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Understanding strongly correlated systems is essential for advancing quantum chemistry and materials science, yet conventional methods like Density Functional Theory (DFT) often fail to capture their complex electronic behavior. To address…

Chemical Physics · Physics 2025-09-01 Archith Rayabharam , N. R. Aluru

In this paper, we propose two time-splitting finite element methods to solve the semiclassical nonlinear Schr\"odinger equation (NLSE) with random potentials. We then introduce the multiscale finite element method (MsFEM) to reduce the…

Numerical Analysis · Mathematics 2025-02-12 Panchi Li , Zhiwen Zhang

A novel overlapping domain decomposition splitting algorithm based on a Crank-Nisolson method is developed for the stochastic nonlinear Schroedinger equation driven by a multiplicative noise with non-periodic boundary conditions. The…

Numerical Analysis · Mathematics 2023-09-08 Lihai Ji

This paper improves the convergence and robustness of a multigrid-based solver for the cross sections of the driven Schroedinger equation. Adding an Coupled Channel Correction Step (CCCS) after each multigrid (MG) V-cycle efficiently…

Computational Physics · Physics 2015-09-18 Siegfried Cools , Wim Vanroose

Density matrix embedding theory (DMET) is a fully quantum-mechanical embedding method which shows great promise as a method of defeating the inherent exponential cost scaling of multiconfigurational wave function-based calculations by…

Chemical Physics · Physics 2019-02-07 Matthew R. Hermes , Laura Gagliardi

Quantum Selected Configuration Interaction (QSCI) methods (also known as Sample-based Quantum Diagonalization, SQD) have emerged as promising near-term approaches to solving the electronic Schr{\"o}dinger equation with quantum computers. In…

We have developed a Scalable Linear Augmented Slater-Type Orbital (LASTO) method for electronic-structure calculations on free-standing atomic clusters. As with other linear methods we solve the Schr\"odinger equation using a mixed basis…

Materials Science · Physics 2008-06-11 K. S. Kang , J. W. Davenport , James Glimm , David Keyes , Michael McGuigan

Quantum computers have the potential for an exponential speedup of classical molecular computations. However, existing algorithms have limitations; quantum phase estimation (QPE) algorithms are intractable on current hardware while…

Quantum Physics · Physics 2023-03-03 Scott E. Smart , David A. Mazziotti

Quantum computers hold immense potential in the field of chemistry, ushering new frontiers to solve complex many body problems that are beyond the reach of classical computers. However, noise in the current quantum hardware limits their…

Quantum Physics · Physics 2024-03-20 Chayan Patra , Sonaldeep Halder , Rahul Maitra

We investigate fully self-consistent multiscale quantum-classical algorithms on current generation superconducting quantum computers, in a unified approach to tackle the correlated electronic structure of large systems in both quantum…

Stochastic Gradient Descent (SGD) and its variants underpin modern machine learning by enabling efficient optimization of large-scale models. However, their local search nature limits exploration in complex landscapes. In this paper, we…

Quantum Physics · Physics 2025-07-22 Sirui Peng , Shengminjie Chen , Xiaoming Sun , Hongyi Zhou

We present and analyze a multiscale method for wave propagation problems, posed on spatial networks. By introducing a coarse scale, using a finite element space interpolated onto the network, we construct a discrete multiscale space using…

Numerical Analysis · Mathematics 2023-04-12 Morgan Görtz , Per Ljung , Axel Målqvist

Fractional evolution equations lack generally accessible and well-converged codes excepting anomalous diffusion. A particular equation of strong interest to the growing intersection of applied mathematics and quantum information science and…

Quantum Physics · Physics 2024-03-13 Joshua M. Lewis , Lincoln D. Carr

A contracted quantum eigensolver (CQE) finds a solution to the many-electron Schr\"odinger equation by solving its integration (or contraction) to the 2-electron space -- a contracted Schr\"odinger equation (CSE) -- on a quantum computer.…

Quantum Physics · Physics 2022-05-05 Scott E. Smart , David A. Mazziotti

We extend the publicly available quantumfdtd code. It was originally intended for solving the time-independent three-dimensional Schr\"odinger equation via the finite-difference time-domain (FDTD) method and for extracting the ground,…

High Energy Physics - Phenomenology · Physics 2023-01-02 Rafael L. Delgado , Sebastian Steinbeißer , Michael Strickland , Johannes H. Weber

We consider solving nonlinear optimization problems with a stochastic objective and deterministic equality constraints, assuming that only zero-order information is available for both the objective and constraints, and that the objective is…

Optimization and Control · Mathematics 2025-10-28 Sen Na

We present a new stochastic extended Lagrangian solution to charge equilibration that eliminates self-consistent field (SCF) calculations, eliminating the computational bottleneck in solving the many-body solution with standard SCF solvers.…

Computational Physics · Physics 2020-05-22 Songchen Tan , Itai Leven , Dong An , Lin Lin , Teresa Head-Gordon

We discuss stationary solutions of the discrete nonlinear Schr\"odinger equation (DNSE) with a potential of the $\phi^{4}$ type which is generically applicable to several quantum spin, electron and classical lattice systems. We show that…

Mathematical Physics · Physics 2015-06-26 Harj S. Dhillon , Fjodor V. Kusmartsev , Karl E. Kürten

The quantum mechanical ground state of electrons is described by Density Functional Theory, which leads to large minimization problems. An efficient minimization method uses a selfconsistent field (SCF) solution of large eigenvalue…

Materials Science · Physics 2007-05-23 Claus Bendtsen , Ole H. Nielsen , Lars B. Hansen

We present a novel numerical method and algorithm for the solution of the 3D axially symmetric time-dependent Schr\"odinger equation in cylindrical coordinates, involving singular Coulomb potential terms besides a smooth time-dependent…

Atomic Physics · Physics 2017-07-11 Szilárd Majorosi , Attila Czirják
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