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Understanding and simulating the thermodynamic and dynamical properties of materials affected by strong ionic anharmonicity is a central challenge in material science. Much interest is in material displaying critical displacive behaviour,…

Materials Science · Physics 2025-04-18 Lorenzo Monacelli

Phonon interactions from lattice anharmonicity govern thermal properties and heat transport in materials. These interactions are described by n-th order interatomic force constants (n-IFCs), which can be viewed as high-dimensional tensors…

Materials Science · Physics 2025-08-12 Yao Luo , Dhruv Mangtani , Shiyu Peng , Jia Yao , Sergei Kliavinek , Marco Bernardi

The inelastic nature of 3-phonon processes is investigated within the framework of perturbation theory and linearized Boltzmann Transport Equation. By considering the energy conservation rule governing this type of interactions in a…

Materials Science · Physics 2017-09-07 Ahmed Hamed , Anter El-Azab

It is textbookly regarded that phonons, i.e., an energy quantum of propagating lattice waves, are the main heat carriers in perfect crystals. As a result, in many crystals, e.g., bulk silicon, the temperature-dependent thermal conductivity…

Materials Science · Physics 2020-09-18 Yanguang Zhou , Yufei Gao , Sebastian Volz

We report a Raman study of the effect of temperature on the self-energies of optical phonons in a number of transition metals with hexagonal-close-packed structure. Anisotropic softening of phonon energies and narrowing of phonon linewidths…

Materials Science · Physics 2017-01-04 Yu. S. Ponosov , S. V. Streltsov

In recent years, nanostructuring of dielectric and semiconducting crystals has enhanced controllability of their thermal conductivity. To carry out computational material search for nanostructured materials with desirable thermal…

Mesoscale and Nanoscale Physics · Physics 2016-02-23 Takuma Shiga , Daisuke Aketo , Lei Feng , Junichiro Shiomi

Lattice vibration frequencies are related to many important materials properties such as thermal and electrical conductivity as well as superconductivity. However, computational calculation of vibration frequencies using density functional…

Materials Science · Physics 2021-11-12 Nghia Nguyen , Steph-Yves Louis , Lai Wei , Kamal Choudhary , Ming Hu , Jianjun Hu

Phonon coherence elucidates the propagation and interaction of phonon quantum states within superlattice, unveiling the wave-like nature and collective behaviors of phonons. Taking MoSe$_2$/WSe$_2$ lateral heterostructures as a model…

Materials Science · Physics 2025-03-11 Xin Wu , Zhang Wu , Ting Liang , Zheyong Fan , Jianbin Xu , Masahiro Nomura , Penghua Ying

The phonon density-of-states (DOS) summarizes the lattice vibrational modes supported by a structure, and gives access to rich information about the material's stability, thermodynamic constants, and thermal transport coefficients. Here, we…

Materials Science · Physics 2022-07-27 Ramya Gurunathan , Kamal Choudhary , Francesca Tavazza

Machine-learning interatomic potentials are widely used as computationally efficient surrogates for density functional theory in atomistic simulations, enabling large-scale, long-time modeling of materials systems. We investigate how…

Materials Science · Physics 2026-04-13 Jonas Grandel , Philipp Benner , Janine George

In this work, we investigate the microscopic mechanisms of anharmonic lattice dynamics and thermal transport in lead-free halide double perovskite Cs2AgBiBr6 from first principles. We combine self-consistent phonon calculations with bubble…

Materials Science · Physics 2024-02-09 Jiongzhi Zheng , Changpeng Lin , Chongjia Lin , Geoffroy Hautier , Ruiqiang Guo , Baoling Huang

Many complex crystals show a flattening or even increasing lattice thermal conductivity at high temperatures, which deviates from the traditional 1/T decay trend given by conventional phonon theory. In this work, we predict the thermal…

Materials Science · Physics 2023-12-20 Janak Tiwari , Tianli Feng

Although extensive experimental and theoretical works have been conducted to understand the ballistic and diffusive phonon transport in nanomaterials recently, direct observation of temperature and thermal nonequilibrium of different phonon…

Mesoscale and Nanoscale Physics · Physics 2017-05-17 Tianli Feng , Wenjun Yao , Zuyuan Wang , Jingjing Shi , Chuang Li , Bingyang Cao , Xiulin Ruan

Phonons are the primary heat carriers in non-metallic solids. In compositionally heterogeneous materials, the thermal properties are believed to be mainly governed by the disrupted phonon transport due to mass disorder and strain…

Phonons, the quanta of lattice vibrations, are primary heat carriers for semiconductors and dielectrics. The demand of effective phonon manipulation urgently emerges, because the thermal management is crucial for the ongoing development of…

We study the impact of phonon anharmonicity on the electronic dynamics of soft materials using a nonperturbative quantum-classical approach. The method is applied to a one-dimensional model of doped organic semiconductors with low-frequency…

Materials Science · Physics 2025-09-24 Jonathan H. Fetherolf , Petra Shih , Timothy C. Berkelbach

Problems of heat transport are ubiquitous to various technologies such as power generation, cooling, electronics, and thermoelectrics. In this paper we advocate for the application of the quantum self-consistent reservoir method, which is…

Mesoscale and Nanoscale Physics · Physics 2019-01-30 Roya Moghaddasi Fereidani , Dvira Segal

In the quest for stable 2D arsenic phases, four different structures have been recently claimed to be stable. We show that, due to phonon contributions, the relative stability of those structures differs from previous reports and depends…

Materials Science · Physics 2017-03-13 Jesús Carrete , Luis J. Gallego , Natalio Mingo

To elucidate the relationship between a crystal's structure, its thermal conductivity, and its phonon dispersion characteristics, an analysis is conducted on layered diatomic Lennard-Jones crystals with various mass ratios. Lattice dynamics…

Materials Science · Physics 2007-05-23 A. J. H. McGaughey , M. I. Hussein , E. S. Landry , M. Kaviany , G. M. Hulbert

Harmonic calculations based on density-functional theory are generally the method of choice for the description of phonon spectra of metals and insulators. The inclusion of anharmonic effects is, however, delicate as it relies on…

Materials Science · Physics 2015-06-17 Ion Errea , Matteo Calandra , Francesco Mauri