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Using an ab initio approach, we explore the stability of small vacancy and vacancy-chromium clusters in dilute body-centred cubic Fe-Cr alloys. To explain experimental observations described in C.D. Hardie et al., J. Nucl. Mater. 439, 33…

Materials Science · Physics 2018-03-14 M. Yu. Lavrentiev , D. Nguyen-Manh , S. L. Dudarev

A first-principles investigation of the electronic and quantum transport properties of double-walled carbon nanotubes doped with nitrogen and boron atoms is presented. Concentric nanotube sidewalls separated by the typical graphitic van der…

Materials Science · Physics 2016-03-24 Alejandro Lopez-Bezanilla

We extracted, from strongly-correlated ab-initio calculations, a complete model for the chain subsystem of the $Sr_{0.4}Ca_{13.6}Cu_{24}O_{41}$ incommensurate compound. A second neighbor $t-J+V$ model has been determined as a function of…

Strongly Correlated Electrons · Physics 2009-11-10 Alain Gelle , Marie-Bernadette Lepetit

We have employed first principles calculations to study the electronic structure and magnetic properties of the low-dimensional phosphates, Ba2Cu(PO4)2 and Sr2Cu(PO4)2. Using the self-consistent tight-binding lin- earized muffin-tin orbital…

Strongly Correlated Electrons · Physics 2007-09-17 Sarita S. Salunke , M. A. H. Ahsan , R. Nath , A. V. Mahajan , I. Dasgupta

he structural, transport, magnetic and optical properties of the double perovskite $A_2$CrWO$_6$ with $A=\text{Sr, Ba, Ca}$ have been studied. By varying the alkaline earth ion on the $A$ site, the influence of steric effects on the Curie…

Strongly Correlated Electrons · Physics 2009-11-10 J. B. Philipp , P. Majewski , L. Alff , A. Erb , R. Gross , T. Graf , M. S. Brandt , J. Simon , T. Walther , W. Mader , D. Topwal , D. D. Sarma

We extend the methods recently introduced in Phys. Rev. Lett. 106 036401 (2011) to investigate correlations between two spin-polarons in a quasi-two-dimensional CuO2 layer. The low-energy wavefunctions for two doped holes introduced in a…

Strongly Correlated Electrons · Physics 2015-05-28 Bayo Lau , Mona Berciu , George. A. Sawatzky

Bonding in the C$_2$ molecule is investigated with CAS(8,8) wave functions using canonical MOs. In a subsequent step, orthogonal atomic orbitals are constructed by localizing the CASSCF MOs on the two carbon atoms with an orthogonal…

Chemical Physics · Physics 2023-04-12 Alexander F. Sax

We develop a coupled-cluster theory for bosonic mixtures of binary species in external traps, providing a promising theoretical approach to demonstrate highly accurately the many-body physics of mixtures of Bose-Einstein condensates. The…

Quantum Gases · Physics 2024-02-01 Anal Bhowmik , Ofir E. Alon

Carbon can exist as isolated dumbbell, one-dimensional (1D) chain, 2D plane, and 3D network in carbon solids or carbon-based compounds, which attributes to its rich chemical binding way, including sp-, sp2-, and sp3-hybridized bonds. Sp2…

Superconductivity · Physics 2014-10-28 Yan-Ling Li , Wei Luo , Zhi Zeng , Hai-Qing Lin , Ho-kwang Mao , Rajeev Ahuja

A new electronic structure model is developed in which the ground state energy of a molecular system is given by a Hartree-Fock-like expression with parametrized one- and two-electron integrals over an extended (minimal + polarization) set…

Chemical Physics · Physics 2014-02-11 Dimitri N. Laikov

The stability and bonding of the ternary complex K$_2$PtCl$_6$ structure hydrides is discussed using first principles density functional calculations. The cohesion is dominated by ionic contributions, but ligand field effects are important,…

Materials Science · Physics 2009-11-10 S. V. Halilov , D. J. Singh , M. Gupta , R. Gupta

Two dimensional materials are attracting new research for optoelectronics and spintronics due to their unique physical properties. A wide range of emerging spintronic devices are achieved from parent and doped two dimensional materials.…

Materials Science · Physics 2023-09-15 S. Koley

Fe-Co alloys with induced tetragonal strain are promising materials for rare-earth-free permanent magnets. However, as ultrathin-film studies have shown, tetragonal Fe-Co structures tend to a rapid relaxation toward a cubic structure as the…

Materials Science · Physics 2025-02-10 Wojciech Marciniak , Mirosław Werwiński

The optimized structure and electronic properties of neutral and singly charged magnesium clusters have been investigated using ab initio theoretical methods based on density-functional theory and systematic post-Hartree-Fock many-body…

Atomic and Molecular Clusters · Physics 2009-09-29 Andrey Lyalin , Ilia A Solov'yov , Andrey V Solov'yov , Walter Greiner

This paper reviews and summarizes the recent first-principles theoretical studies of the structural stability, electronic structure, optical and magnetic properties of nonmetal-doped TiO$_2$. The first section presents a comparison study of…

Materials Science · Physics 2020-09-10 Kesong Yang , Ying Dai , Baibiao Huang

We introduce two-dimensional borane, a single-layered material of BH stoichiometry, with promising electronic properties. We show that, according to Density Functional Theory calculations, two-dimensional borane is semimetallic, with two…

Materials Science · Physics 2017-12-01 Miguel Martinez-Canales , Timur R. Galeev , Alexander I. Boldyrev , Chris J. Pickard

We have studied the changes in the electronic structure and the superconducting transition temperature T_c of Mg(B_{1-x}C_{x})_{2} alloys as a function of x with 0\leq x\leq 0.3. Our density-functional-based approach uses coherent-potential…

Superconductivity · Physics 2009-11-10 Prabhakar P. Singh

A container picture is proposed for understanding cluster dynamics where the clusters make nonlocalized motion occupying the lowest orbit of the cluster mean-field potential characterized by the size parameter $``B"$ in the THSR…

The structure, binding energy, magnetic moments and electronic structure of FemIrn clusters are investigated using state of the art density functional theory techniques. Fully unconstrained structural relaxations are undertaken by…

Mesoscale and Nanoscale Physics · Physics 2013-01-23 S. Assa Aravindh

We study the properties of ThCr$_2$Si$_2$ structure BaMn$_2$As$_2$ and BaMn$_2$Sb$_2$ using density functional calculations of the electronic and magnetic as well experimental measurements on single crystal samples of BaMn$_2$As$_2$. These…

Materials Science · Physics 2009-02-25 J. an , A. S. Sefat , D. J. Singh , M. H. Du