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Synthetic chiral light enables ultrafast and highly efficient imaging of molecular chirality. Unlike standard circularly polarized light, the handedness of synthetic chiral light does not rely on the spatial structure of the light field: it…

Optics · Physics 2022-06-06 Laura Rego , David Ayuso

Photoelectron circular dichroism refers to the forward/backward asymmetry in the photoelectron angular distribution with respect to the propagation axis of circularly polarized light. It has recently been demonstrated in femtosecond…

Quantum Physics · Physics 2017-01-16 R. E. Goetz , T. A. Isaev , B. Nikoobakht , R. Berger , C. P. Koch

Many chirality-sensitive light-matter interactions are governed by chiral electron dynamics. Therefore, the development of advanced technologies harnessing chiral phenomena would critically benefit from measuring and controlling chiral…

Chiral light-matter interactions have been investigated for two centuries, leading to the discovery of many chiroptical processes used for discrimination of enantiomers. Whereas most chiroptical effects result from a response of bound…

Chiral molecules ionized by circularly polarized fields produce a photoelectron current orthogonal to the polarization plane. This current has opposite directions for opposite enantiomers and provides an extremely sensitive probe of…

Atomic Physics · Physics 2022-06-28 Andres F. Ordonez , Olga Smirnova

Chirality causes symmetry breaks in a large variety of natural phenomena ranging from particle physics to biochemistry. We investigate one of the simplest conceivable chiral systems, a laser-excited, oriented, effective one-electron Li…

Chiroptical techniques for detecting and characterizing the chirality of matter and artificial nanostructures are traditionally based on their interaction with chiral light, typically circularly-polarized fields propagating in free space.…

We establish a general unified formulation which, using the optical theorem of electromagnetic helicity, shows that dichorism is a phenomenon arising in any scattering -or diffraction- process, elastic or not, of chiral electromagnetic…

Optics · Physics 2017-04-12 Manuel Nieto-Vesperinas

Mirror symmetry is among the most fundamental concepts of physics and its spontaneous breaking at the molecular level allows chiral molecules to exist in two enantiomers that are mirror images of each other. The majority of chiro-optical…

Optics · Physics 2021-09-29 Alessandro Ciattoni

Magnetic fields break the symmetry of the interaction of atoms with photons with different polarizations, yielding chirality and anisotropy properties. The dependence of the absorption spectrum on the polarization, a phenomenon known as…

Solar and Stellar Astrophysics · Physics 2025-01-08 René D. Rohrmann

We show that a nonchiral atom can act as an antenna to induce a photoelectron circular dichroism in a nearby chiral molecule in a three-step process: The donor atom (antenna) is initially resonantly excited by circularly polarized…

Atomic and Molecular Clusters · Physics 2025-05-14 Stefan Yoshi Buhmann , Andreas Hans , Janine C. Franz , Philipp V. Demekhin

Photoelectron circular dichroism (PECD) is a method where randomly oriented chiral molecules are photoionized due to irradiation by circularly-polarized lasers, yielding large chiral signals in the photoelectron momentum distribution.…

Optics · Physics 2025-12-16 Gal Bouskila , Avner Fleischer , Ofer Neufeld

Circular dichroism spectroscopy is an essential technique for understanding molecular structure and magnetic materials, but spatial resolution is limited by the wavelength of light, and sensitivity sufficient for single-molecule…

It has been long recognized that the spatial polarization of the electronic clouds in molecules, and the spatial arrangements of atoms into chiral molecular structures, play crucial roles in physics, chemistry and biology. However, these…

Optics · Physics 2020-04-14 David Ayuso , Andres Ordonez , Piero Decleva , Misha Ivanov , Olga Smirnova

Polarization-dependent photon spectroscopy (dichroism) of the second-harmonic generation (SHG) response is shown to reveal chiral and magnetic properties of a sample. Two dichroic signals are allowed with electric-dipole (E1) and…

Strongly Correlated Electrons · Physics 2019-12-11 S. W. Lovesey , G. van der Laan

Chiral molecules exhibit enantiosensitive light-matter interactions, with photoelectron circular dichroism (PECD) serving as a sensitive probe of molecular chirality through the asymmetry in the photoelectron wavepacket amplitude. Here, we…

Atomic Physics · Physics 2025-05-07 Zheming Zhou , Yang Li , Xu Zhang , Yueming Zhou , Peixiang Lu

We demonstrate that an effect phenomenologically analogous to circular dichroism can arise even for dielectric and isotropic chiral spherical particles. By analyzing the polarimetry of light scattered from a chiral, lossless microsphere…

Recent studies demonstrated the violation of reciprocity in optical processes in low-symmetry magnetic crystals. In these crystals the speed of light can be different for counter-propagating beams. Correspondingly, they can show strong…

Materials Science · Physics 2014-01-15 David Szaller , Sandor Bordacs , Istvan Kezsmarki

Angular distribution of photoelectrons released by the ionization of randomly-oriented molecules with two laser fields of carrier frequencies $\omega$ and $2\omega$, which are linearly polarized in two mutually-orthogonal directions, is…

Quantum Physics · Physics 2019-06-11 Philipp V. Demekhin

The topological response of matter to electromagnetic fields is a property in high demand in materials design and metrology due to its robustness against noise and decoherence, stimulating recent advances in ultrafast photonics. Embedding…