cecchi-Pestellini , S. Rezaei , R. Saija

CO2 ice is one of the most abundant components in ice-coated interstellar ices besides H2O and CO, but the most favorable path to CO2 ice is still unclear. Molecular dynamics calculations on the ultraviolet photodissociation of different…

Chemical Physics · Physics 2015-06-17 Carina Arasa , Marc C. van Hemert , Ewine F. van Dishoeck , Geert-Jan Kroes

This work purports to help understand the InterStellar Extinction Curve in and near the visible range. In this range, crystalline materials are known to be transparent, so amorphous dust is needed. Molecular modeling experiments are used to…

Astrophysics of Galaxies · Physics 2019-05-21 Renaud Papoular

We investigate how the existence of hydrogen molecules on grain surfaces may affect H$_2$ formation efficiency in diffuse and translucent clouds. Hydrogen molecules are able to reduce the desorption energy of H atoms on grain surfaces in…

Astrophysics of Galaxies · Physics 2022-03-30 Gang Zhao , Qiang Chang , Xia Zhang , Donghui Quan , Yong Zhang , Xiao-Hu Li

We devise a physical model of formation and distribution of molecular gas clouds in galaxies. We use the model to predict the intensities of rotational transition lines of carbon monoxide (CO) and the molecular hydrogen (H$_{\rm 2}$)…

Astrophysics of Galaxies · Physics 2020-10-14 Shigeki Inoue , Naoki Yoshida , Hidenobu Yajima

The motivation to study experimentally CO ice under mimicked interstellar conditions is supported by the large CO gas abundances and ubiquitous presence of CO in icy grain mantles. Upon irradiation in its pure ice form, this highly stable…

Instrumentation and Methods for Astrophysics · Physics 2022-10-31 Cristóbal González Díaz , Hector Carrascosa , Guillermo M. Muñoz Caro , Miguel Ángle Satorre , Y. -J. Chen

Detailed modeling of stellar evolution requires a better understanding of the (magneto-)hydrodynamic processes which mix chemical elements and transport angular momentum. Understanding these pro- cesses is crucial if we are to accurately…

Solar and Stellar Astrophysics · Physics 2017-10-11 T. M. Rogers , J. N. McElwaine

Astrochemistry has been widely developed as a power tool to probe physical properties of the interstellar medium (ISM) in various conditions of the Milky Way (MW) Galaxy, and in near and distant galaxies. Most current studies conventionally…

We use 3D-PDR, a three-dimensional astrochemistry code for modeling photodissociation regions (PDRs), to post-process hydrodynamic simulations of turbulent, star-forming clouds. We focus on the transition from atomic to molecular gas, with…

Solar and Stellar Astrophysics · Physics 2015-06-15 Stella S. R. Offner , Thomas G. Bisbas , Serena Viti , Thomas A. Bell

Context. Ice lines are suggested to play a significant role in grain growth and planetesimal formation in protoplanetary disks. Evaporation fronts directly influence the gas and ice abundances of volatile species in the disk and therefore…

Earth and Planetary Astrophysics · Physics 2017-04-19 Sebastian Markus Stammler , Tilman Birnstiel , Olja Panić , Cornelis Petrus Dullemond , Carsten Dominik

Convenient variational formula for collective diffusion of many particles adsorbed at lattices of arbitrary geometry is formulated. The approach allows to find the expressions for the diffusion coefficient for any value of the system's…

Statistical Mechanics · Physics 2018-07-04 Marcin Mińkowski , Magdalena A. Załuska--Kotur

Starless molecular cores are natural laboratories for interstellar molecular chemistry research. The chemistry of ices in such objects was investigated with a three-phase (gas, surface, and mantle) model. We considered the center part of…

Astrophysics of Galaxies · Physics 2015-04-24 Juris Kalvans

Carbon monoxide (CO) is a poor tracer of H$_{2}$ in the diffuse interstellar medium (ISM), where most of the carbon is not incorporated into CO molecules unlike the situation at higher extinctions. We present a novel, indirect method to…

Astrophysics of Galaxies · Physics 2023-12-18 Raphael Skalidis , Paul F. Goldsmith , Philip F. Hopkins , Sam B. Ponnada

Binding energy (BE) is a critical parameter in astrochemical modeling, governing the retention of species on interstellar dust grains and their subsequent chemical evolution. However, conventional models often rely on single-valued BEs,…

Astrophysics of Galaxies · Physics 2025-09-03 Arghyadeb Roy , Ankan Das , Milan Sil , Prasanta Gorai , Kenji Furuya , Naoki Nakatani , Takashi Shimonishi