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A two-electron one-dimensional model of a heteroatomic molecule composed of two open-shell atoms is considered. Including only two electrons isolates and examines the effect that the highest occupied molecular orbital has on the Kohn-Sham…

Materials Science · Physics 2010-03-22 David G. Tempel , Todd J. Martinez , Neepa T. Maitra

Real-time time-dependent density functional theory, in conjunction with the Ehrenfest molecular dynamics scheme, is becoming a popular methodology to investigate ultrafast phenomena on the nanoscale. Thanks to recent developments, it is…

Materials Science · Physics 2020-08-18 Jannis Krumland , Ana M. Valencia , Stefano Pittalis , Carlo A. Rozzi , Caterina Cocchi

We follow the emergence of quantum entanglement in a scattering event between two initially uncorrelated distinguishable quantum particles interacting via a delta potential. We calculate the time dependence of the Neumann entropy of the…

Quantum Physics · Physics 2015-05-30 Mihaly G. Benedict , Judit Kovacs , Attila Czirjak

We derive quantum kinetic equations for fermions in a homogeneous time-dependent background in presence of decohering collisions, by use of the Schwinger-Keldysh CTP-formalism. The quantum coherence (between particles and antiparticles) is…

High Energy Physics - Phenomenology · Physics 2009-03-24 Matti Herranen , Kimmo Kainulainen , Pyry Matti Rahkila

We formulate a theory of low-temperature, stationary photoluminescence from a quantum-dot molecule composed of two spherical quantum dots whose electronic subsystems are resonantly coupled via the Coulomb interaction. We show that the…

Mesoscale and Nanoscale Physics · Physics 2016-08-05 S. Yu. Kruchinin , I. D. Rukhlenko , A. S. Baimuratov , M. Yu. Leonov , V. K. Turkov , Yu. K. Gun'ko , A. V. Baranov , A. V. Fedorov

By means of quantum mechanics and quantum electrodynamics applied to coupled harmonic Drude oscillators, we study the interaction between two neutral atoms or molecules subject to a uniform static electric field. Our focus is to understand…

Chemical Physics · Physics 2022-03-16 Mohammad Reza Karimpour , Dmitry V. Fedorov , Alexandre Tkatchenko

We investigate (non-relativistic) atomic systems interacting with quantum electromagnetic field (QEF). The resulting model describes spontaneous emission of light from a two-level atom surrounded by various initial states of the QEF. We…

Quantum Physics · Physics 2009-11-10 P. Marecki , N. Szpak

Cavity-mediated light-matter coupling can dramatically alter opto-electronic and physico-chemical properties of a molecule. Ab initio theoretical predictions of these systems need to combine non-perturbative, many-body electronic structure…

Quantum Physics · Physics 2024-06-19 Derek S. Wang , Tomáš Neuman , Johannes Flick , Prineha Narang

A relativistic density-functional theory based on a Fock-space effective quantum-electrodynamics (QED) Hamiltonian using the Coulomb or Coulomb-Breit two-particle interaction is developed. This effective QED theory properly includes the…

Chemical Physics · Physics 2021-05-03 Julien Toulouse

The dynamics of strongly interacting trapped dilute Fermi gases (dilute in the sense that the range of interatomic potential is small compared with inter-particle spacing) is investigated in a single-equation approach to the time-dependent…

Soft Condensed Matter · Physics 2009-02-05 Yeong E. Kim , Alexander L. Zubarev

The quantum entanglement phenomenon was demonstrated to operate on a bipartite entangled system composed of two single layers of graphene embedded in an electrolytic medium (which did not permit the transport of electrons) and subjected to…

General Physics · Physics 2024-10-17 David A. Miranda , Edgar F. Pinzón , Paulo R. Bueno

Adiabatic time-dependent density functional theory fails for excitations of a heteroatomic molecule composed of two open-shell fragments at large separation. Strong frequency-dependence of the exchange-correlation kernel is necessary for…

Other Condensed Matter · Physics 2009-11-11 Neepa T. Maitra , David G. Tempel

We present an effective theory for describing electron dynamics driven by an optical external field in a Schr\"{o}dinger's cat state. We show that the electron density matrix evolves as an average over trajectories $\{\rho_\alpha\}$…

Quantum Physics · Physics 2025-01-29 Shohei Imai , Atsushi Ono , Naoto Tsuji

Systems whose underlying classical dynamics are chaotic exhibit signatures of the chaos in their quantum mechanics. We investigate the possibility of using time-dependent density functional theory (TDDFT) to study the case when chaos is…

Other Condensed Matter · Physics 2009-11-13 Adam Wasserman , Neepa T. Maitra , Eric J. Heller

The Hamiltonian conservative system of two interacting particles has been considered both in classical and quantum description. The quantum model has been realized using a symmetrized two-particle basis reordered in the unperturbed energy.…

chao-dyn · Physics 2009-10-30 Fausto Borgonovi , Italo Guarneri , Felix Izrailev

We study a general problem of the translational/rotational/vibrational/electronic dynamics of a diatomic molecule exposed to an interaction with an arbitrary external electromagnetic field. The theory developed in this paper is relevant to…

Quantum Physics · Physics 2016-09-28 Milan Sindelka , Nimrod Moiseyev

Time-dependent density functional theory (TDDFT) is a standard approach for calculating optical excitations of molecules and solids, while ensemble DFT (EDFT) is a promising alternative under development. We introduce ensemble TDDFT…

Chemical Physics · Physics 2026-05-22 Kimberly J. Daas , Steven Crisostomo , Kieron Burke

We present a self-contained theoretical and computational framework for dynamics following photoexcitation in quantum dots near planar interfaces. A microscopic Hamiltonian parameterized by first principles calculations is merged with a…

Mesoscale and Nanoscale Physics · Physics 2015-06-15 Kuljit S. Virk , Mark S. Hybertsen , David R. Reichman

A time-dependent theory for the interactions between spatially separated lossy cavities in a homogeneous background medium using quantized quasinormal modes (QNMs) is presented. The cavities interact via a bath of traveling photons,…

Mesoscale and Nanoscale Physics · Physics 2026-04-15 Robert Meiners Fuchs , Juanjuan Ren , Sebastian Franke , Stephen Hughes , Marten Richter

This paper studies the model of the quantum electrodynamics (QED) of a single nonrelativistic electron due to W. Pauli and M. Fierz and studied further by P. Blanchard. This model exhibits infrared divergence in a very simple context. The…

High Energy Physics - Theory · Physics 2022-10-12 O. W. Greenberg