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The temperature-dependent phonons are a generalization of interatomic force constants varying in T, which as found widespread use in computing the thermal transport of materials. A formal justification for using this combination to access…

Materials Science · Physics 2025-01-31 Aloïs Castellano , J. P. Alvarinhas Batista , Olle Hellman , Matthieu J. Verstraete

It is textbookly regarded that phonons, i.e., an energy quantum of propagating lattice waves, are the main heat carriers in perfect crystals. As a result, in many crystals, e.g., bulk silicon, the temperature-dependent thermal conductivity…

Materials Science · Physics 2020-09-18 Yanguang Zhou , Yufei Gao , Sebastian Volz

Phonon coherence elucidates the propagation and interaction of phonon quantum states within superlattice, unveiling the wave-like nature and collective behaviors of phonons. Taking MoSe$_2$/WSe$_2$ lateral heterostructures as a model…

Materials Science · Physics 2025-03-11 Xin Wu , Zhang Wu , Ting Liang , Zheyong Fan , Jianbin Xu , Masahiro Nomura , Penghua Ying

In the design of materials with low lattice thermal conductivity, compounds with high density, low speed of sound, and complexity at either the atomic, nano- or microstructural level are preferred. The layered compound Mg$_3$Sb$_2$ defies…

Materials Science · Physics 2018-04-05 Wanyue Peng , Guido Petretto , Gian-Marco Rignanese , Geoffroy Hautier , Alexandra Zevalkink

The intrinsic lattice thermal conductivity of MoS$_2$ is an important aspect in the design of MoS$_2$-based nanoelectronic devices. We investigate the lattice dynamics properties of MoS$_2$ by first principles calculations. The intrinsic…

Materials Science · Physics 2016-06-23 Bo Peng , Hao Zhang , Hezhu Shao , Yuanfeng Xu , Xiangchao Zhang , Heyuan Zhu

Understanding thermal and electrical transport in topological materials is essential for advancing their applications in quantum technologies and energy conversion. Herein, we employ first-principles calculations to systematically…

The phonon thermal conductivity of semiconducting periodic solids can be obtained using the lattice dynamics calculations along with the Boltzmann transport equation and with input from density functional theory calculations. These…

Mesoscale and Nanoscale Physics · Physics 2025-05-30 Ankit Jain , Yagyank Srivastava , Amey G. Gokhale , Nidheesh Virakante , Hardik L. Kagdada

Group-VI transition metal dichalcogenides (TMDs), MoS$_2$ and MoSe$_2$, have emerged as prototypical low-dimensional systems with distinctive phononic and electronic properties, making them attractive for applications in nanoelectronics,…

Materials Science · Physics 2025-09-18 Tugbey Kocabas , Murat Keceli , Tanju Gurel , Milorad Milosevic , Cem Sevik

Heat transport in low-dimensional systems has attracted enormous attention from both theoretical and experimental aspects due to its significance to the perception of fundamental energy transport theory and its potential applications in the…

Chaotic Dynamics · Physics 2013-01-04 Nianbei Li , Baowen Li

Phonon liquid-like thermal conduction in the solid state enables superionic conductors to serve as efficient thermoelectric device candidates. While liquid-like motion of ions effectively suppresses thermal conductivity (\kappa), their high…

High performance thermoelectric devices requires materials with low lattice thermal conductivities. Many strategies, such as phonon engineering, have been made to reduce lattice thermal conductivity without simultaneously decrease of the…

Materials Science · Physics 2020-01-07 Xiaoxia Yu , Hezhu Shao , Xueyun Wang , Yingcai Zhu , Daining Fang , Jiawang Hong

Very recently, a new graphene-like crystalline, hole-free, 2D-single-layer carbon nitride C3N, has been fabricated by polymerization of 2,3-diaminophenazine and used to fabricate a field-effect transistor device with an on-off current ratio…

Computational Physics · Physics 2017-09-27 Yan Gao , Haifeng Wang , Maozhu Sun , Yingchun Ding , Lichun Zhang , Qingfang Li , Jidong Zhang

Knowledge of lattice anharmonicity is essential to elucidate distinctive thermal properties in crystalline solids. Yet, accurate \textit{ab initio} investigations of lattice anharmonicity encounter difficulties owing to the cumbersome…

Materials Science · Physics 2022-04-13 Zhen Zhang , Dong-Bo Zhang , Tao Sun , Renata M. Wentzcovitch

Achieving high thermoelectric performance requires efficient manipulation of thermal conductivity and a fundamental understanding of the microscopic mechanisms of phonon transport in crystalline solids. One of the major challenges in…

Materials Science · Physics 2023-05-18 Jiaoyue Yuan , Yubi Chen , Bolin Liao

Within the framework of the unified theory thermal transport model, the competing contributions of coherent and incoherent terms create a trade-off relationship, posing substantial challenges to achieving a reduction in overall $\rm…

Materials Science · Physics 2025-04-04 Wenjie Xiong , Hao Huang , Yu Wu , Xinji Xu , Geng Li , Zonglin Gu , Shuming Zeng

The lattice thermal conductivities of silicon clathrate frameworks II and VIII are investigated by using ab initio lattice dynamics and iterative solution of the linearized Boltzmann transport equation(BTE) for phonons. Within the…

Materials Science · Physics 2016-04-26 Ville J. Härkönen , Antti J. Karttunen

Superlattices provide a great platform for studying coherent transportation of low-frequency phonons, which are the main issues in mastering the manipulation of heat conduction. Studies have shown that the dominating characteristics in the…

Materials Science · Physics 2021-08-12 Hai Jun Cho , Yuzhang Wu , Youngha Kwon , Jiajun Qi , Yuna Kim , Keiji Saito , Hiromichi Ohta

The lattice dynamics of members of the M2Mo6Se6 family of materials with guest ions M = K, Rb, Cs, In, and Tl has been studied using inelastic x-ray scattering and Raman spectroscopy at room temperature, as well as by ab-initio…

Phonon interactions from lattice anharmonicity govern thermal properties and heat transport in materials. These interactions are described by n-th order interatomic force constants (n-IFCs), which can be viewed as high-dimensional tensors…

Materials Science · Physics 2025-08-12 Yao Luo , Dhruv Mangtani , Shiyu Peng , Jia Yao , Sergei Kliavinek , Marco Bernardi

In crystalline materials, low lattice thermal conductivity is often associated with strong anharmonicity, which can cause significant deviations from the expected Lorentzian lineshape of phonon spectral functions. These deviations,…

Materials Science · Physics 2025-03-20 Đorđe Dangić , Giovanni Caldarelli , Raffaello Bianco , Ivana Savić , Ion Errea