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We present a comprehensive theory for a novel method to discretize the spectral density of a bosonic heat bath, as introduced in [H. Takahashi and R. Borrelli, J. Chem. Phys. \textbf{161}, 151101 (2024)]. The approach leverages a low-rank…

Quantum Physics · Physics 2024-12-19 Hideaki Takahashi , Raffaele Borrelli

Optimal control theory is implemented with fully converged hierarchical equations of motion (HEOM) describing the time evolution of an open system density matrix strongly coupled to the bath in a spin-boson model. The populations of the…

A well-known approach to describe the dynamics of an open quantum system is to compute the master equation evolving the reduced density matrix of the system. This approach plays an important role in describing excitation transfer through…

Quantum Physics · Physics 2022-10-25 Kimara Naicker , Ilya Sinayskiy , Francesco Petruccione

The transfer tensor method (TTM) [Cerrillo and Cao, Phys. Rev. Lett. 2014, 112, 110401] can be considered a discrete-time formulation of the Nakajima-Zwanzig quantum master equation (NZ-QME) for modeling non-Markovian quantum dynamics. A…

Quantum Physics · Physics 2025-07-30 Ruojing Peng , Lachlan P. Lindoy , Joonho Lee

The hybrid tensor network (HTN) method is a general framework allowing for the construction of an effective wavefunction with the combination of classical tensors and quantum tensors, i.e., amplitudes of quantum states. In particular,…

Quantum Physics · Physics 2025-08-08 Hiroyuki Harada , Yasunari Suzuki , Bo Yang , Yuuki Tokunaga , Suguru Endo

We introduce a general numerical method to compute dynamics and multi-time correlations of chains of quantum systems, where each system may couple strongly to a structured environment. The method combines the process tensor formalism for…

Quantum Physics · Physics 2023-08-16 Gerald E. Fux , Dainius Kilda , Brendon W. Lovett , Jonathan Keeling

We present a new, computationally inexpensive method for the calculation of reduced density matrix dynamics for systems with a potentially large number of subsystem degrees of freedom coupled to a generic bath. The approach consists of…

Chemical Physics · Physics 2015-12-09 Andrés Montoya-Castillo , Timothy C. Berkelbach , David R. Reichman

An exact method to compute the entire equilibrium reduced density matrix for systems characterized by a system-bath Hamiltonian is presented. The approach is based upon a stochastic unraveling of the influence functional that appears in the…

Mesoscale and Nanoscale Physics · Physics 2015-06-04 Jeremy M. Moix , Yang Zhao , Jianshu Cao

An open quantum system refers to a system that is further coupled to a bath system consisting of surrounding radiation fields, atoms, molecules, or proteins. The bath system is typically modeled by an infinite number of harmonic…

Chemical Physics · Physics 2020-07-10 Yoshitaka Tanimura

The hierarchical equations of motion technique has found widespread success as a tool to generate the numerically exact dynamics of non-Markovian open quantum systems. However, its application to low temperature environments remains a…

Chemical Physics · Physics 2013-10-15 Jeremy M. Moix , Jianshu Cao

The discretization approximation method commonly used to simulate the dynamics of quantum system coupled to the environment in continuum often suffers from the periodically partial recovery of initial state because of the effect of finite…

Quantum Physics · Physics 2025-05-07 H. T. Cui , Y. A. Yan , M. Qin , X. X. Yi

Time- and frequency resolved optical signals provide insights into the properties of light harvesting molecular complexes, including excitation energies, dipole strengths and orientations, as well as in the exciton energy flow through the…

Chemical Physics · Physics 2018-06-15 Tobias Kramer , Matthias Noack , Alexander Reinefeld , Mirta Rodriguez , Yaroslav Zelinskyy

Dissipaton-equation-of-motion (DEOM) theory [Y. J. Yan, J. Chem. Phys. 140, 054105 (2014)] is an exact and nonperturbative many-particle method for open quantum systems. The existing dissipaton algebra treats also the dynamics of hybrid…

Chemical Physics · Physics 2020-01-24 Yao Wang , Rui-Xue Xu , YiJing Yan

We unite two of the most widely used approaches for strongly damped, non-Markovian open quantum dynamics, the Hierarchical Equations of Motion (HEOM) and the pseudomode method by proving two statements: First, every physical bath…

Quantum Physics · Physics 2026-04-09 Kai Müller , Walter T. Strunz

There is presently considerable interest in accurately simulating the evolution of open systems for which Markovian master equations fail. Examples are systems that are time-dependent and/or strongly damped. A number of elegant methods have…

Quantum Physics · Physics 2014-04-23 Luciano Silvestri , Kurt Jacobs , Vanja Dunjko , Maxim Olshanii

An implicit purification scheme is proposed for calculation of the temperature-dependent, grand canonical single-particle density matrix, given as a Fermi operator expansion in terms of the Hamiltonian. The computational complexity is shown…

Materials Science · Physics 2009-11-10 Anders M. N. Niklasson

First, two examples of 1D distributed port-Hamiltonian systems with dissipation, given in explicit (descriptor) form, are considered: the Dzekster model for the seepage of underground water and a nanorod model with non-local viscous…

Dynamical Systems · Mathematics 2024-02-13 Antoine Bendimerad-Hohl , Denis Matignon , Ghislain Haine , Laurent Lefèvre

This paper extends the previously reported theory of dissipation pathways [J. Chem. Phys. 160, 214111 (2024)] to incorporate off-diagonal subsystem-bath coupling, which is often required to model molecular systems where the environment…

Chemical Physics · Physics 2026-01-26 Ignacio Gustin , Chang Woo Kim , Ignacio Franco

This study presents a novel state estimation approach integrating Deep Neural Networks (DNNs) into Moving Horizon Estimation (MHE). This is a shift from using traditional physics-based models within MHE towards data-driven techniques.…

Systems and Control · Electrical Eng. & Systems 2025-07-29 Alexander Winkler , Pranav Shah , Katrin Baumgärtner , Vasu Sharma , David Gordon , Jakob Andert

Quantum transport and other phenomena are typically modeled by coupling the system of interest to an environment, or bath, held at thermal equilibrium. Realistic bath models are at least as challenging to construct as models for the quantum…