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A solid-state feature was detected at around 2175 cm-1 towards 30 embedded young stellar objects in spectra obtained using the ESO VLT-ISAAC. We present results from laboratory studies of CO adsorbed at the surface of Zeolite wafers, where…

The interaction of carbon atoms with solid carbon monoxide (CO) is a fundamental process in astrochemistry, influencing the formation of complex organic molecules in interstellar environments. This study investigates the adsorption and…

Astrophysics of Galaxies · Physics 2025-09-23 Masashi Tsuge , Germán Molpeceres , Ryota Ichimura , Hideko Nomura , Kenji Furuya , Naoki Watanabe

Experimental results on the formation of molecular hydrogen on amorphous silicate surfaces are presented and analyzed using a rate equation model. The energy barriers for the relevant diffusion and desorption processes are obtained. They…

We measured the binding energy of N$_2$, CO, O$_2$, CH$_4$, and CO$_2$ on non-porous (compact) amorphous solid water (np-ASW), of N$_2$ and CO on porous amorphous solid water (p-ASW), and of NH$_3$ on crystalline water ice. We were able to…

Instrumentation and Methods for Astrophysics · Physics 2016-07-13 Jiao He , Kinsuk Acharyya , Gianfranco Vidali

CO is one of the most abundant ice components on interstellar dust grains. When it is mixed with amorphous solid water (ASW) or located on its surface, an absorption band of CO at 2152 cm$^{-1}$ is always present in laboratory measurements.…

Instrumentation and Methods for Astrophysics · Physics 2022-12-14 Jiao He , Giulia Perotti , Shahnewaz M. Emtiaz , Francis E. Toriello , Adwin Boogert , Thomas Henning , Gianfranco Vidali

Within the framework of The Heterogeneous dust Evolution Model at the IaS (THEMIS) this work investigates in detail the surface processes and chemistry relating to core/mantle interstellar and cometary grain structures and its influence on…

Astrophysics of Galaxies · Physics 2021-11-09 A. P. Jones

At the low temperatures of interstellar dust grains, it is well established that surface chemistry proceeds via diffusive mechanisms of H atoms weakly bound (physisorbed) to the surface. Until recently, however, it was unknown whether atoms…

Astrophysics of Galaxies · Physics 2014-06-06 E. Congiu , M. Minissale , S. Baouche , H. Chaabouni , A. Moudens , S. Cazaux , G. Manicò , V. Pirronello , F. Dulieu

Water (H2O) ice is ubiquitous component of the universe, having been detected in a variety of interstellar and Solar System environments where radiation plays an important role in its physico-chemical transformations. Although the radiation…

The dissolution and subsequent mass transfer of carbon dioxide gas into liquid barriers plays a vital role in many environmental and industrial applications. In this work, we study the downward dissolution and propagation dynamics of CO2…

The presence of dust can strongly affect the chemical composition of the interstellar medium. We model the chemistry in photodissociation regions (PDRs) using both gas-phase and dust-phase chemical reactions. Our aim is to determine the…

Astrophysics of Galaxies · Physics 2016-06-22 G. B. Esplugues , S. Cazaux , R. Meijerink , M. Spaans , P. Caselli

AIM: We have recently developed a microscopic Monte Carlo approach to study surface chemistry on interstellar grains and the morphology of ice mantles. The method is designed to eliminate the problems inherent in the rate-equation formalism…

Astrophysics · Physics 2009-11-13 Q. Chang , H. M. Cuppen , E. Herbst

The results of experiments on the formation of molecular hydrogen on low density and high density amorphous ice surfaces are analyzed using a rate equation model. The activation energy barriers for the relevant diffusion and desorption…

Binding energies (BEs) of adsorbates on interstellar dust grains critically control adsorption, desorption, diffusion, and surface reactivity, and therefore strongly influence astrochemical models of star- and planet-forming regions. While…

Chemical Physics · Physics 2026-02-12 Anant Vaishnav , Niels M. Mikkelsen , Mie Andersen

Ice is ubiquitous in the interstellar medium. We model the formation of the main constituents of interstellar ices, including H2O, CO2 , CO, and CH3 OH. We strive to understand what physical or chemical parameters influence the final…

Astrophysics of Galaxies · Physics 2023-07-26 A. Clément , A. Taillard , V. Wakelam , P. Gratier , J. -C. Loison , E. Dartois , F. Dulieu , J. A. Noble , M. Chabot

Processing by interstellar photons affects the composition of the icy mantles on interstellar grains. The rate of photodissociation in solids differs from that of molecules in the gas phase. The aim of this work was to determine an average,…

Astrophysics of Galaxies · Physics 2018-05-16 Juris Kalvans

Nearby dwarf irregular galaxies are ideal laboratories for studying the interstellar medium (ISM) at low metallicity, which is expected to be common for galaxies at very high redshift being observed by the James Webb Space Telescope. We…

Astrophysics of Galaxies · Physics 2023-08-02 Chia-Yu Hu , Amiel Sternberg , Ewine F. van Dishoeck

One believed path to Interstellar Complexes Organic Molecules (iCOMs) formation inside the Interstellar Medium (ISM) is through chemical recombination at the surface of amorphous solid water (ASW) mantle covering the silicate-based core of…

Chemical Physics · Physics 2020-09-25 Aurèle Germain , Piero Ugliengo

The activation energy for desorption (Edes) and that for surface diffusion (Esd) of adsorbed molecules on dust grains are two of the most important parameters for the chemistry in the interstellar medium. Although Edes is often measured by…

Astrophysics of Galaxies · Physics 2022-07-20 Kenji Furuya , Tetsuya Hama , Yasuhiro Oba , Akira Kouchi , Naoki Watanabe , Yuri Aikawa

Emission from carbon monoxide (CO) is ubiquitously used as a tracer of dense star forming molecular clouds. There is, however, growing evidence that a significant fraction of CO emission originates from diffuse molecular gas. Quantifying…

Astrophysics of Galaxies · Physics 2016-03-09 Julia Roman-Duval , Mark Heyer , Christopher Brunt , Paul Clark , Ralf Klessen , Rahul Shetty

Physisorbed atoms on the surface of interstellar dust grains play a central role in solid state astrochemistry. Their surface reactivity is one source of the observed molecular complexity in space. In experimental astrophysics, the high…

Solar and Stellar Astrophysics · Physics 2016-03-10 Marco Minissale , Emanuele Congiu , François Dulieu