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While important for many industrial applications, chemical reactions responsible for charging of solids in water are often poorly understood. We theoretically investigate the charging kinetics of solid-liquid interfaces, and find that the…

Soft Condensed Matter · Physics 2023-02-08 Willem Boon , Marjolein Dijkstra , René van Roij

Many key industrial processes, from electricity production, conversion and storage to electrocatalysis or electrochemistry in general, rely on physical mechanisms occurring at the interface between a metallic electrode and an electrolyte…

Computational Physics · Physics 2021-09-03 Laura Scalfi , Mathieu Salanne , Benjamin Rotenberg

The contact line dynamics of a thermal field assisted flow configuration of two immiscible fluids is considered in a narrow thermofluidic pathway. The surfaces of the channel are wetted with predesigned wettabilities and interdigitated…

Fluid Dynamics · Physics 2018-04-23 Golak Kunti , Anandaroop Bhattacharya , Suman Chakraborty

The finite element simulation of dynamic wetting phenomena, requiring the computation of flow in a domain confined by intersecting a liquid-fluid free surface and a liquid-solid interface, with the three-phase contact line moving across the…

Computational Physics · Physics 2012-02-20 J. E. Sprittles , Y. D. Shikhmurzaev

In this paper, we present a novel approach to model the fluid/solid interaction forces in a direct solver of the Navier-Stokes equations based on the volume of fluid interface tracking method. The key ingredient of the model is the explicit…

Fluid Dynamics · Physics 2015-06-16 Kyle Mahady , Shahriar Afkhami , Lou Kondic

Drag and diffusion of mobile ions in solids are of interest for both purely theoretical and applied scientific communities. This article proposes a theoretical description of ion drag in solids that can be used to estimate ionic…

Mesoscale and Nanoscale Physics · Physics 2022-06-24 Aleksandr Rodin , Keian Noori , Alexandra Carvalho , Antonio Helio Castro Neto

The integration of the coupling effects of intrinsic wettability and surface charge in a nanochannel can cause non-intuitive behavior in the electrokinetic energy conversion processes. We demonstrate that in a nanofluidic device the energy…

Fluid Dynamics · Physics 2015-11-12 Chirodeep Bakli , Suman Chakraborty

Electrokinetic transport phenomena can strongly influence the behaviour of macromolecules and colloidal particles in solution, with applications in, e.g., DNA translocation through nanopores, electro-osmotic flow in nanocapillaries, and…

Soft Condensed Matter · Physics 2016-08-03 Georg Rempfer , Gary B. Davies , Christian Holm , Joost de Graaf

Wetting is fundamental to many technological applications that involve the motion of the fluid-fluid interface on a solid. While static wetting is well understood in the context of thermodynamic equilibrium, dynamic wetting is more…

Fluid Dynamics · Physics 2021-08-16 Shahriar Afkhami

We present a general formalism of ultrafast diffractive voltammetry approach as a contact-free tool to investigate the ultrafast surface charge dynamics in nanostructured interfaces. As case studies, the photoinduced surface charging…

Chemical Physics · Physics 2015-06-17 Kiseok Chang , Ryan A. Murdick , Zhensheng Tao , Tzong-Ru T. Han , Chong-Yu Ruan

Recent microfluidic experiments have explored the precise positioning of micron-sized particles in liquid environments via laser-induced thermoviscous flow. From micro-robotics to biology at the subcellular scale, this versatile technique…

Fluid Dynamics · Physics 2025-10-01 Weida Liao , Eric Lauga

We present a model treating the kinetics of adsorption of soluble surface-active molecules at the interface between an aqueous solution and another fluid phase. The model accounts for both the diffusive transport inside the solution and the…

Soft Condensed Matter · Physics 2007-05-23 H. Diamant , D. Andelman

A new simulation approach of field evaporation is presented. The model combines classical electrostatics with molecular dynamics (MD) simulations. Unlike previous atomic-level simulation approaches, our method does not rely on an…

Materials Science · Physics 2022-10-17 Jiayuwen Qi , Christian Oberdorfer , Emmanuelle A. Marquis , Wolfgang Windl

A variational theory is developed to study electrolyte solutions, composed of interacting point-like ions in a solvent, in the presence of dielectric discontinuities and charges at the boundaries. Three important and non-linear…

Soft Condensed Matter · Physics 2013-05-29 Sahin Buyukdagli , Manoel Manghi , John Palmeri

Recent developments in fabrication techniques enabled the production of nano- and angstrom-scale conduits. While scientists are able to conduct experimental studies to demonstrate extreme evaporation rates from these capillaries,…

Soft Condensed Matter · Physics 2019-03-18 Yigit Akkus , Anil Koklu , Ali Beskok

Collective modes in two-dimensional electron fluids show an interesting response to a background carrier flow. Surface plasmons propagating on top of a flowing Fermi liquid acquire a non-reciprocal character manifest in a $\pm k$ asymmetry…

Mesoscale and Nanoscale Physics · Physics 2020-01-01 Haoyang Gao , Zhiyu Dong , Leonid Levitov

This progress report summarizes recent studies of electrochemical oxidation to modulate the interfacial tension of gallium-based alloys. These alloys, which are liquid at ambient conditions, have the largest interfacial tension of any…

We theoretically study the electrokinetic transport properties of nano-fluidic devices under the influence of a pressure, voltage or salinity gradient. On a microscopic level the behaviour of the device is quantified by the Onsager matrix…

Soft Condensed Matter · Physics 2019-12-02 B. L. Werkhoven , R. van Roij

We propose a new unfitted finite element method for simulation of two-phase flows in presence of insoluble surfactant. The key features of the method are 1) discrete conservation of surfactant mass; 2) the possibility of having meshes that…

Numerical Analysis · Mathematics 2022-11-30 Thomas Frachon , Sara Zahedi

In the last decade, there has been a surge of experiments showing that certain chemical reactions undergo an enormous boost when taken from bulk aqueous conditions to microdroplet environments. The microscopic basis of this phenomenon…