Related papers: Functionalization of Benzene Ices by Atomic Oxygen
Simple and complex organic molecules (COMs) are observed along different phases of star and planet formation and have been successfully identified in prestellar environments such as dark and translucent clouds. Yet the picture of organic…
Recent laboratory experiments have demonstrated that, even though contribution from other reaction channels cannot be neglected, unsaturated hydrocarbons easily break their multiple C-C bonds to form CO after their interactions with atomic…
The recent observation of complex organic molecules (COMs) in interstellar ices by the James Webb Space Telescope (JWST), along with previous gas-phase detections, underscores the importance of grain surface and ice mantle chemistry in the…
N-carbophenes are a class of two-dimensional covalent organic frameworks with potential for solid-state gas storage and as 2D topological materials. Previous studies have demonstrated that variations in their bonding, topology, and…
Observational efforts in the last decade suggest the prevalence of photochemical hazes in exoplanetary atmospheres. Recent JWST observations raise growing evidence that exoplanetary hazes tend to have reflective compositions, unlike the…
We present a chemical kinetics model of the solid-phase chemical evolution of a comet, beginning with a long period of cold-storage in the Oort Cloud, followed by five orbits that bring the comet close to the Sun. The chemical model is…
Alice ultraviolet spectrometer onboard Rosetta space mission observed several spectroscopic emissions emanated from volatile species of comet 67P/Churyumov-Gerasimenko (hear after 67P/C-G) during its entire escorting phase. We have…
The catalytic activities of the atomic Y-, Ru-, At-, In-, Pd-, Ag-, Pt-, and Os- ions have been investigated theoretically using the atomic Au- ion as the benchmark for the selective partial oxidation of methane to methanol without CO2…
Iron manganese trioxide (Fe0.25Mn0.75)2O3 nanocrystals were synthesized by the sol-gel method. The 80 K Mossbauer spectrum was well-fitted using two doublets representing the 8b and 24d crystallographic sites of the (FexMn1-x)2O3 phase and…
Photochemistry induced by stellar UV flux should produce haze particles in exoplanet atmospheres. Recent observations indicate that haze and/or cloud layers exist in the atmospheres of exoplanets. However, photochemical processes in…
A new chemical model is presented that simulates fully-coupled gas-phase, grain-surface and bulk-ice chemistry in hot cores. Glycine (NH2CH2COOH), the simplest amino acid, and related molecules such as glycinal, propionic acid and propanal,…
Benzonitrile (c-C6H5CN) has been recently detected in cold and dense regions of the interstellar medium (ISM), where it has been used as a signpost of a rich aromatic organic chemistry that might lead to the production of polycyclic…
The C$_4$F$_7$N/CO$_2$/O$_2$ gas mixture is the most promising eco-friendly gas insulation medium available. However, there are few studies on the mechanism of the influence of the buffer gas O2 ratio and its role in the decomposition…
Icy mantles of benzonitrile, an aromatic with a cyanide side chain that has recently been detected in the interstellar medium, were subjected to vacuum ultraviolet photon irradiation and found to form a residue. The residue was removed from…
Neptune remains a mysterious world that deserves further exploration and is a high-priority objective for a future planetary mission in order to better understand the formation and evolution of ice giant planets. We have developed a coupled…
We present an interferometric and single dish study of small organic species toward Comets C/1995 O1 (Hale-Bopp) and C/2002 T7 (LINEAR) using the BIMA interferometer at 3 mm and the ARO 12m telescope at 2 mm. For Comet Hale-Bopp, both the…
The interaction between dust, ice, and gas during the formation of stars produces complex organic molecules. While observations indicate that several species are formed on ice-covered dust grains and are released into the gas phase, the…
Comets and small Kuiper belt objects are considered to be among the most primitive objects in the solar system as comets like C/1995 O1 Hale-Bopp are rich in highly volatile ices like CO. It has been suggested that early in the solar system…
Alternative synthetic fuels can be produced by renewable energy sources and represent a potential route for solving long-term energy storage. Among them, oxygenated fuels have the advantage of significantly reducing pollutant emissions and…
Little is known about oxygen-related defects in diamond. Recently, the promising room-temperature spin centre named ST1 was identified as an oxygen centre, but of still unknown atomic structure and thermal stability. In this work, we report…