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Aqueous two-phase systems (ATPSs), that is, phase-separating solutions of water soluble but mutually immiscible molecular species, offer fascinating prospects for selective partitioning, purification, and extraction. Here, we formulate a…

Soft Condensed Matter · Physics 2023-11-29 Alberto Scacchi , Carlo Rigoni , Mikko Haataja , Jaakko V. I. Timonen , Maria Sammalkorpi

Molecular dynamics simulation is a prominent way of analyzing the dynamic properties of a system. The molecular dynamics simulation of diffusion, an important transport property, of dilute solution of cysteine in SPCE water at five…

Chemical Physics · Physics 2018-09-25 Hem Prasad Bhusal , Narayan Prasad Adhikari

Oxide-water interfaces govern a wide range of physical and chemical processes fundamental to many fields like catalysis, geochemistry, corrosion, electrochemistry, and sensor technology. Near solid oxide surfaces, water behaves differently…

Chemical Physics · Physics 2025-10-31 Jan Elsner , K Nikolas Lausch , Jörg Behler

Effect of confinement on the liquid-liquid transition of water are studied by simulations in the Gibbs ensemble. Upon cooling along the liquid-vapor coexistence curve, confined water undergoes transition from normal to strongly tetrahedral…

Soft Condensed Matter · Physics 2007-05-23 Ivan Brovchenko , Alla Oleinikova

The steady-state homogeneous vapor-to-liquid nucleation and the succeeding liquid droplet growth process are studied for water system by means of the coarse-grained molecular dynamics simulations with the mW-model suggested originally in…

Soft Condensed Matter · Physics 2012-10-03 Anatolii V. Mokshin , Bulat N. Galimzyanov

Parameter extension simulation (PES) as a mathematical method for simulating turbulent flows has been proposed in the study. It is defined as a calculation of the turbulent flow for the desired parameter values with the help of a reference…

Fluid Dynamics · Physics 2020-01-08 Yan Jin

The progress in high performance computing we are witnessing today offers the possibility of accurate electron density calculations of systems in realistic physico-chemical conditions. In this paper, we present a strategy aimed at…

Soft Condensed Matter · Physics 2018-09-18 Giovanni La Penna , Velia Minicozzi , Silvia Morante , Giancarlo Rossi , Francesco Stellato

Even though atomistic and coarse-grained (CG) models have been used to simulate liquid nanodroplets in vapor, very few rigorous studies of the liquid-liquid interface structure are available, and most of them are limited to planar…

Chemical Physics · Physics 2019-07-16 Peiyuan Gao , Xiu Yang , Alexandre M. Tartakovsky

The interaction of water with Fe$_3$O$_4$(001) is studied by density functional theory (DFT) calculations including an on-site Coulomb term. For isolated molecules dissociative adsorption is strongly promoted at surface defect sites, while…

While several studies confirmed that machine-learned potentials (MLPs) can provide accurate free energies for determining phase stabilities, the abilities of MLPs for efficiently constructing a full phase diagram of multi-component systems…

Computational Physics · Physics 2022-08-26 Kyeongpung Lee , Yutack Park , Seungwu Han

The unique properties exhibited in immiscible metals, such as excellent strength, hardness, and radiation-damage tolerance, have stimulated the interest of many researchers. As a typical immiscible metal system, the Cu-W nano-multilayers…

Materials Science · Physics 2024-07-02 Jiahao Pan , Huiqun Cheng , Gaosheng Yan , Lei Zhang , Wenshan Yu , Shengping Shen

The common-envelope (CE) phase is a crucial stage in binary star evolution because the orbital separation can shrink drastically while ejecting the envelope of a giant star. Three-dimensional (3D) hydrodynamic simulations of CE evolution…

Solar and Stellar Astrophysics · Physics 2023-11-14 V. A. Bronner , F. R. N. Schneider , Ph. Podsiadlowski , F. K. Roepke

The symmetrical restricted Gibbs ensemble (RGE) is a version of the Gibbs ensemble in which particles are exchanged between two boxes of fixed equal volumes. It has recently come to prominence because -- when combined with specialized…

Statistical Mechanics · Physics 2015-05-14 Douglas J. Ashton , Nigel B. Wilding , Peter Sollich

We present a scaled particle density functional study of two-dimensional binary mixtures of hard convex particles with one or both species being ellipses. In particular, we divide our study into two parts. The first part is devoted to the…

Soft Condensed Matter · Physics 2022-06-07 Yuri Martinez-Raton

First principles molecular dynamics simulation protocol is established using revised functional of Perdew-Burke-Ernzerhof (revPBE) in conjunction with Grimme's third generation of dispersion (D3) correction to describe properties of water…

In fluid dynamics, an important problem is linked to the knowledge of the fluid pressure. Recently, another approach to study incompressible fluid flow was suggested. It consists in using a general pressure equation (GPE) derived from…

Fluid Dynamics · Physics 2020-05-14 Adrien Toutant

The hard-sphere potential has become a cornerstone in the study of both molecular and complex fluids. Despite its mathematical simplicity, its implementation in fixed time-step molecular simulations remains a formidable challenge due to the…

Soft Condensed Matter · Physics 2025-04-21 Edwin A. Bedolla-Montiel , Ramón A. Castañeda-Cerdán , Ramón Castañeda-Priego

The accurate description of iron oxides/water interfaces requires reliable force field parameters that can be developed through the comparison with sophisticated quantum mechanical calculations. Here a set of CLASS2 force field parameters…

Materials Science · Physics 2021-12-07 Paulo Siani , Enrico Bianchetti , Hongsheng Liu , Cristiana Di Valentin

Molecular simulations have provided valuable insight into the microscopic mechanisms underlying homogeneous ice nucleation. While empirical models have been used extensively to study this phenomenon, simulations based on first-principles…

Free-energy differences between pairs of end-states can be estimated based on molecular dynamics (MD) simulations using standard pathway-dependent methods such as thermodynamic integration (TI), free-energy perturbation, or Bennett's…

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