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In this paper, we present a U(1)-invariant expansion theory of the adiabatic process. As its application, we propose and discuss new sufficient adiabatic approximation conditions. In the new conditions, we find a new invariant quantity…

Quantum Physics · Physics 2009-04-15 Jianda Wu , Meisheng Zhao , Jianlan Chen , Yongde Zhang

We present an efficient \textit{ab initio} algorithm for quantum dynamics simulations of interacting systems that is based on the conditional decomposition of the many-body wavefunction [Phys. Rev. Lett. 113, 083003 (2014)]. Starting with…

Mesoscale and Nanoscale Physics · Physics 2019-02-27 Guillermo Albareda , Aaron Kelly , Angel Rubio

We provide a general formula of quantum transfer that includes the non-adiabatic effect under periodic environmental modulation by using full counting statistics in Hilbert-Schmidt space. Applying the formula to an anharmonic junction model…

Quantum Physics · Physics 2014-05-09 Chikako Uchiyama

For adiabatic controls of quantum systems, the non-adiabatic transitions are reduced by increasing the operation time of processes. Perfect quantum adiabaticity usually requires the infinitely slow variation of control parameters. In this…

Quantum Physics · Physics 2022-07-01 Jin-Fu Chen

A quantum mechanical model on histone modification is proposed. Along with the methyl / acetate or other groups bound to the modified residues the torsion angles of the nearby histone chain are supposed to participate in the quantum…

Biomolecules · Quantitative Biology 2015-06-05 Liaofu Luo

Quantum thermodynamics aims at investigating both the emergence and the limits of the laws of thermodynamics from a quantum mechanical microscopic approach. In this scenario, thermodynamic processes with no heat exchange, namely, adiabatic…

Mixed-quantum-classical molecular dynamics simulation implies an effective measurement on the electronic states owing to continuously tracking the atomic forces.Based on this insight, we propose a quantum trajectory mean-field approach for…

Chemical Physics · Physics 2014-08-08 Wei Feng , Luting Xu , Xin-Qi Li , Weihai Fang , YiJing Yan

We review mathematical results concerning exponentially small corrections to adiabatic approximations and Born--Oppenheimer approximations.

Mathematical Physics · Physics 2007-05-23 George A. Hagedorn , Alain Joye

We discuss systematically several possible inequivalent ways to describe the dynamics and the transition probabilities of a quantum system when its hamiltonian is not self-adjoint. In order to simplify the treatment, we mainly restrict our…

Mathematical Physics · Physics 2015-06-24 Fabio Bagarello

Quantum theory can be regarded as a non-commutative generalization of classical probability. From this point of view, one expects quantum dynamics to be analogous to classical conditional probabilities. In this paper, a variant of the…

Quantum Physics · Physics 2007-05-23 M. S. Leifer

On-the-fly quantum nonadiabatic dynamics for large systems greatly benefits from the adiabatic representation readily available from the electronic structure programs. However, frequently occurring in this representation conical…

Adiabatic quantum computation is based on the adiabatic evolution of quantum systems. We analyse a particular class of qauntum adiabatic evolutions where either the initial or final Hamiltonian is a one-dimensional projector Hamiltonian on…

Quantum Physics · Physics 2015-05-13 Avatar Tulsi

We prove the existence of a unitary transformation that enables two arbitrarily given Hamiltonians in the same Hilbert space to be transformed into one another. The result is straightforward yet, for example, it lays the foundation to…

Quantum Physics · Physics 2020-12-09 Lian-Ao Wu , Dvira Segal

The system undergoes adiabatic evolution when its population in the instantaneous eigenbasis of its time-dependent Hamiltonian changes only negligibly. Realization of such dynamics requires slow-enough changes of the parameters of the…

Quantum Physics · Physics 2015-06-23 Bogdan Damski

Many physically interesting models show a quantum phase transition when a single parameter is varied through a critical point, where the ground state and the first excited state become degenerate. When this parameter appears as a coupling…

Quantum Physics · Physics 2008-09-24 Gernot Schaller

The adiabatic quantum algorithm has drawn intense interest as a potential approach to accelerating optimization tasks using quantum computation. The algorithm is most naturally realised in systems which support Hamiltonian evolution, rather…

Quantum Physics · Physics 2019-10-02 Liming Zhao , Carlos A. Perez-Delgado , Simon C. Benjamin , Joseph F. Fitzsimons

We propose a transport probe scheme to detect the nonadiabatic transition caused by Majornana moving, which is relevant to the braiding operations in topological quantum computation. The scheme is largely based on a time dependent…

Mesoscale and Nanoscale Physics · Physics 2023-09-26 Luting Xu , Xin-Qi Li

We propose a method to compute free-energy differences from nonadiabatic alchemical transformations using flow-based generative models. The method, nonadiabatic force matching, hinges on estimating the dissipation along an alchemical…

Chemical Physics · Physics 2025-11-21 Jorge L. Rosa-Raíces , David T. Limmer

In this paper we study a Hamiltonian system with a spatially asymmetric potential. We are interested in the effects on the dynamics when the potential becomes symmetric slowly in time. We focus on a highly simplified non-trivial model…

chao-dyn · Physics 2008-02-03 R. J. A. G. Huveneers , F. Verhulst

Quantum adiabatic transfer is widely used in quantum computation and quantum simulation. However, the transfer speed is limited by the quantum adiabatic approximation condition, which hinders its application in quantum systems with a short…

Quantum Physics · Physics 2022-08-31 Wen Zheng , Jianwen Xu , Zhimin Wang , Yuqian Dong , Dong Lan , Xinsheng Tan , Yang Yu