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Doubly occupied configuration interaction (DOCI), the exact diagonalization of the Hamiltonian in the paired (seniority zero) sector of the Hilbert space, is a combinatorial cost wave function that can be very efficiently approximated by…

Chemical Physics · Physics 2020-05-14 Jacob M. Wahlen-Strothman , Thomas M. Henderson , Gustavo E. Scuseria

The Jordan-Wigner transformation establishes a duality between $su(2)$ and fermionic algebras. We present qualitative arguments and numerical evidence that when mapping spins to fermions, the transformation makes strong correlation weaker,…

Strongly Correlated Electrons · Physics 2022-11-30 Thomas M. Henderson , Guo P. Chen , Gustavo E. Scuseria

Doubly occupied configuration interaction (DOCI) with optimized orbitals often accurately describes strong correlations while working in a Hilbert space much smaller than that needed for full configuration interaction. However, the scaling…

Chemical Physics · Physics 2016-02-25 Thomas M. Henderson , Ireneusz W. Bulik , Tamar Stein , Gustavo E. Scuseria

Zero-seniority methods have shown great promise for the description of strongly-correlated electronic systems. Other seniority sectors have been much less explored, and in particular the maximal seniority sector and zero seniority have the…

Strongly Correlated Electrons · Physics 2026-04-22 Thomas M Henderson , Guo P. Chen , Gustavo E. Scuseria

The Jordan-Wigner transformation is traditionally applied to one dimensional systems, but recent works have generalized the transformation to fermionic lattice systems in higher dimensions while keeping locality manifest. These developments…

Strongly Correlated Electrons · Physics 2021-08-24 Hoi Chun Po

Over the past few years pair coupled cluster doubles (pCCD) has shown promise for the description of strong correlation. This promise is related to its apparent ability to match results from doubly occupied configuration interaction (DOCI),…

Chemical Physics · Physics 2016-03-23 James J. Shepherd , Thomas M. Henderson , Gustavo E. Scuseria

The Jordan--Wigner transformation permits one to convert spin $1/2$ operators into spinless fermion ones, or vice versa. In some cases, it transforms an interacting spin Hamiltonian into a noninteracting fermionic one which is exactly…

The Jordan-Wigner transformation is a powerful tool for converting systems of spins into systems of fermions, or vice versa. While this mapping is exact, the transformation itself depends on the labeling of the spins. One consequence of…

Strongly Correlated Electrons · Physics 2023-09-07 Thomas M Henderson , Fei Gao , Gustavo E. Scuseria

Recent work has highlighted that the strong correlation inherent in spin Hamiltonians can be effectively reduced by mapping spins to fermions via the Jordan-Wigner transformation (JW). The Hartree-Fock method is straightforward in the…

Strongly Correlated Electrons · Physics 2025-08-26 Shadan Ghassemi Tabrizi , Thomas M. Henderson , Thomas D. Kühne , Gustavo E. Scuseria

We propose a method to solve the electronic Schr\"odinger equation for strongly correlated systems by applying a unitary transformation to reduce the complexity of the physical Hamiltonian. In particular, we seek a transformation that maps…

Chemical Physics · Physics 2026-04-14 Daniel F. Calero-Osorio , Paul W. Ayers

We study $N$ interacting massless Dirac fermions confined in a two-dimensional quantum dot. Physical realizations of this problem include a graphene monolayer and the surface state of a strong topological insulator. We consider both a…

Mesoscale and Nanoscale Physics · Physics 2011-02-15 Tomi Paananen , Reinhold Egger , Heinz Siedentop

It is usually asserted that physical Hamiltonians for fermions must contain an even number of fermion operators. This is indeed true in electronic structure theory. However, when the Jordan-Wigner transformation is used to map physical spin…

Strongly Correlated Electrons · Physics 2024-01-10 Thomas M. Henderson , Shadan Ghassemi Tabrizi , Guo P. Chen , Gustavo E. Scuseria

The Jordan-Wigner transformation is known as a powerful tool in condensed matter theory, especially in the theory of low-dimensional quantum spin systems. The aim of this chapter is to review the application of the Jordan-Wigner…

Strongly Correlated Electrons · Physics 2016-11-23 Oleg Derzhko

Proposed is a generalization of Jordan-Wigner transform that allows to exactly fermionize a large family of quantum spin Hamiltonians in dimensions higher than one. The key new steps are to enlarge the Hilbert space of the original model by…

Strongly Correlated Electrons · Physics 2014-11-20 Victor Galitski

We present an approach that uses the doubly occupied configuration interaction (DOCI) wave function as the trial wave function in phaseless auxiliary-field quantum Monte Carlo (ph-AFQMC). DOCI is a seniority-zero method focused on electron…

Polynomially-large ground-state energy gaps are rare in many-body quantum systems, but useful for adiabatic quantum computing. We show analytically that the gap is generically polynomially-large for quadratic fermionic Hamiltonians. We then…

Quantum Physics · Physics 2013-05-29 Michael J. O'Hara , Dianne P. O'Leary

The Jordan-Wigner transformation is applied to study magnetic properties of the quantum spin-1/2 $XX$ model on the diamond chain. Generally, the Hamiltonian of this quantum spin system can be represented in terms of spinless fermions in the…

Strongly Correlated Electrons · Physics 2011-05-09 Taras Verkholyak , Jozef Strecka , Michal Jascur , Johannes Richter

We introduce the fermionized time-dependent Hartree-Fock (fTDHF), a real-time quantum dynamics method for spin-1/2 Hamiltonians following their mapping to fermions via the Jordan-Wigner transformation. fTDHF is formally equivalent to exact…

Strongly Correlated Electrons · Physics 2026-05-25 Rishab Dutta , Marc Illa , Niranjan Govind , Karol Kowalski

Inspired by recent developments generalizing Jordan-Wigner dualities to higher dimensions, we develop a framework of such dualities using an algebraic formalism for translation-invariant Hamiltonians proposed by Haah. We prove that given a…

Strongly Correlated Electrons · Physics 2020-06-19 Nathanan Tantivasadakarn

Numerical difficulties associated with computing matrix elements of operators between Hartree-Fock-Bogoliubov (HFB) wavefunctions have plagued the development of HFB-based many-body theories for decades. The problem arises from divisions by…

Chemical Physics · Physics 2023-06-09 Guo P. Chen , Gustavo E. Scuseria
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