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Previous studies of the structure of liquid water under pressure performed by neutron diffraction, allowed us to establish two structural limits in liquid water. These two limits are closely connected to the two known forms of amorphous ice…

Disordered Systems and Neural Networks · Physics 2016-08-31 M. -C. Bellissent-Funel

We perform molecular dynamics simulations of 512 water-like molecules that interact via the TIP5P potential and are confined between two smooth hydrophobic plates that are separated by 1.10 nm. We find that the anomalous thermodynamic…

Soft Condensed Matter · Physics 2009-11-11 Pradeep Kumar , Sergey V. Buldyrev , Francis W. Starr , Nicolas Giovambattista , H. Eugene Stanley

A new classical interaction potential for water simulations is presented. Water is modeled as a fully dissociable set of atoms with a point dipole, determined self-consistently, on every oxygen atom. The oxygen polarizability is not fixed…

Condensed Matter · Physics 2009-11-10 E. Lussetti , G. Pastore , E. Smargiassi

The structure of polar liquids and electrolytic solutions, such as water and aqueous electrolytes, at interfaces underlies numerous phenomena in physics, chemistry, biology, and engineering. In this work, we develop a continuum theory that…

Soft Condensed Matter · Physics 2022-07-13 J. Pedro de Souza , Alexei A. Kornyshev , Martin Z. Bazant

We consider the practicalities of defining, simulating, and characterizing "Liquids" from a pedagogical standpoint based on atomistic computer simulations. For simplicity and clarity we study two-dimensional systems throughout. In addition…

Statistical Mechanics · Physics 2021-03-30 Karl P. Travis , William Graham Hoover , Carol Griswold Hoover , Amanda Bailey Hass

Supercooling of water can be easily studied with a simple apparatus suitable for the student laboratory. We describe such an apparatus and its capabilities. The parameters influencing supercooling include the initial temperature of the…

Chemical Physics · Physics 2016-05-04 K. -C. Tan , W. Ho , J. I. Katz , S. -J. Feng

We look ahead from the frontiers of research on ice dynamics in its broadest sense; on the structures of ice, the patterns or morphologies it may assume, and the physical and chemical processes in which it is involved. We highlight open…

Water is commonly associated to the existence of life. However, there is no clear reason why water should be the only liquid in which life could form and survive. Since the seminal work of L. J. Henderson in 1913, scientists are trying to…

Soft Condensed Matter · Physics 2007-05-23 Giancarlo Franzese , H. Eugene Stanley

Surface freezing is a phenomenon in which crystallization is enhanced at a vapor-liquid interface. In some systems, such as $n$-alkanes, this enhancement is dramatic, and results in the formation of a crystalline layer at the free interface…

Soft Condensed Matter · Physics 2017-09-13 Amir Haji Akbari , Pablo G. Debenedetti

The static and dynamical properties of heavy water have been studied at ambient conditions with extensive Car-Parrinello molecular-dynamics simulations in the canonical ensemble, with temperatures ranging between 325 K and 400 K.…

Soft Condensed Matter · Physics 2007-05-23 P. H-L. Sit , Nicola Marzari

We determine and compare structural, dynamical, and electronic properties of liquid water at near ambient conditions through density-functional molecular dynamics simulations, when using either plane-wave or atomic-orbital basis sets. In…

Chemical Physics · Physics 2016-09-26 Giacomo Miceli , Jürg Hutter , Alfredo Pasquarello

Despite the simplicity of the water molecule, the kinetics of ice nucleation under natural conditions can be complex. We investigated spontaneously grown ice nuclei using all-atom molecular dynamics simulations and found significant…

Soft Condensed Matter · Physics 2025-04-28 Maodong Li , Yupeng Huang , Yijie Xia , Dechin Chen , Cheng Fan , Lijiang Yang , Yi Qin Gao , Yi Isaac Yang

The work presents the detailed analysis of the water dimer properties. Their parameters are investigated on the basis of a multipole interaction potential extended up to the quadrupole--quadrupole and dipole--octupole terms. All main…

Chemical Physics · Physics 2013-05-02 P. V. Makhlaichuk , M. P. Malomuzh , I. V. Zhyganiuk

In this work we present the dielectric behavior of water with a novel flexible model that improved all three sites water models Different concentrations of the ionic liquid 1- butyl-3-methylimidazolium [bmim]…

Molecular Dynamics simulations of water molecules in nanometre sized cylindrical channels connecting two reservoirs show that the permeation of water is very sensitive to the channel radius and to electric polarization of the embedding…

Soft Condensed Matter · Physics 2009-11-07 Rosalind Allen , Simone Melchionna , Jean-Pierre Hansen

Liquid crystal is a typical kind of soft matter that is intermediate between crystalline solids and isotropic fluids. The study of liquid crystals has made tremendous progress over the last four decades, which is of great importance on both…

Numerical Analysis · Mathematics 2021-04-07 Wei Wang , Lei Zhang , Pingwen Zhang

Among the over eighteen different forms of water ice, only the common hexagonal phase and a cubic phase are present in nature on Earth. The existence of these two polytypes, almost degenerate in energy, represents one of the most important…

Premelting describes the confluence of phenomena that are responsible for the stable existence of the liquid phase of matter in the solid region of its bulk phase diagram. Here we develop a theoretical description of the premelting of water…

Soft Condensed Matter · Physics 2013-05-29 Hendrik Hansen-Goos , J. S. Wettlaufer

We examine ice crystal growth from water vapor at temperatures near the melting point, when surface premelting creates a quasiliquid layer at the solid/vapor interface. Recent ice growth measurements as a function of vapor supersaturation…

Materials Science · Physics 2014-07-04 Kenneth G. Libbrecht

Bulk water presents a large number of crystalline and amorphous ices. Hydrophobic nanoconfinement is known to affect the tendency of water to form ice and to reduce the melting temperature. However, a systematic study of the ice phases in…

Soft Condensed Matter · Physics 2011-02-15 Oriol Vilanova , Giancarlo Franzese