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The charge carrier transport in metal phthallocyanine based disordered thin films has been investigated. Charge carrier mobility in these disordered thin films strongly depends on the electric field and temperature due to hopping…

Disordered Systems and Neural Networks · Physics 2015-06-25 Ajit Kumar Mahapatro , Subhasis Ghosh

In recent years, thin-film organic field-effect transistors (OFETs) have begun to be considered as a possible alternative to the hydrogenated amorphous silicon thin-film transistors (a-Si:H TFT's) used in active matrix flat panel displays…

One of the basic assumptions in organic field-effect transistors, the most fundamental device unit in organic electronics, is that charge transport occurs two-dimensionally in the first few molecular layers near the dielectric interface.…

Mesoscale and Nanoscale Physics · Physics 2016-01-11 Yuhan Zhang , Jingsi Qiao , Si Gao , Fengrui Hu , Daowei He , Bing Wu , Ziyi Yang , Bingchen Xu , Yun Li , Yi Shi , Wei Ji , Peng Wang , Xiaoyong Wang , Min Xiao , Hangxun Xu , Jian-Bin Xu , Xinran Wang

We studied spin transport in four organic semiconductors (OSCs) with different electronic properties, with Fe and Co as the top and bottom ferromagnetic (FM) contacts, respectively. Magnetoresistance (MR) effects were observed up to room…

Materials Science · Physics 2012-05-14 Yaohua Liu , Taegweon Lee , Howard E. Katz , Daniel H. Reich

Mixed layers of copper-phthalocyanine (p-conductive) and fullerene (n-conductive) are used for the fabrication of organic field-effect transistors (OFETs) and inverters. Regarding the electrical characteristics of these donor-acceptor…

Soft Condensed Matter · Physics 2007-05-23 A. Opitz , M. Bronner , W. Bruetting

Predicting the electrical properties of organic molecular crystals (OMCs) is challenging due to their complex crystal structures and electron-phonon (e-ph) interactions. Charge transport in OMCs is conventionally categorized into two…

Materials Science · Physics 2022-04-22 Benjamin K. Chang , Jin-Jian Zhou , Nien-En Lee , Marco Bernardi

Organic semiconductors (OSCs) have received much attention as promising materials for electronic devices. In this study, we investigate the impact of halogen groups on the charge transport properties of n-type OSC-6,13 bis…

Materials Science · Physics 2024-05-28 Sara Roosta , Marcus Elstner , Weiwei Xie

Understanding the movement of charge within organic semiconducting films is crucial for applications in photo-voltaics and flexible electronics. We study the sensitivity of the electrical conductance of a silicon nanowire to changes of…

Mesoscale and Nanoscale Physics · Physics 2019-05-20 M. V. Klymenko , J. A. Vaitkus , J. H. Cole

Understanding charge transport in organic semiconductors in large electric fields is relevant to many applications. We present transport measurements in organic field-effect transistors based on poly(3-hexylthiophene) and…

Materials Science · Physics 2010-03-09 J. H. Worne , J. E. Anthony , D. Natelson

The formation of donor-acceptor complexes (DACs) between the electron donor Dibenzotetrathiafulvalene (DBTTF) and the acceptor Hexaaza\-triphenylene\-hexacarbo\-nitrile (HATCN) results in a new phase with a distinctly different crystal…

Single-crystal organic field-effect transistors (OFETs) based on p-channel molecular semiconductors have led to breakthrough carrier mobilities and to the observation of band-like transport. These results represent the limit in our quest…

Materials Science · Physics 2012-02-10 Nikolas A. Minder , Shimpei Ono , Zhihua Chen , Antonio Facchetti , Alberto F. Morpurgo

We studied the influence of oxygen on the electronic trap states in a pentacene thin film. This was done by carrying out gated four-terminal measurements on thin-film transistors as a function of temperature and without ever exposing the…

Materials Science · Physics 2009-12-21 Wolfgang L. Kalb , Kurt Mattenberger , Bertram Batlogg

In organic field effect transistors (FETs), charges move near the surface of an organic semiconductor, at the interface with a dielectric. In the past, the nature of the microscopic motion of charge carriers -that determines the device…

Materials Science · Physics 2015-06-25 I. N. Hulea , S. Fratini , H. Xie , C. L. Mulder , N. N. Iossad , G. Rastelli , S. Ciuchi , A. F. Morpurgo

We present a systematic investigation of the low-frequency charge carrier dynamics in different charge states of the organic conductors $\theta$-(BEDT-TTF)$_2$$M$Zn(SCN)$_4$ with $M$=Rb,Tl, which result from quenching or relaxing the charge…

Strongly Correlated Electrons · Physics 2022-05-25 Tatjana Thomas , Tim Thyzel , Hungwei Sun , Kenichiro Hashimoto , Takahiko Sasaki , Hiroshi M. Yamamoto , Jens Müller

Discotic liquid crystals can self-align to form one-dimensional semiconducting wires, many tens of microns long. In this letter, we describe the preparation of semiconducting films where the stacking direction of the disc-like molecules is…

Materials Science · Physics 2007-05-23 C. Deibel , D. Janssen , P. Heremans , V. de Cupere , Y. Geerts , M. L. Benkhedir , G. J. Adriaenssens

In highest quality organic single-crystal field-effect transistors, electron transport occurs in the band-like regime, with the carrier mobility increasing upon lowering temperature. Neither the microscopic nature of this regime, nor why it…

Materials Science · Physics 2016-03-01 Yulia Krupskaya , Marco Gibertini , Nicola Marzari , Alberto F. Morpurgo

Organic semiconductors based on small conjugated molecules generally behave as insulators when undoped, but the hetero-interfaces of two such materials can show electrical conductivity as large as in a metal. Although charge transfer is…

Organic charge-transfer complexes (CTCs) formed by strong electron acceptor and strong electron donor molecules are known to exhibit exotic effects such as superconductivity and charge density waves. We present a low-temperature scanning…

Mesoscale and Nanoscale Physics · Physics 2021-06-24 Avijit Kumar , Kaustuv Banerjee , Mikko M. Ervasti , Shawulienu Kezilebieke , Marc Dvorak , Patrick Rinke , Ari Harju , Peter Liljeroth

Titanyl-phthalocyanines catalytic ability towards oxygen reduction is demonstrated in experimental literature. Our recent theoretical simulations revealed electronic structure origin of catalytic ability in peripherally and axially…

Materials Science · Physics 2016-11-01 Jeffrey R. De Lile , Su Zhou

We investigated transport properties of organic heterointerfaces formed by single-crystals of two organic donor-acceptor molecules, tetramethyltetraselenafulvalene (TMTSF) and 7,7,8,8-tetracyanoquinodimethane (TCNQ). Whereas the individual…

Materials Science · Physics 2015-05-18 M. Nakano , H. Alves , A. S. Molinari , S. Ono , N. Minder , A. F. Morpurgo
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