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We have developed a microfluidic tool to measure the diffusion coefficient $D$ of solutes in an aqueous solution, by following the temporal relaxation of an initially steep concentration gradient in a microchannel. Our chip exploits…

Soft Condensed Matter · Physics 2022-08-23 Hoang-Thanh Nguyen , Anne Bouchaudy , Jean-Baptiste Salmon

Electro- and diffusio- phoresis of particles correspond respectively to the transport of particles under electric field and solute concentration gradients. Such interfacial transport phenomena take their origin in a diffuse layer close to…

Soft Condensed Matter · Physics 2020-04-22 Sophie Marbach , Hiroaki Yoshida , Lydéric Bocquet

Our object is to formulate and analyze a physically plausible and mathematically sound model to better understand the phenomenon of clumping in colloid dispersions. Our model is stochastic but rigorously derived from a deterministic setup…

Materials Science · Physics 2009-09-29 Peter. Kotelenez , Marshall J. Leitman , J. Adin Mann

The dissolution or growth of a droplet in a host liquid is an important part for processes like chemical extraction, chromatography or emulsification. In this work we look at the dissolution of a pair of vertically aligned droplets immersed…

Fluid Dynamics · Physics 2022-01-25 Ricardo Arturo Lopez de la Cruz , Christian Diddens , Xuehua Zhang , Detlef Lohse

The dissolution of NaCl in water is one of the most common everyday processes, yet it remains poorly understood at the molecular level. Here we report the results of an extensive density functional theory study in which the initial stages…

Chemical Physics · Physics 2013-12-18 Jiří Klimeš , David R. Bowler , Angelos Michaelides

A new technique for the separation of macromolecules is proposed and investigated. A thin mesh with pores comparable to the radius of gyration of a free chain is used to filter chains according to their length. Without a field it has…

Soft Condensed Matter · Physics 2009-10-28 J. M. Deutsch , Hyoungsoo Yoon

Due to the complex interplay between surface adsorption and hydrodynamic interactions, representative microscopic mechanisms of colloidal membrane fouling are still not well understood. Numerical simulations overcome experimental…

Computational Physics · Physics 2018-03-22 Johannes Lohaus , Yannic Martin Perez , Matthias Wessling

We experimentally, numerically and analytically explore the diffusive transport of active colloidal particles with sensory delay, navigating motility landscapes in which the self-propulsion speed depends on space. We show how the transport…

Statistical Mechanics · Physics 2026-04-29 Adrià Garcés , Ueli Töpfer , Lucio Isa , Demian Levis , Ignacio Pagonabarraga

A low diffusive flux difference splitting based kinetic scheme is developed based on a discrete velocity Boltzmann equation, with a novel three velocity model. While two discrete velocities are used for upwinding, the third discrete…

Fluid Dynamics · Physics 2024-10-01 Shrinath. K. S , Maruthi. N. H , S. V. Raghurama Rao , Veeredhi Vasudeva Rao

Assembly of colloidal particles on fluid interfaces is a promising technique for synthesizing two-dimensional micro-crystalline materials useful in fields as diverse as biomedicine1, materials science2, mineral flotation3 and food…

Soft Condensed Matter · Physics 2007-05-23 Anand Bala Subramaniam , Manouk Abkarian , Howard A. Stone

A new method is proposed to numerically extract the diffusivity of a (typically nonlinear) diffusion equation from underlying stochastic particle systems. The proposed strategy requires the system to be in local equilibrium and have…

Statistical Mechanics · Physics 2018-05-09 Peter Embacher , Nicolas Dirr , Johannes Zimmer , Celia Reina

Surface interactions provide a class of mechanisms which can be employed for propulsion of micro- and nanometer sized particles. We investigate the related efficiency of externally and self-propelled swimmers. A general scaling relation is…

Soft Condensed Matter · Physics 2015-05-20 Benedikt Sabass , Udo Seifert

Flowing granular materials segregate due to differences in particle size (driven by percolation) and density (driven by buoyancy). Modelling the segregation of mixtures of large/heavy particles and small/light particles is challenging due…

Soft Condensed Matter · Physics 2021-05-18 Yifei Duan , Paul B. Umbanhowar , Julio M. Ottino , Richard M. Lueptow

When colloids flow in a narrow channel, the transport efficiency is controlled by the non-equilibrium interplay between colloid-wall interactions and hydrodynamics. In this paper, a general, unifying description of colloidal dispersion flow…

Fluid Dynamics · Physics 2018-06-12 Patrice Bacchin

Design strategies to assemble dissipative building blocks are essential to create novel and smart materials and machines. We recently demonstrated the hierarchical self-assembly of phoretic microswimmers into self-spinning microgears and…

Soft Condensed Matter · Physics 2019-09-26 Antoine Aubret , Jérémie Palacci

We show that phase separation in ordered polar active fluids belongs to a new universality class. This describes large collections of self-propelled entities (``flocks"), all spontaneously moving in the same direction, in which attractive…

Soft Condensed Matter · Physics 2024-01-12 Maxx Miller , John Toner

The experiments of Leptos et al. [Phys. Rev. Lett. 103, 198103 (2009)] show that the displacements of small particles affected by swimming microorganisms achieve a non-Gaussian distribution, which nevertheless scales diffusively -- the…

Soft Condensed Matter · Physics 2017-10-26 Jean-Luc Thiffeault

Liquid-liquid phase separation is ubiquitous in suspensions of nanoparticles, proteins and colloids. With a few notable exceptions, surface-tension-minimizing liquid droplets in bulk suspensions continuously coalesce, increasing in size…

Soft Condensed Matter · Physics 2014-09-10 Prerna Sharma , Andrew Ward , T. Gibaud , Michael F. Hagan , Zvonimir Dogic

In order to obtain a comprehensive understanding of both thermodynamics and kinetics of water dissociation on TiO2, the reactions between liquid water and perfect and defective rutile TiO2 (110) surfaces were investigated using ab initio…

Chemical Physics · Physics 2018-03-29 Huili Wang , Zhenpeng Hu , Hui Li

We consider the axisymmetric displacement of an ambient fluid by a second input fluid of lower density and lower viscosity in a horizontal porous layer. If the two fluids have been vertically segregated by buoyancy, the flow becomes…

Fluid Dynamics · Physics 2022-08-24 Edward M. Hinton , Apoorv Jyoti