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Water is detected in environments representing every stage of star and solar system formation, but its chemical evolution throughout these stages remains poorly constrained. Deuterium ratios offer a means of probing chemical links between…

While the number of detected molecules, particularly complex organic molecules, in the solid-state in astrophysical environments is still rather limited, laboratory experiments and astrochemical models predict many potential candidates.…

Solar and Stellar Astrophysics · Physics 2025-05-07 Alexey Potapov , Hendrik Linz , Jeroen Bouwman , Will Rocha , Johannes Martin , Sebastian Wolf , Thomas Henning , Hiroshi Terada

[Abridged] The infrared ro-vibrational emission lines from organic molecules in the inner regions of protoplanetary disks are unique probes of the physical and chemical structure of planet forming regions and the processes that shape them.…

Solar and Stellar Astrophysics · Physics 2017-04-26 Arthur Bosman , Simon Bruderer , Ewine F. van Dishoeck

The chemical evolution in star forming regions is driven by the interplay between gas and ice mantles. Identifying the ice compositions at the early stage of star formation thus provides constraints on the chemical processes inaccessible…

Astrophysics of Galaxies · Physics 2026-02-06 Andrew M. Turner , Yao-Lun Yang , Rachel Gross , Nami Sakai , Ralf I. Kaiser

We present the first Spitzer Infrared Spectrograph observations of the 15.2 micron bending mode of CO2 ice towards field stars behind a quiescent dark cloud. CO2 ice is detected towards 2 field stars (Elias 16, Elias 3) and a single…

Infrared spectroscopic observations toward objects obscured by dense cloud material show that H$_2$O, CO and, likely, CO$_2$ are important constituents of interstellar ice mantles. In order to accurately calculate the column densities of…

Astrophysics · Physics 2008-02-03 P. A. Gerakines , W. A. Schutte , J. M. Greenberg , Ewine F. van Dishoeck

Spectroscopic studies play a key role in the identification and analysis of interstellar ices and their structure. Some molecules have been identified within the interstellar ices either as pure, mixed, or even as layered structures.…

We present a study of the detectability of CO molecules in the Galactic interstellar medium using high-resolution X-ray spectra obtained with the XMM-Newton Reflection Grating Spectrometer. We analyzed 10 bright low mass X-ray binaries…

High Energy Astrophysical Phenomena · Physics 2016-07-27 Katerine Joachimi , Efraín Gatuzz , Javier A. García , Timothy R. Kallman

Gas-phase hydroxylamine (NH$_2$OH) has recently been detected within dense clouds in the interstellar medium. However, it is also likely present within interstellar ices, as well as on the icy surfaces of outer Solar System bodies, where it…

Analyses of infrared signatures of CO$_2$ in water dominated ices in the ISM can give information on the physical state of CO$_2$ in icy grains and on the thermal history of the ices themselves. In many sources, CO$_2$ was found in the…

Instrumentation and Methods for Astrophysics · Physics 2018-12-19 Jiao He , SM Emtiaz , Adwin Boogert , Gianfranco Vidali

We investigate the bright CO fundamental emission in the central regions of five protostars in their primary mass assembly phase using new observations from JWST's Near-Infrared Spectrograph (NIRSpec) and Mid-Infrared Instrument (MIRI). CO…

Carbon monoxide (CO) is the second most abundant molecule in the gas-phase of the interstellar medium. In dense molecular clouds, it is also present in the solid-phase as a constituent of the mixed water-dominated ices covering dust grains.…

We analyze the rest-frame near-UV and optical nebular spectra of three $z > 7$ galaxies from the Early Release Observations taken with the Near-Infrared Spectrograph (NIRSpec) on the James Webb Space Telescope (JWST). These three high-z…

Infrared (IR) spectra of vapor-deposited amorphous water at low temperatures show two weak peaks at around 3720 and 3696 cm-1 assigned to free-OH stretching modes of two- and three-coordinated water molecules (so-called dangling OH bonds),…

Astrophysics of Galaxies · Physics 2024-07-11 Takeshi Hasegawa , Hiroto Yanagisawa , Takumi Nagasawa , Reo Sato , Naoki Numadate , Tetsuya Hama

Context. Infrared spectroscopy of star and planet forming regions is at the dawn of a new age with the upcoming James Webb Space Telescope. In support of these observations, laboratory spectra are required to identify complex organic…

The molecular species hydrogen peroxide, HOOH, is likely to be a key ingredient in the oxygen and water chemistry in the interstellar medium. Our aim with this investigation is to determine how abundant HOOH is in the cloud core {\rho} Oph…

Astrophysics of Galaxies · Physics 2011-06-02 P. Bergman , B. Parise , R. Liseau , B. Larsson , H. Olofsson , K. M. Menten , R. Güsten

NH3 and CH3OH are key molecules in astrochemical networks leading to the formation of more complex N- and O-bearing molecules, such as CH3CN and HCOOCH3. Despite a number of recent studies, little is known about their abundances in the…

Solid O2 has been proposed as a possible reservoir for oxygen in dense clouds through freeze-out processes. The aim of this work is to characterize quantitatively the physical processes that are involved in the desorption kinetics of CO-O2…

Astrophysics · Physics 2009-11-13 K. Acharyya , G. W. Fuchs , H. J. Fraser , E. F. van Dishoeck , H. Linnartz

Icy grain mantles are commonly observed through infrared spectroscopy toward dense clouds, cloud cores, protostellar envelopes and protoplanetary disks. Up to 80% of the available oxygen, carbon and nitrogen are found in such ices; the most…