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The optimized effective potential (OEP) method presents an unambiguous way to construct the Kohn-Sham potential corresponding to a given diagrammatic approximation for the exchange-correlation functional. The OEP from the random-phase…

Materials Science · Physics 2023-07-18 Stefan Riemelmoser , Merzuk Kaltak , Georg Kresse

We present SPARC-atomSFE, a spectral finite-element package for accurate and efficient atomic structure calculations within the framework of Kohn-Sham density functional theory. The package supports both all-electron and norm conserving…

Computational Physics · Physics 2026-05-19 Qihao Cheng , Shubhang Krishnakant Trivedi , Phanish Suryanarayana

The optimized effective potential (OEP) method is a promising technique for calculating the ground state properties of a system within the density functional theory. However, it is not widely used as its computational cost is rather high…

Materials Science · Physics 2016-12-15 Taro Fukazawa , Hisazumi Akai

The optimized effective potential (OEP) method allows for calculation of the local, effective single particle potential of density functional theory for explicitly orbital-dependent approximations to the exchange-correlation energy…

Materials Science · Physics 2015-06-25 P. Sule , S. Kurth , V. Van Doren

In electronic structure calculations the optimized effective potential (OEP) is a method that treats exchange interactions exactly using a local potential within density-functional theory (DFT). We present a method using density functional…

Materials Science · Physics 2013-01-24 Tom W. Hollins , Stewart J. Clark , Keith Refson , Nikitas I. Gidopoulos

The optimized-effective-potential (OEP) method is a special technique to construct local Kohn-Sham potentials from general orbital-dependent energy functionals. In a recent publication [M. Betzinger, C. Friedrich, S. Bl\"ugel, A. G\"orling,…

Materials Science · Physics 2012-06-22 Markus Betzinger , Christoph Friedrich , Andreas Görling , Stefan Blügel

The spectral/hp element method combines the geometric flexibility of the classical h-type finite element technique with the desirable numerical properties of spectral methods, employing high-degree piecewise polynomial basis functions on…

In this work we propose an efficient and accurate multi-scale optical simulation algorithm by applying a numerical version of slowly varying envelope approximation in FEM. Specifically, we employ the fast iterative method to quickly compute…

Optics · Physics 2024-12-03 Fan Xiao , Jingwei Wang , Zhongfei Xiong , Yuntian Chen

The optimized effective potential (OEP) approach has so far mainly been used in benchmark studies and for the evaluation of band gaps. In this work, we extend the application of the OEP by determining the analytical ionic forces within the…

Materials Science · Physics 2024-09-13 Damian Contant , Maria Hellgren

We present an implementation of the optimised effective potential (OEP) scheme for the exact-exchange (EXX) and random phase approximation (RPA) energy functionals and apply these methods to a range of bulk materials. We calculate the…

Materials Science · Physics 2014-05-16 Jiří Klimeš , Georg Kresse

For exchange-correlation functionals that depend explicitly on the Kohn-Sham orbitals, the potential $V_{\mathrm{xc}\sigma}(\re)$ must be obtained as the solution of the optimized effective potential (OEP) integral equation. This is very…

Materials Science · Physics 2009-11-07 Stephan Kümmel , John P. Perdew

Attaining a reliable complete basis set (CBS) limit remains a significant challenge in ab initio correlated electronic-structure calculations. Building on our previous work for atoms and diatomic molecules, we present a finite-element (FE)…

Materials Science · Physics 2026-03-30 Hao Peng , Haochen Liu , Chuhao Li , Hehu Xie , Xinguo Ren

We introduce an orbital-optimized double-hybrid (DH) scheme using the optimized-effective-potential (OEP) method. The orbitals are optimized using a local potential corresponding to the complete exchange-correlation energy expression…

The optimized effective potential (OEP) is the exact Kohn-Sham potential for explicitly orbital-dependent energy functionals, e.g., the exact exchange energy. We give a proof for the OEP equation which does not depend on the chain rule for…

Materials Science · Physics 2009-11-10 Stephan Kümmel , John P. Perdew

We propose a practical approximation to the exchange-correlation functional of (time-dependent) density functional theory for many-electron systems coupled to photons. The (time non-local) optimized effective potential (OEP) equation for…

Mesoscale and Nanoscale Physics · Physics 2015-09-02 Camilla Pellegrini , Johannes Flick , Ilya V. Tokatly , Heiko Appel , Angel Rubio

We have derived a new method which allows to compute the full and the Pauli reference kinetic potentials for atoms and molecules in a real space representation. This is done by applying the optimized effective potential (OEP) method to…

Chemical Physics · Physics 2020-05-08 Szymon Śmiga , Sylwia Siecińska , Eduardo Fabiano

In this paper, we study a generalized finite element method for solving second-order elliptic partial differential equations with rough coefficients. The method uses local approximation spaces computed by solving eigenvalue problems on…

Numerical Analysis · Mathematics 2025-07-17 Christian Alber , Peter Bastian , Moritz Hauck , Robert Scheichl

A numerical scheme is presented for approximating fractional order Poisson problems in two and three dimensions. The scheme is based on reformulating the original problem posed over $\Omega$ on the extruded domain…

Numerical Analysis · Mathematics 2019-05-27 Mark Ainsworth , Christian Glusa

We present an optimized random phase approximation method (optRPA26) that significantly improves upon conventional RPA. The method employs an empirically constructed hybrid functional to generate DFT orbitals to evaluate the RPA correlation…

Chemical Physics · Physics 2026-02-06 Neung-Kyung Yu , Johannes Voss , Andrew J. Medford

In Paper I, the effective one-electron potentials (OEP) method was introduced and demonstrated as an efficient approach to reduce the computational cost of evaluation of the charge-transfer interaction energy within the effective fragment…

Chemical Physics · Physics 2020-02-04 Bartosz Błasiak , Robert W. Góra , Wojciech Bartkowiak
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