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Understanding the kinetic selectivity of carbon nanotube growth at the scale of individual nanotubes is essential for the development of high chiral selectivity growth methods. Here we demonstrate that homodyne polarization microscopy can…

Carbon nanotubes have properties depending on the arrangement of carbon atoms on the tube walls, called chirality. Also it has been tried to grow nanotubes of only one chirality for more than a decade it is still not possible today. A…

Materials Science · Physics 2013-05-02 Heiko Dumlich , John Robertson , Stephanie Reich

Single-walled carbon nanotubes have been a candidate for outperforming silicon in ultrascaled transistors, but the realization of nanotube-based integrated circuits requires dense arrays of purely semiconducting species. Control over…

Applied Physics · Physics 2022-04-27 K. Otsuka , R. Ishimaru , A. Kobayashi , T. Inoue , R. Xiang , S. Chiashi , Y. K. Kato , S. Maruyama

Single-walled carbon nanotubes exist in a variety of different geometries, so-called chiralities, that define their electronic properties. Chiral selectivity has been reported in catalytic chemical vapor deposition synthesis experiments,…

Mesoscale and Nanoscale Physics · Physics 2024-06-12 Georg Daniel Förster , Thomas D. Swinburne , Hua Jiang , Esko Kauppinen , Christophe Bichara

Single-walled carbon nanotubes are hollow cylinders, that can grow centimeters long by carbon incorporation at the interface with a catalyst. They display semi-conducting or metallic characteristics, depending on their helicity, that is…

Materials Science · Physics 2018-11-14 Yann Magnin , Hakim Amara , François Ducastelle , Annick Loiseau , Christophe Bichara

We consider geometric constraints for the addition of carbon atoms to the rim of a growing nanotube. The growth of a tube proceeds through the conversion of dangling bonds from armchair to zigzag and vice versa. We find that the growth rate…

Materials Science · Physics 2012-07-20 Heiko Dumlich , Stephanie Reich

Carbon nanotubes (CNT) hold enormous technological promise. It can only be harnessed if one controls in a practical way the CNT chirality, the feature of the tubular carbon topology that governs all the CNT properties---electronic, optical,…

Materials Science · Physics 2014-09-18 Vasilii I. Artyukhov , Evgeni S. Penev , Boris I. Yakobson

Recent direct measurements of the growth kinetics of individual carbon nanotubes revealed abrupt changes in the growth rate of nanotubes maintaining the same crystal structure. These stochastic switches call into question the possibility of…

Mesoscale and Nanoscale Physics · Physics 2023-02-24 Georg Daniel Förster , Vladimir Pimonov , Huy-Nam Tran , Saïd Tahir , Vincent Jourdain , Christophe Bichara

Chemical vapor deposition synthesis of single-walled carbon nanotubes experiments, using Fe catalyst, and alternating methane and carbon monoxide as carbon feedstocks, lead to the reversible formation of junctions between tubes of different…

We have assigned the chirality of the internal tubes of double walled carbon nanotubes grown by catalytic chemical vapor deposition using the high sensitivity of the radial breathing mode (RB) in inelastic light scattering experiments. The…

Materials Science · Physics 2009-11-07 R. R. Bacsa , A. Peigney , Ch. Laurent , P. Puech , W. S. Bacsa

The selective etching of carbon nanotubes has been widely explored as a post-synthetic route for enriching semiconducting species. As nanoelectronic applications increasingly demand pure semiconducting nanotubes for use in field-effect…

Materials Science · Physics 2025-06-26 K. Otsuka , S. Maruyama

Two paramount challenges in carbon nanotube research are achieving chirality-controlled synthesis and understanding chirality-dependent device physics. High-throughput and in-situ chirality and electronic structural characterization of…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 Kaihui Liu , Xiaoping Hong , Qin Zhou , Chenhao Jin , Jinghua Li , Weiwei Zhou , Jie Liu , Enge Wang , Alex Zettl , Feng Wang

The electronic properties of carbon nanotubes are governed by their chirality, specified by the integer indices (n,m). While chirality-controlled synthesis has achieved notable successes, theoretical understanding remains predominantly…

Mesoscale and Nanoscale Physics · Physics 2025-11-12 Zhengrong Guo

Optimized growth of Single Wall Carbon Nanotubes requires a full knowledge of the actual state of the catalyst nanoparticle and its interface with the tube. Using Tight Binding based atomistic computer simulations, we calculate carbon…

Materials Science · Physics 2015-06-05 Mamadou Diarra , Alexandre Zappelli , Hakim Amara , François Ducastelle , Christophe Bichara

Carbon nanotube (CNT) is expected for much more important and broader applications in the future, because of its amazing electrical and mechanical properties. However, today, the prospect is detained by the fact that the growth of CNTs…

Materials Science · Physics 2007-05-23 Shuang Zhang , Takeo Hoshi , Takeo Fujiwara

The origin of the chirality of single-walled carbon nanotubes (SWCNTs) has been a long-standing dispute. Molecular dynamics (MD) simulations driven by machine-learning force fields (MLFF), which can study the interface dynamics under near…

Mesoscale and Nanoscale Physics · Physics 2025-03-06 Sida Sun , Shigeo Maruyama , Yan Li

There is an emerging recognition that successful utilization of chiral degrees of freedom can bring new scientific and technological opportunities to diverse research areas. Hence, methods are being sought for creating artificial matter…

Laser-assisted chemical vapour deposition (CVD) growth is an attractive mask-less process for growing locally aligned carbon nanotubes (CNTs) in selected places on temperature sensitive substrates. The nature of the localized process…

Chemical Physics · Physics 2017-09-13 Yoeri van de Burgt , Yves Bellouard , Rajesh Mandamparambil

The variation of the optical absorption of carbon nanotubes with their geometry has been a long standing question at the heart of both metrological and applicative issues, in particular because optical spectroscopy is one of the primary…

Although significant efforts have been directed towards a selective single wall carbon nanotube synthesis, the resulting diameter and chirality distributions are still too broad and their control remains a challenge. Progress in this…

Materials Science · Physics 2015-06-04 Mamadou Diarra , Hakim Amara , Christophe Bichara , François Ducastelle
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